• Geomechanics and Engineering
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• v.29 no.2
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• pp.113-131
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• 2022

A rockburst is a common disaster in deep-tunnel excavation engineering, especially for high-geostress areas. An anomalously low friction effect is one of the most important inducements of rockbursts. To elucidate the correlation between an anomalously low friction effect and a rockburst, we establish a two-dimensional prediction model that considers the discontinuous structure of a rock mass. The degree of freedom of the rotation angle is introduced, thus the motion equations of the blocks under the influence of a transient disturbing force are acquired according to the interactions of the blocks. Based on the two-dimensional discontinuous block model of deep rock mass, a rockburst prediction model is established, and the initiation process of ultra-low friction rockburst is analyzed. In addition, the intensity of a rockburst, including the location, depth, area, and velocity of ejection fragments, can be determined quantitatively using the proposed prediction model. Then, through a specific example, the effects of geomechanical parameters such as the different principal stress ratios, the material properties, a dip of principal stress on the occurrence form and range of rockburst are analyzed. The results indicate that under dynamic disturbance, stress variation on the structural surface in a deep rock mass may directly give rise to a rockburst. The formation of rockburst is characterized by three stages: the appearance of cracks that result from the tension or compression failure of the deformation block, the transformation of strain energy of rock blocks to kinetic energy, and the ejection of some of the free blocks from the surrounding rock mass. Finally, the two-dimensional rockburst prediction model is applied to the construction drainage tunnel project of Jinping II hydropower station. Through the comparison with the field measured rockburst data and UDEC simulation results, it shows that the model in this paper is in good agreement with the actual working conditions, which verifies the accuracy of the model in this paper.

• Applied Chemistry for Engineering
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• v.19 no.3
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• pp.332-337
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• 2008

Hydrosilylation reaction of 1,1,1,3,5,5,5-heptamethyl trisiloxane (HMTS) and unsaturated poly(oxyethylene) (UPOE) was carried out in the presence of Speier's catalyst. The effect of molar ratio of two reagents on the reactivity and the structure of the product (HMTS-POE) were investigated by FT-IR and $^1H-NMR$. The pure HMTS-POE without containing unreacted HMTS or UPOE could be obtained by the reaction with excess amount of HMTS and followed by removing unreacted HMTS under vacuum. Under the same reaction conditions, various HMTS-POEs composed of UPOEs with a different molecular weight were synthesized, and the surface tensions of HMTS-POEs were analyzed. HMTS-POE, whose EO contents are in the range of 49~57%, exhibited lower surface tension and a potential application for low molecular weight silicone modified with polyethers.

• Journal of the Korean Society of Hazard Mitigation
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• v.4 no.2 s.13
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• pp.19-27
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• 2004

The interest in the dynamic properties of soils has increased strongly because of earthquake, heavy traffic, and foundations undergo high amplitude of vibrations. Most of soils in Korean peninsula are composed of granite soils, especially the decomposed mudstone soils are widely spread in Pohang areas, Kyong-buk province. Therefore, it is very important to investigate the dynamic properties of these types of soils. The most important soil parameters under dynamic loadings are shear modulus and material dampings. Furthermore, few definitive data exist that can evaluate the behavior of unsaturated decomposed mudstone soils under dynamic loading conditions. The investigations described in this paper is designed to identify the shear modulus and damping ratio due to a surface tension for the unsaturated decomposed mudstone soils under low and high strain amplitude. For this purpose, the resonant column test and the cyclic triaxial test were performed. Test results and data have shown that the optimum saturated degree of decomposed mudstone soils under low and strain amplitude is $32{\sim}37%$ which is higher than that of decomposed granite due to the amount of fine particles as well as the type and proportion of chief rock-forming minerals.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.44 no.4
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• pp.381-388
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• 2018

Various characteristics of Opuntia humifusa (O. humifusa) extract solution obtained under low temperature and reduced pressure were examined and cosmetic essences using the extract solution as a humectant were prepared. The O. humifusa extract solution represented very small surface tension (25 mN/m) and contact angle ($8^{\circ}$), compared with other humectants such as glycerine and 1% hyaluronic acid solution. Also, the viscosity and stickiness of the extract solution were very low. The O. humifusa extract solution made it possible for a small amount of oil to be dispersed stably in water without any surfactant. Unlike other humectants, the viscosity and stickiness of cosmetic essences were reduced as the extract solution content in formulation increased. These results show that the O. humifusa extract solution obtained under low temperature and reduced pressure can be used as a natural humectant that provides moisturizing property and less sticky feeling.

• Journal of the Korean Wood Science and Technology
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• v.42 no.1
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• pp.49-57
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• 2014

The pre-air-drying of Korean pine before the high-temperature and low-humidity drying was shown to be effective in uniform moisture content distribution and prevention of surface check. Our results suggest that initial moisture content of the timber also plays important role in high-temperature and low-humidity drying method. The pre-air-drying also helps in the reduction of surface checks in Korean pine when compared to the Korean pine dried by only high-temperature and low-humidity. End-coating was not effective in the prevention of twist, shrinkage, case hardening and internal checks. The pre-air-drying reduces the internal tension stresses which occur during high-temperature and low-humidity drying thus decreasing case hardening and also preventing internal checks. The pre-air-drying decreases the moisture content and causes shrinkage which leads to increased twist in the Korean pine.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.04a
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• pp.42-42
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• 2008

Considerable attention has been focused on the applications of flexible liquid crystal (LC)-based displays because of their many potential advantages, such as portability, durability, light weight, thin packaging, flexibility, and low power consumption. To develop flexible LCDs that are capable of delivering high-quality moving images, like conventional glass-substrate LCDs, the LC device structure must have a stable alignment layer of LC molecules, concurrently support uniform cell gaps, and tightly bind two flexible substrates under external tension. However, stable LC molecular alignment has not been achieved because of the layerless LC alignment, and consequently high-quality images cannot be guaranteed. To solve these critical problems, we have proposed a PDMS pixel-wall based bonding method via the IB irradiation was developed for fasten the two substrates together strongly and maintain uniform cell gaps. The effect of the IB irradiation on PDMS with PI surface was also evaluated by side structure configuration and a result of x-ray photoelectron spectroscopic analysis of PDMS interlayer as a function of binder with substrates. large number of PDMS pixel-walls are tightly fastened to the surface of each flexible substrate and could maintain a constant cell gap between the LC molecules without using any other epoxy or polymer. To enhance the electro-optical performance of the LC device, we applied an alignment method that creates pretilt angle on the PI surface via ion beam irradiation. Using this approach, our flexible LCDs have a contrast ratio of 132:1 and a response time of about 15 ms, resulting in highly reliable electro-optical performance in the bent state, comparable to that of glass-substrate LCDs.

• Journal of Microbiology and Biotechnology
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• v.23 no.11
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• pp.1598-1609
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• 2013

Organochlorine pesticide residues continue to remain as a major environmental threat worldwide. Lindane is an organochlorine pesticide widely used as an acaricide in medicine and agriculture. In the present study, a new lindane-degrading yeast strain, Pseudozyma VITJzN01, was identified as a copious producer of glycolipid biosurfactant. The glycolipid structure and type were elucidated by FTIR, NMR spectroscopy, and GC-MS analysis. The surface activity and stability of the glycolipid was analyzed. The glycolipids, characterized as mannosylerythritol lipids (MELs), exhibited excellent surface active properties and the surface tension of water was reduced to 29 mN/m. The glycolipid was stable over a wide range of pH, temperature, and salinity, showing a very low CMC of 25 mg/l. Bio-microemulsion of olive oil-in-water (O/W) was prepared using the purified biosurfactant without addition of any synthetic cosurfactants, for lindane solubilization and enhanced degradation assay in liquid and soil slurry. The O/W bio-microemulsions enhanced the solubility of lindane up to 40-folds. Degradation of lindane (700 mg/l) by VITJzN01 in liquid medium amended with bio-microemulsions was found to be enhanced by 36% in 2 days, compared with degradation in 12 days in the absence of bio-microemulsions. Lindane-spiked soil slurry incubated with bio-microemulsions also showed 20-40% enhanced degradation compared with the treatment with glycolipids or yeast alone. This is the first report on lindane degradation by Pseudozyma sp., and application of bio-microemulsions for enhanced lindane degradation. MEL-stabilized bio-microemulsions can serve as a potential tool for enhanced remediation of diverse lindane-contaminated environments.

• Transactions of the Korean Society of Pressure Vessels and Piping
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• v.8 no.3
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• pp.13-22
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• 2012

According to recent research on leak-rate estimates to assess rupture probabilities of nuclear piping which contains a circumferential surface/through-wall cracks due to PWSCC, i.e., xLPR (Extremely Low Probability of Rupture) program, it has been revealed that the use of crack shape with an idealized circumferential through-wall crack during actual crack growth can lead to overestimate of the leak-rate. Thus, for accurate estimation of the leak-rate during crack growth, the more realistic crack shape that can simulate the crack shape transition from surface crack to through-wall crack should be used. In this context, in the present study, the elastic crack opening displacement of slanted circumferential through-wall crack in thick-walled cylinder was proposed based on 3-dimensional elastic finite element fracture mechanics analyses. To propose the elastic crack opening displacement of slanted circumferential through-wall crack in thick-walled cylinder, the geometric variables affecting crack opening displacement, i.e., thickness of cylinder, reference inner crack length and slant crack ratio were systematically varied. In terms of loading conditions, axial tension, global bending moment and internal pressure were considered. The present results can be applied to calculate the leak-rate considering more realistic crack shape transition from surface crack to idealized through-wall crack, and can be expected to enhance current leak-rate estimation scheme, for instance, in xLPR program etc.

• Journal of the Korean Society of Hazard Mitigation
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• v.5 no.2 s.17
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• pp.57-63
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• 2005

In case of general structures, it has been known that the strain amplitude band experienced by the base in a state of service load is less than 1% and most of the base show low, strain amplitude behavior less than 0.01%. In this study examining the influence affected to dynamic behavior in a condition of the low strain amplitude of unsaturated decomposed granite soils, the resonant column test, using some samples in Su-won area, has been performed for each degree of saturation resulted from different void ratios and confined stress. It is found out that the minimum value of the damping ratio occurred in roughly $17{\sim}18%$ according to void ratios regardless of confined pressure in the same manner with the case of the maximum shear elastic modulus; and it is estimated that for the influence of surface tension in the optimum degree of saturation, the damping ratio appears to be least.

• Korean Journal of Materials Research
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• v.25 no.12
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• pp.719-726
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• 2015

For a decade, solution-processed functional materials and various printing technologies have attracted increasingly the significant interest in realizing low-cost flexible electronics. In this study, Cu nanoparticles are synthesized via the chemical reduction of Cu ions under inert atmosphere. To prevent interparticle agglomeration and surface oxidation, oleic acid is incorporated as a surface capping molecule and hydrazine is used as a reducing agent. To endow water-compatibility, the surface of synthesized Cu nanoparticles is modified by a mixture of carboxyl-terminated anionic polyelectrolyte and polyoxylethylene oleylamine ether. For reducing the surface tension and the evaporation rate of aqueous Cu nanoparticle inks, the solvent composition of Cu nanoparticle ink is designed as DI water:2-methoxy ethanol:glycerol:ethylene glycol = 50:20:5:25 wt%. The effects of poly(styrene-co-maleic acid) as an adhesion promoter(AP) on rheology of aqueous Cu nanoparticle inks and adhesion of Cu pattern printed on polyimid films are investigated. The 40 wt% aqueous Cu nanoparticle inks with 0.5 wt% of Poly(styrene-co-maleic acid) show the "Newtonian flow" and has a low viscosity under $10mPa{\cdots}S$, which is applicable to inkjet printing. The Cu patterns with a linewidth of $50{\sim}60{\mu}m$ are successfully fabricated. With the addition of Poly(styrene-co-maleic acid), the adhesion of printed Cu patterns on polyimid films is superior to those of patterns prepared from Poly(styrene-co-maleic acid)-free inks. The resistivities of Cu films are measured to be $10{\sim}15{\mu}{\Omega}{\cdot}cm$ at annealing temperature of $300^{\circ}C$.