• Title/Summary/Keyword: Low Dielectric Constant

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BTMSM/O2 유량변화에 따른 SiOCH 박막의 유전상수 특성 (Properties of SiOCH Thin Film Dielectric Constant by BTMSM/O2 Flow Rates)

  • 김종욱;황창수;김홍배
    • 한국전기전자재료학회논문지
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    • 제21권4호
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    • pp.362-367
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    • 2008
  • We have Manufactured the low-k dielectric interlayer fabricated by plasma enhanced chemical vapor deposition (PECVD), The thin film of SiOCH is studied correlation between components and Dielectric constant. The precursor was evaporated and introduced with the flow rates from 16 sccm to 25 sccm by 1sccm step in the constant flow rate of 60 sccm $O_2$ in process chamber. The chemical characteristics of SiOCH were analyzed by measuring FT/IR absorption lines and obtained each dielectric constant measuring C-V. Then compare respectively. ILD of BTMSM/$O_2$ could have low dielectric constant about $k\sim2$, and react sensitively. Also dielectric constant could be decreased by the effects of decreasing $CH_3$ and growing Si-O-Si(C) after annealing process.

Electrical and Mechanical Properties of Ordered Mesoporous Silica Film with HMDS Treatment

  • Ha, Tae-Jung;Choi, Sun-Gyu;Reddy, A. Sivasankar;Yu, Byoung-Gon;Park, Hyung-Ho
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.159-159
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    • 2007
  • In order to reduce a signal delay in ULSI, low resistive metal and intermetal dielectric material of low dielectric constant are required. Ordered mesoporous silica film is proper to intermetal dielectric due to its low dielectric constant and superior mechanical properties. In this study, ordered mesoporous silica films was synthesized using TEOS (tetraethoxysilane) / MTES (methyltriethoxysilane) mixed silica precursor and Brij-$76^{(R)}$ surfactant. These films had the porosity of 40% and dielectric constant of 2.5. To lower dielectric constant, the ordered mesoporous silica films were surface-modified by HMDS (hexamethyldisilazane) treatment. HMDS substituted -OH groups on the surface of silica wall for -Si$(CH_3)_3$ groups. After the HMDS treatment, ordered mesoporous silica films were calcined at various calcination temperatures. Through the investigation, it was concluded that the proper calcination temperature is necessary as aspects of structural, electrical, and mechanical properties.

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중금속으로 오염된 포화사질토의 저주파대에서의 유전특성

  • 방선영;오명학;김용성;박준범
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2003년도 추계학술발표회
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    • pp.289-292
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    • 2003
  • Laboratory tests were performed to investigate the dielectric property of saturated sands contaminated by heavy metals solution at low frequency. Differences of contamination and the real part of dielectric constant depend on heavy metal concentration was measured at low frequency, 100KHz below. The optimal frequency to develop the detection potentials of monitoring was 1KHz, 10KHz, 100KHz. At this frequency, Heavy metal contamination of saturated sands contamination can be recommended by analysis of complex dielectric constant.

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Glass Frit 및 TiO2 첨가에 따른 LTCC용 마이크로파 유전체의 유전 특성 (Microwave Dielectric Properties of Low Temperature Co-fired Ceramics with Glass Frit and TiO2 Additives)

  • 윤중락;이석원;이헌용
    • 한국전기전자재료학회논문지
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    • 제17권9호
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    • pp.942-946
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    • 2004
  • The crystalline and dielectric properties on Al$_2$O$_3$ filled glass frit (CaO-Al$_2$O$_3$-SiO$_2$-MgO-B$_2$O$_3$) with admixtures of TiO$_2$ have been investigated. The dielectric constant value of 7.5 ∼ 7.8, qualify factor value of 700 were obtained for glass frit : Al$_2$O$_3$(50 : 50 wt%) ceramics. Addition of TiO$_2$ less than 5 wt% slightly increased the dielectric constant from 7.8 to 8.8 due to higher dielectric constant of TiO$_2$. With increasing the amount of TiO$_2$ up to 5 wt%, the temperature coefficient of dielectric properties was improved. When the TiO$_2$ 5 wt% were added, dielectric properties were dielectric constant 8.8, quality factor 840 and the temperature coefficient of dielectric 45 ppm/$^{\circ}C$ at a sintering temperature 920$^{\circ}C$.

마이크로전자 응용에서의 저유전율 고분자 재료 (Low Dielectric Constant Polymeric Materials for Microelectronics Applications)

  • 이호영
    • 마이크로전자및패키징학회지
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    • 제9권3호
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    • pp.57-67
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    • 2002
  • 반도체 칩의 신호처리속도를 향상시키기 위한 방법에는 세 가지가 있다. 첫 번째 방법은 금속배선의 배치(layout)를 바꾸는 것이고, 두 번째 방법은 배선으로 사용되는 금속의 비저항을 감소시키는 것이며, 세 번째 방법은 절연재료(insulating material)의 유전상수(dielectric constant)를 감소시키는 것이다. 첫 번째나 두 번째의 방법에 대해서는 많은 연구가 이루어졌고, 지금도 연구가 이루어지고 있다. 그러나 첫 번째나 두 번째의 방법을 통하여 얻을 수 있는 신호처리속도의 향상보다는 세 번째 방법을 통하여 얻을 수 있는 신호처리속도의 향상이 더 크다. 본 논문에서는 먼저 마이크로전자에 응용되기 위한 절연재료의 요구조건을 살펴보고, 지금까지 개발된 저유전율 고분자재료들을 간략하게 소개할 예정이다. 아울러 유전상수를 낮추기 위하여 최근 개발된 기공을 갖는 고분자재료들과 이들을 제조하기 위한 공정에 대해서도 간략하게 소개할 예정이다.

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플라즈마 디스플레이 패널을 위한 $B_2O_3-Al_2O_3$-SrO계 유리의 물리적 특성 (Optical, Thermal and Dielectric Properties of $B_2O_3-Al_2O_3$-SrO Glasses for Plasma Display Panel)

  • 황성진;김진호;이상욱;김형순
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.33-33
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    • 2007
  • In PDP industry, the dielectrics and barrier ribs have been required with low dielectric constant, low melting point and Pb-free composition due to the low power consumption, low signal delay time and the environment restriction. We were studied with $B_2O_3-Al_2O_3$-SrO glass systems about optical, thermal and dielectric properties. The glass forming region of the $B_2O_3-Al_2O_3$-SrO glass systems was narrow due to the amount of the glass former $(B_2O_3)$. The glass transition temperature (Tg) of the glasses was at $550{\sim}590^{\circ}C$. The glasses have 6~8 for the dielectric constant. Furthermore, the transmittance of the glasses was over 80% on the range of the visible ray. From the results, the glasses of the $B_2O_3-Al_2O_3$-SrO glass systems should enable to be a good candidate of the PDP devices for information display with low dielectric constant. The aim of this study is to give a fundamental result of new glass system for low dielectric constant in the information display.

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Study on the Formation of SiOC Films and the Appropriate Annealing Temperature

  • Oh, Teresa
    • Journal of information and communication convergence engineering
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    • 제9권2호
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    • pp.217-219
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    • 2011
  • As silicon devices shrink and their density increases, the low dielectric constant materials instead of $SiO_2$ film is required. SiOC film as low-k films was deposited by the capacitively coupled plasma chemical vapor deposition and then annealed at $300{\sim}500^{\circ}C$ to find out the properties of the dependence on the temperature and polarity. This study researched the dielectric constant using by the structure of the metal/SiOC film/p-Si, chemical shift, thickness, refractive index and hardness. The trend of reflective index was inverse proportioned the thickness, but the dielectric constant was proportioned it. The dielectric constant decreased with decreasing the thickness and the increment of the refractive index.

Cordierite/Glass Composite계 LTCC 소재의 소결 및 유전특성 (Sintering and Dielectric Properties in Cordierite/Glass Composite for LTCC Application)

  • 황일선;여동훈;신효순;김종희
    • 한국전기전자재료학회논문지
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    • 제21권2호
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    • pp.144-150
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    • 2008
  • Recently, there has been growing interest in low loss and low dielectric constant material for LTCC application, as the frequency range for electronic devices increases. This study was designed to evaluate the effect of cordierite filler for low dielectric constant LTCC material. From the previous experiments, two glass compositions of B-Si-Al-Zn-Ba-Ca-O and B-Si-Al-Sr-Ca-O system, were chosen. Each powder of two glass compositions was sintered respectively with commercial cordierite powder in temperature range from $800^{\circ}C\;to\;900^{\circ}C$. Crystalline cordierite and glass peaks were affected only with two factors of composition and sintering temperature among various factors. With the optimized condition of two cordierite/glass compositions, obtained dielectric constant was below 5.5 and quality factor was above 1,000. Closed pore of sintered body was controled by sintering temperature and sintering time. When cordierite/glass composite with ratio of 5.5:4.5 was sintered at $900^{\circ}C$, densification was sufficient with good dielectric characteristics of ${\epsilon}_r<5.1,\;Q{\ge}1,000$. Residual fine closed pores could be reduced with control of sintering temperature and time. 3 point bending strength and chemical durability were evaluated to obtain feasibility for substrate material.

Epoxy/Annealing $SiO_2$ Composites의 충진함량에 대한 저 유전특성 (Low Dielectric Properties of Epoxy/Annealing $SiO_2$ Composites for Filler Contents Variation)

  • 박재준;안준오;윤종현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.224-225
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    • 2007
  • The Low dielectric properties of epoxy/Annealing $SiO_2$ composites using Annealing new material of nanosized amorphous particles were investigated as function frequency, temperature and filler contents composition. The dielectric constant decrease with increasing frequency and also increase with increasing ambient temperature. The dielectric constant decrease with increase annealing filler contents for epoxy base. The result of x-ray diffraction could obtained single crystal of annealing $SiO_2$ from 500nm amorphous $SiO_2$ powder.

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Design of a new barrier rib with low dielectric constant and thermal stability

  • Lee, Chung-Yong;Hwang, Seong-Jin;You, Young-Jin;Lee, Sang-Ho;Kim, Hyung-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.725-727
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    • 2009
  • Lowering the dielectric constant is one of the important issues for the efficiency and the power consumption in the plasma display panel (PDP) industry. This study examined the effect of the addition of ceramic filler (up to 10% of crystalline and amorphous silica, respectively) to a $B_2O_3$-ZnO- $P_2O_5$ glass matrix on the dielectric, coefficient of thermal expansion, etching behaviors and residual stress for the barrier ribs in plasma display panels. The dielectric constant of barrier ribs is affected by containing two types of $SiO_2$ filler for the barrier rib composition in PDP.

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