• Atmosphere
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• v.20 no.3
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• pp.307-318
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• 2010

This study investigates the generation and movement of low-concentration $CO_2$ observed in Gosan during summer from 2002 to 2006. For analysis, additional $CO_2$ data in Anmyeondo, Ryori, Barrow, and Minamitorishima as well as NOAA/ESRL daily global $CO_2$ fields, background trajectories data, and 850 hPa wind fields are also used. Based on analyses using various observed data, we classified three types of low-concentration $CO_2$ in Gosan according to its origin: i) the origin of the Siberian continental, in which the consumption of $CO_2$ is active due to photosynthesis from broad forests, ii) the origin of Okhotsh and Artic seas, in which the low-concentration $CO_2$ is dominant due to high primary productivity by a plankton bloom, and iii) the origin of the Northwestern Pacific which is related to the entry of air mass from high latitudes. These results show that the low-concentration $CO_2$ observed in Gosan during summer is not originated from the Pacific oceans as known in previous studies, but originated from high latitude regions such as the Siberian continental and the Okhotsh and Artic seas.

• Clean Technology
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• v.28 no.1
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• pp.1-8
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• 2022

To confirm the applicability of the water gas shift reaction for the production of high purity hydrogen for petroleum cokes, an unutilized low grade resource, Cu/ZnO/MgO/Al₂O₃ (CZMA), catalyst was prepared using the co-precipitation method. The prepared catalyst was analyzed using BET and H₂-TPR. Catalyst reactivity tests were compared and analyzed in two cases: a single LTS reaction from syngas containing a high concentration of CO, and an LTS reaction immediately after the syngas passed through a HTS reaction without condensation of steam. Reaction characteristics in accordance with steam/CO ratio, flow rate, and temperature were confirmed under both conditions. When the converted low concentration of CO and steam were immediately injected into the LTS, the CO conversion was rather low in most conditions despite the presence of large amounts of steam. In addition, because the influence of the steam/CO ratio, temperature, and flow rate was significant, additional analysis was required to determine the optimal operating conditions. Meanwhile, carbon deposition or activity degradation of the catalyst did not appear under high CO concentration, and high CO conversion was exhibited in most cases. In conclusion, it was confirmed that when the Cu/ZnO/MgO/Al₂O₃ catalyst and the appropriate operating conditions were applied to the syngas composition containing a high concentration of CO, the high concentration of CO could be converted in sufficient amounts into CO₂ by applying a single LTS reaction.

• Journal of Preventive Medicine and Public Health
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• v.27 no.3 s.47
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• pp.505-516
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• 1994

For the purpose of preparing the fundamental data on air pollution in underground shopping center and also contributing to the health improvement of residents, the authors measured the level of $SO_2,\;NO_2,\;TSP,\;CO,\;CO_2$ and also some related factors as air temperature, air movement, relative humidity and mean radiation temperature at inside and outside of underground shopping center in Pusan from January to February and from July to August 1994. The results were as follows : 1. The mean concentration of CO within the underground shopping center was $3.1{\pm}1.3ppm$ in winter and $2.1{\pm}0.9ppm$ in summer. There was a negative correlation (p<0.01) between inner CO concentration and temperature in summer and no correlation between inner CO concentration and outer CO concentration in underground shopping center 2. The mean concentration of COE within the underground shopping center was $876{\pm}353ppm$ in winter and $757{\pm}125ppm$ in summer. There was a negative correlation (p<0.01) between inner $CO_2$ concentration and air movement in summer and positive correlation (p<0.05) between inner $CO_2$ concentration and outer $CO_2$ concentration in underground shopping center. 3. The mean concentration of $SO_2$ within a underground shopping center was $0.036{\pm}0.019ppm$ in winter and $0.040{\pm}0.013ppm$ in summer. There was a positive correlation(p<0.01) between inner $SO_2$ concentration and temperature in summer and positive correlation between inner $SO_2$ concentration and outer $SO_2$ concentration in summer and winter in underground shopping center. 4. The mean concentration of $NO_2$ within a underground shopping center was $0.052{\pm}0.038ppm$ in winter and $0.042{\pm}0.016ppm$ in summer. There was a no correlation between inner $SO_2$ concentration and thermal factors in summer and winter and low correlation between inner $SO_2$ concentration and outer $SO_2$ concentration in underground shopping center 5. The mean concentration of TSP within a underground shopping center was $430{\pm}214{\mu}g/m^3$ in winter, $366{\pm}73{\mu}g/m^3$ in summer, and very in excess of the atmospheric environmental quality standards of Korea ($150{\mu}g/m3{\downarrow}$). There was low correlation between inner TSP concentration and temperature in summer and high correlation between inner TSP concentration and outer TSP concentration in underground shopping center.

• Journal of the Microelectronics and Packaging Society
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• v.27 no.4
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• pp.11-17
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• 2020

Copper has been proved to be the best catalyst for electrochemical CO2 reduction reaction, however, for optimal efficiency and selectivity, its performance requires improvements. Electrochemical CO2 reduction reaction (RR) using CuO nanowire electrode was performed with different concentrations of KHCO3 electrolyte (0.1 M, 0.5 M, and 1 M). Cu(OH)2 was formed on Cu foil, followed by thermal-treatment at 200℃ under the air atmosphere for 2 hrs to transform it to the crystalline phase of CuO. We evaluated the effects of different KHCO3 electrolyte concentrations on electrochemical CO2 reduction reaction (RR) using the CuO nanowire electrode. At a constant current (5mA), low concentrated bicarbonate exhibited a more negative potential -0.77 V vs. Reversible Hydrogen Electrode (RHE) (briefly abbreviated as VRHE), while the negative potential reduced to -0.33 VRHE in the high concentration of bicarbonate solution. Production of H2 and CH4 increased with an increased concentration of electrolyte (KHCO3). CH4 production efficiency was high at low negative potential whereas HCOOH was not influenced by bicarbonate concentration. Our study provides insights into efficient, economically viable, and sustainable methods of mitigating the harmful environmental effects of CO2 emission.

• Journal of the Korean institute of surface engineering
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• v.36 no.5
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• pp.379-385
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• 2003

The surface morphology, the glossiness and the hardness of Zn-Cr and Zn-Cr-X(X:Co, Mn) alloy electrodeposits were investigated by using chloride bath with EDTA additive and flow cell system. The surface morphology of Zn-Cr alloy and Zn-Cr-Mn alloy changed from fine needle shape crystalline structure to colony structure of fine granular crystallites with increasing current density in the range of 20-100 $A/dm^2$. The surface morphology of Zn-Cr-Co alloy deposited from low Co concentration bath(2.5-10 g/$\ell$) was similar to that of Zn-Cr alloy, while that of Zn-Cr-Co alloy deposited from high cobalt concentration bath was fine granular crystalline structure in the same range of current density. The glossiness of Zn-Cr and Zn-Cr-Mn alloy increased noticeably with increasing current density, while that of Zn-Cr-Mn alloy decreased with increasing Mn concentration of bath in high current density region. The glossiness of Zn-Cr-Co alloy deposited from low Co concentration bath increased with current density while that of the alloy from high Co concentration bath decreased with increasing current density. The hardness of Zn-Cr and Zn-Cr-X alloy increased noticeably with current density.

• Journal of the Korean Society of Clothing and Textiles
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• v.31 no.11
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• pp.1565-1573
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• 2007

This research was aimed to investigate the effect of $K_2CO_3$ instead of NaOH on retting of the kenaf bast. We examined the relationship between separation of fiber bundle and tensile strength besides observing the color, handle and cross sectional view for the kenaf fiber retted with various concentration(100, 150, 200, 250, 500, 1000mmol) of $K_2CO_3$ and double retted with 0.5% pectinase after $K_2CO_3$ retting. The one retted on low $K_2CO_3$ concentration, $150{\sim}200mmol$, showed the best result on color, handle and luster. The separation of fiber bundle started even at the low $K_2CO_3$ concentration, 100mmol, and as the $K_2CO_3$ concentration was higher, the size of the fiber bundle was smaller. In the case of 1000mmol, the fiber bundle became irregular, but they were breaking up into certain way. Regardless of $K_2CO_3$ concentration, the thinner the diameters of the kenaf fiber bundle, the stronger tensile strength have appeared. This result corresponds with the result of cross sectional view. Retting on $150{\sim}200mmol\;K_2CO_3$ concentration was most effective on fiber bundle#s separation and tensile strength. The one with double retted with 0.5% pectinase after $K_2CO_3$ retting showed very small size of fiber bundle and low tensile strength compare to the one just retted on $K_2CO_3$. This decrease of tensile strength seem to be related to damage of the fiber resulted by excessive fibrillation.

• 한국연소학회:학술대회논문집
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• 2007.05a
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• pp.54-59
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• 2007

In a view of capturing $CO_2$ as a greenhouse gas, an experimental study was conducted on the combustion characteristics of pulverized coal in $O_2$/$CO_2$ environment using TGA/DSC and DTF facilities. The effects of gas composition and concentration on the processes of devolatilization and char burning experienced by coal particles in combustion furnace and on the concentration of products such as $CO_2$, CO and $NO_x$ were observed using TGA/DSC and DTF respectively. As results, it were found that the rate of devolitilation is nearly independent on the $O_2$ concentration if it is over 20% but the char burning rate is a sensitive function of $O_2$ percent, and the two rates can be controlled by $O_2$ concentration in order to be similar with those of air combustion case. It was also found that high concentration $CO_2$ can be captured by oxy-coal combustion and high concentration of CO and low value of $NO_x$ are exhausted in that case. Additionally, NO reducing reaction by CO with char as catalyst was observed and a meaningful results were obtained.

• Journal of the Korean institute of surface engineering
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• v.49 no.4
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• pp.331-338
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• 2016

In this work, anodic oxidation behavior of AZ31 Mg alloy was studied as a function of $Na_2CO_3$ concentration in electrolyte by voltage-time curves and observation of surface appearances and morphologies after the anodic treatments, using optical microscopy and confocal scanning laser microscopy (CSLM). The voltage-time curves of AZ31 Mg alloy surface and surface appearances after the anodic treatments showed three different regions with $Na_2CO_3$ concentration : region I, below 0.2 M $Na_2CO_3$ where shiny surface with a number of small size pits; region II, between 0.4 M and 0.6 M $Na_2CO_3$ where dark surface with relatively low number of large size burned or dark spots; region III, more than 0.8 M $Na_2CO_3$ where bright surface with or without large size dark spots were obtained. The anodically treated AZ31 Mg alloy surface became significantly brightened with increasing $Na_2CO_3$ concentration from 0.5 M to 0.8 M which was attribute to the formation of denser and smoother surface films. Pits and porous protruding reaction products were found at relatively large size and small size spots, respectively, on the AZ31 Mg alloy surface in low concentration of $Na_2CO_3$ less than 0.2 M. The formation of pits is attributed to the result of repetition of the formation and detachment of porous anodic reaction products. Based on the experimental results obtained in this work, it is concluded that more uniform, denser and smoother surface of AZ31 Mg alloy could be obtained at more than 0.8 M $Na_2CO_3$ concentration if there is no other oxide forming agent.

• Journal of Mechanical Science and Technology
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• v.19 no.11
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• pp.2068-2076
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• 2005

The influence of oxygen concentration and CO$_{2}$ as diluent in oxidizer side on soot characteristics was studied by Laser Induced Incandescence, Time Resolved LII and Transmission Electron Microscopy photography in non-premixed co flowing flames. Through the comparison of TEM photographs and the decay rate of LII signal, suitable two delay times of TIRE-LII method and signal sensitivity ($\Delta$S$_{TIRE-LII/) were determined. The effects of O$_{2}$ and CO$_{2}$ as diluent in oxidizer side on soot formation are investigated with these calibrated techniques. The O$_{2}$+CO$_{2}$, N$_{2}$, and [Ar+CO$_{2}$] mixture in co-flow were used to isolate CO2 effects systematically. The number concentration of primary particle and soot volume fraction abruptly decrease by the addition of CO$_{2}$ to the co-flow. This suppression is resulted from the short residence time in inception region because of the late nucleation and the decrease of surface growth distance by the low flame temperature due to the higher thermal capacity and the chemical change of CO$_{2}$ including thermal dissociation. As the oxygen concentration increases, the number concentration of soot particles at the inception region increases and thus this increase of nucleation enhances the growth of soot particle.

• Ocean and Polar Research
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• v.37 no.3
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• pp.201-209
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• 2015

To examine the effects of increased $CO_2$ concentration and seawater temperature on the photosynthesis and growth of forest forming Ecklonia cava (Laminariales, Phaeophyta), sporophytic discs and gametophytes were cultured under three $pCO_2$ concentrations (380, 750, 1000 ppm), four temperatures (5, 10, 15, $20^{\circ}C$ for sporophytes; 10, 15, 20, $25^{\circ}C$ for gametophytes), and two irradiance levels (40, $80{\mu}mol$ photons $m^{-2}s^{-1}$) for 5 days. Photosynthetic parameter values ($ETR_{max}$, $E_k$, and ${\alpha}$) were generally higher as sporophytic discs were grown under low temperature and increased $CO_2$ concentration at 750 ppm. However, photosynthesis of Ecklonia sporophytes was severely inhibited under a combination of high temperature ($20^{\circ}C$) and 1000 ppm $CO_2$ concentration at the two photon irradiance levels. The growth of gametophytes was maximal at the combination of 380 ppm (present seawater $CO_2$ concentration) and $25^{\circ}C$. Minimal growth of gametophytes occurred at enriched $pCO_2$ concentration levels (750, 1000 ppm) and high temperature of $25^{\circ}C$. The present results imply that climate change which is increasing seawater temperature and $pCO_2$ concentration might diminish Ecklonia cava kelp beds because of a reduction in recruitments caused by the growth inhibition of gametophytes at high $pCO_2$ concentration. In addition, the effects of increased temperature and $pCO_2$ concentration were different between generations - revealing an enhancement in the photosynthesis of sporophytes and a reduction in the growth of gametophytes.