• Title/Summary/Keyword: Low $O_2$ concentration

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Optical Properties of Soluble Polythiophene for Flexible Solar Cell

  • Kim, Byoung-Ju;Park, Eun-Hye;Kang, Kwang-Sun
    • Current Photovoltaic Research
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    • v.6 no.4
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    • pp.91-93
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    • 2018
  • Polythiophene-$TiO_2$ composite was synthesized with different molar ratios of thiophene and titaniumisopropoxide ($Ti(OPr)_4$) for flexible solar cell application as a flexible electrode or an active material. The $Ti(OPr)_4$ was stabilized by thiophene. The thiophene was polymerized by ferric chloride catalyst. The synthesized polythiophene exhibited strong UV-visible absorption in the range of the wavelength shorter than 500 nm. Field emission scanning electron microscope (FESEM) image of low concentration of $TiO_2$ film showed smooth surface. However, FESEM image of high concentration of $TiO_2$ film exhibited relatively rough surface. Polythiophene concentration dependent strong photoluminescence quenching of surfrhodamine-B was observed.

Synthesis of zinc oxide nanoparticles via aqueous solution routes (수용액 합성법에 의한 ZnO 나노분말의 합성)

  • Koo, Jin Heui;Yang, Jun Seok;Cho, Soo Jin;Lee, Byeong Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.5
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    • pp.175-180
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    • 2016
  • ZnO nanoparticles were synthesized by aqueous preparation routes of a precipitation and a hydrothermal process. In the processes, the powders were formed by mixing aqueous solutions of Zn-nitrate hexahydrate ($Zn(NO_3)_2{\cdot}6H_2O$) with NaOH aqueous solution under controlled reaction conditions such as Zn precursor concentration, reaction pH and temperature. Single ZnO phase has been obtained under low Zn precursor concentration, high reaction pH and high temperature. The synthesized particles exhibited flakes (plates), multipods or rods morphologies and the crystallite sizes and shapes would be efficiently controllable by changing the processing parameters. The hydrothermal method showed advantageous features over the precipitation process, allowing the precipitates of single ZnO phase with higher crystallinity at relatively low temperatures below $100^{\circ}C$ under a wider pH range for the Zn precursor concentration of 0.1~1 M.

Hardening Properties of Activated Calcium Dialuminate Clinker with Phosphoric Acid Solution

  • Song, Tae-Woong;Kim, Sei-Gi
    • The Korean Journal of Ceramics
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    • v.3 no.4
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    • pp.235-238
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    • 1997
  • Basic properties of new cement pastes based on the system $CaO-Al_2O_3-P_O_5-H_2O$were studied Phosphoric acid solutions and calcium dialuminate clinkers synthesized by the hydration-burning method were used for liquid and powder components of the paste, respectively Variation in the compositions of the paste was achieved by changing the liquid/powder ratio and the concentration of phosphoric acid solution. The hardening rate of the paste was so largely affected by the amount of phosphoric acid that hardening was inhibited with the low-concentrated solution but was explosively accelerated with the high-concentrated solution. The phosphoric acid solutions of concentration of 45~50% and the liquid/powder ratio of 0.5~1.5 were favoured for the high early-strength cement paste with the reasonable hardening rate and high strength. The binding phase of hardened paste was the dense amorphous gel of the system $CaO-Al_2O_3-P_O_5-H_2O$. in which the unreacted calcium dialuminate grains were embeded.

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Smartphone-based O2 Deficiency Monitoring Device (스마트폰 기반 산소 결핍 모니터링 장치)

  • Loh, Byoung Gook
    • Journal of the Korean Society of Safety
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    • v.30 no.6
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    • pp.117-121
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    • 2015
  • $O_2$-deficiency related accidents occur every year and the most effective way to prevent them is to measure $O_2$ concentration in air with a properly-calibrated $O_2$ monitoring device before entering low-$O_2$ areas. An electro-chemical sensor, Texas Instrument gas platform, and iPhone are used to construct a smartphone-based $O_2$ monitoring device. The smartphone based $O_2$ measuring approach offers advantages of small size, accessibility, internet-connectivity, and programmability in comparison to conventional $O_2$ measuring devices. Multiple gas sensors can be conveniently interfaced to single smartphone, allowing for creating a network of gas sensors distributed across workplaces and remote monitoring via existing mobile communication network. To check proper function of the $O_2$ monitoring device the sensor was exposed to shallow and deep human breaths. The readings decreased immediately after being exposed to exhalation and recovered during inhalation to a calibrated level of 20.9%. When readings decreased below a preset warning value of 19.5%, a low $O_2$ warning was successfully activated on the smartphone.

Characteristics of Anion Concentration Distributions in Airbone Fine Particles in Urban Atmosphere (도시대기 중에 부유하는 미세입자중 음이온의 농도분포 특성)

  • 천만영;조기철;여현구
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.1
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    • pp.1-7
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    • 1997
  • Anion concentrations and distributions of airborne fine particles less than 2 $\mu$m in urban atmosphere were determined from Feb. 5 to 16, 1996. The sampling was carried out using 8 stages Hering's low pressure impactor (LPI, aerodynamic cutoff diameters are 0.05, 0.075, 0.11, 0.26, 0.50, 1.0, 2.0, and 4.0$\mu$m) on the top of a five-story building located at Kon-Kuk university in Seoul. Average concentrations if C $l^{[-10]}$ , N $O_3$$^{[-10]}$ and S $O_4$$^{2-}$ were 9.4, 8.4, and 14.5 $\mu\textrm{g}$/㎥, respectively. The distributions of these anion concentrations were bimodal types which showed two peaks in the range of 0.075~0.12 ${\mu}{\textrm}{m}$ and 0.5~1 ${\mu}{\textrm}{m}$ in aerodynamic diameter. These results were 2.5~4.7 times higher than anion concentrations collected by Anderson low volume air sampler.

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A Comparison of N and P Removal Characteristics by the Variation of Non-aeration Time in A2O SBBR (A2O SBBR에서 비포기 시간 배분에 따른 질소-인 제거 특성 비교)

  • Park, Young-Seek;Jeong, No-Sung;Kim, Dong-Seog
    • Journal of Environmental Science International
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    • v.16 no.7
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    • pp.813-821
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    • 2007
  • Laboratory scale experiments were conducted to investigate the removal characteristics of nitrogen and phosphorus in two sequencing batch biofilm reactors (SBBRs). SBBR1 had a short first non-aeration period and SBBR2 had a long first non-aeration period. The removal characteristics of nitrogen and phosphorus in each SBBR were precisely observed according to the variation of influent TOC concentration, and the operation control parameters (pH, DO concentration, ORP) in each reactor were measured. In biological nitrogen removal, there was little difference between SBBR1 and SBBR2 and the nitrogen removal efficiencies were very low. The nitrogen and phosphorus removal characteristics in high influent TOC concentration were different from those in low TOC. Nitrogen removals by simultaneous nitrification/denitrification (SND) were occurred in both SBBR1 and SBBR2. The P removal in SBBR1 was superior to that in SBBR2. The second P release was observed in SBBR1 which had long second non-aeration period.

A Study on the Characteristics of $CO_3O_4/{\gamma}-Al_2O_3$ Catalysts for the Emergency Escape Mask Cartridge (화재대피용 방독마스크 정화통 적용을 위한 $CO_3O_4/{\gamma}-Al_2O_3$ 촉매 특성 연구)

  • Kim Deogki;Kim Bokie;Shin Chae-Ho;Shin Changsub
    • Journal of the Korean Society of Safety
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    • v.19 no.4 s.68
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    • pp.74-79
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    • 2004
  • [ $CO_3O_4/{\gamma}-Al_2O_3$ ] catalysts were reported high activity on the low temperature CO oxidation. The effects of the calcination temperature, the loaded amount of cobalt and the oxygen concentration on the characteristics of CO oxidation have been investigated for a emergency escape mask cartridge. $Co(NO_3)_2\cdot6H_2O$ was used as cobalt precursor and the catalysts were prepared by incipient wetness impregnation. TGA shows that enough calcination is accomplished at $450^{\circ}C$ and cobalt phase is $Co_3O_4$ after calcination in the temperature range of $300\ ~500^{\circ}C$. The specific surface area and pore volume of catalysts are decreased with increasing of loaded amount of cobalt. And with the increase of loaded amount of cobalt and the oxygen concentration, the catalytic activity is increased.

Semiconductor coupled solar photo-Fenton's treatment of dyes and textile effluent

  • Raji, Jeevitha R.;Palanivelu, Kandasamy
    • Advances in environmental research
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    • v.5 no.1
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    • pp.61-77
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    • 2016
  • $NanoTiO_2$ was synthesized by ultrasonication assisted sol-gel process and subjected to iron doping and carbon-iron codoping. The synthesized catalysts were characterized by XRD, HR-SEM, EDX, UV-Vis absorption spectroscopy and BET specific surface area analysis. The average crystallite size of pure $TiO_2$ was in the range of 30 - 33 nm, and that of Fe-$TiO_2$ and C-Fe $TiO_2$ was in the range of 7 - 13 nm respectively. The specific surface area of the iron doped and carbon-iron codoped nanoparticles was around $105m^2/g$ and $91m^2/g$ respectively. The coupled semiconductor photo-Fenton's activity of the synthesized catalysts was evaluated by the degradation of a cationic dye (C.I. Basic blue 9) and an anionic dye (C.I. Acid orange 52) with concurrent investigation on the operating variables such as pH, catalyst dosage, oxidant concentration and initial pollutant concentration. The most efficient C-Fe codoped catalyst was found to effectively destruct synthetic dyes and potentially treat real textile effluent achieving 93.4% of COD removal under minimal solar intensity (35-40 kiloLUX). This reveals the practical applicability of the process for the treatment of real wastewater in both high and low insolation regimes.

Studies on the Grassland Development in the Forest XIII. Effect of potassium fertilization on grass production, nutritive value and nitrate nitrogen concentration by growing senson and growth stage under shading condition (임간초지 개발에 관한 연구 X III. 차광조건하에서 칼리시비수준이 계절별 , 생육시기별 목초의 건물생산과 사료가치 및 질산태질소 함량에 미치는 영향)

  • Seo, Sung
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.13 no.2
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    • pp.93-98
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    • 1993
  • To determine the effects of potassium($K_2O$) fertilization level(0, 100, 200 and 300 kg/ha/year) on the growth, dry matter(DM) yield, nutritive value and nitrate nitrogen($NO_3$-N) concentration of grasses grown under shading condition, this experiment was carried out in Grassland Div., LES, 1989. The plants were sampled on different growing seasons (spring, summer and autumn) and growth stages (grazing and soiling), respectively. Shade was controlled artificially ca. 45-50%, and the level of nitrogen fertilization was 200 kg/ha/year in all treatments. Higher DM was produced in spring 1, 453 kg at grazing and 2, 364 kg/ha at soiling stage, and DM production was increased with increasing level of $K_2O$. In this experiment, the optimum amount of $K_2O$ fertilizer was 200 kg/ha. The neutral detergent fiber, acid detergent fiber, DM digestibility, and relative feed value of grasses were not affected by $K_2O$ fertilization, regardless of growing season and growth stage. The $NO_3$-N concentration of grasses grown in spring was very low (ca. 1.0%), regardless of growth stage and $K_2O$ level. However, $NO_3$-N concentration was very high in summer and autumn season, also $NO_3$-N was decreased significantly with increasing level of $K_2O$ fertilization (P<0.05). Application of $K_2O$ fertilizer, therefore, is thoughs to be desirable for reducing $NO_3$-N concentration of grasses, especially in summer and autumn season. So annual split fertilization of $K_2O$ could be recommended on woodland pasture.

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Oxygen Transport in Axisymmetric Thrombosed Aneurysm (혈전이 있는 축대칭 동맥류에서의 산소전달현상)

  • 김한일;태기식;김영호
    • Journal of Biomedical Engineering Research
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    • v.23 no.4
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    • pp.295-300
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    • 2002
  • Localized hypoxia, due to the diminished $O_2$supply, is reported to cause necrosis of the arterial cell and to significantly decrease resistances to physiologic distending pressures. In the present study, in order to understand the mechanism of localized hypoxia which might result in the rupture of the aneurysm. $O_2$ transport phenomena across intraluminal thrombus in axisymmetric aneurysms under steady laminar flow condition were numerically analyzed using the Fick's law and the analogy with the fluid-solid heat transfer. For computational models, varying the thickness of intraluminal thrombus, numerical results showed that for the axisymmetric aneurysm with intraluminal thrombus. $O_2$ concentration became minimal at the aneurysm wall. With increased thickness of the intraluminal thrombus in the aneurysm. regions of low $O_2$ concentration were widely distributed near the aneurysm wall, which resulted in the possibility of localized hypoxia. The present study verifis that intraluminal thrombus influences $O_2$ transport to the aneurysm wall. depending on its size and structure.