• Bulletin of the Korean Chemical Society
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• v.18 no.12
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• pp.1249-1256
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• 1997

Single phase La1-xSrxCoO3 (x≤0.2) was synthesized as a uniform sized 100 nm particulates with relatively high surface area of 20-30 m2/g, at low temperature (≥600 ℃), from a polymeric gel precursors prepared by using poly(vinyl alcohol) as homogenizer. No minor phase developed during the crystallization when polymer/metal mole ratio was higher than 3. As the polymer/metal mole ratio was raised in the gel, the amount of carbonaceous residues in the amorphous solid precursor prepared by heating the gel at 300 ℃ increased. Most of the residues were eliminated by exothermic thermal decomposition around 400 ℃. The amount of residual carbon (less than 1%) left in the crystalline La1-xSrxCoO3 decreased as more polymer was used, eliminating detrimental effect which might be posed by using large amount of organic homogenizer. The crystal structure of La1-xSrxCoO3 synthesized at temperature lower than 800 ℃ was observed to be shifted from rhombohedral to more symmetric cubic. The structure shifted back to rhombohedral as the cubic sample was annealed at 1000 ℃.

• JSTS:Journal of Semiconductor Technology and Science
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• v.15 no.1
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• pp.77-84
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• 2015

This paper presents the design of a low-power, low area 256-radix 16-bit crossbar switch employing a 2D Hyper-X network topology. The Hyper-X crossbar switch realizes the high radix of 256 by hierarchically combining a set of 4-radix sub-switches and applies three modifications to the basic Hyper-X topology in order to mitigate the adverse scaling of power consumption and propagation delay with the increasing radix. For instance, by restricting the directions in which signals can be routed, by restricting the ports to which signals can be connected, and by replacing the column-wise routes with diagonal routes, the fanout of each circuit node can be substantially reduced from 256 to 4~8. The proposed 256-radix, 16-bit crossbar switch is designed in a 65 nm CMOS and occupies the total area of $0.93{\times}1.25mm^2$. The simulated worst-case delay and power dissipation are 641 ps and 13.01 W when operating at a 1.2 V supply and 1 GHz frequency. In comparison with the state-of-the-art designs, the proposed crossbar switch design achieves the best energy-delay efficiency of $2.203cycle/ns{\cdot}fJ{\cdot}{\lambda}2$.

• Korean Chemical Engineering Research
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• v.48 no.4
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• pp.540-543
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• 2010

In this study, we made low temperature plasma reactor in order to treat safely $NO_x$ which included in the gas. We investigated experimently and inspected efficiency characteristics of equipment about flow rate of reactant material and discharge input power which supplied into reactor. As a reaction gas, by using mixture gas of $NO/N_2$ and $N_2/O_2$, we setted up initial NO concentration and supplied the speed of a current to 1~4 l/min. When the amount of flow increased, reduction rate of NO was low. Also when discharge input power was high, decomposition of NO was easy. Also the longer delay time of reaction material and the higher discharge input power was, the higher decomposition energy efficiency was. And when the amount of flow was much, and the more discharge input power increased, the more ozone generated.

• Korean Journal of Metals and Materials
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• v.50 no.3
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• pp.201-205
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• 2012

The effects of various manganese precursors for the low-temperature selective catalytic reduction (SCR) of $NO_x$ were investigated in terms of structural, morphological, and physico-chemical analyses. $MnO_x/TiO_2$ catalysts were prepared from three different precursors, manganese nitrate, manganese acetate(II), and manganese acetate(III), by the sol-gel method. The manganese acetate(III)-$MnO_x/TiO_2$ catalyst tended to suppress the phase transition from the anatase structure to the rutile or the brookite after calcination at $500^{\circ}C$ for 2 h. It also had a high specific surface area, which was caused by a smaller particle size and more uniform distribution than the others. The change of catalytic acid sites was confirmed by Raman and FT-IR spectroscopy and the manganese acetate(III)-$MnO_x/TiO_2$ had the strongest Lewis acid sites among them. The highest de-NOx efficiency and structural stability were achieved by using the manganese cetate(III) as a precursor, because of its high specific surface area, a large amount of anatase $TiO_2$, and the strong catalytic acidity.

• Journal of Advanced Marine Engineering and Technology
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• v.35 no.4
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• pp.379-387
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• 2011

Research and development of LP EGR system for the performance improvement and emission reduction on diesel engine is proceeding at a good pace. LP EGR system seems to be helpful method to further reduce$NO_x$ emissions while maintaining PM emissions at a low level because the boost pressure is unchanged while varying EGR rate. This study is experimentally conducted on a 2.0L common rail DI engine at the medium load condition (2000 rpm, BMEP 1.0 MPa, boost pressure 181.3 kPa) that difficult to use large amount of EGR gas because of deteriorations of performance and fuel consumption. And we investigated the characteristics of performance and fuel consumption while varying EGR systems. The overall results using LP EGR system equipped with ETC identified benefits on reduction of PM and improvement of fuel consumption and thermal efficiency while keep the $NO_x$ level compared to HP EGR and LP EGR with back pressure valve.

• Transactions of the Korean Society of Automotive Engineers
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• v.20 no.1
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• pp.20-27
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• 2012

The $NH_3$-SCR characteristics of $NO_X$ over a V-based catalyst are experimentally examined over a wide range of operating conditions, i.e., $170-590^{\circ}C$ and $30,000-50,000h^{-1}$, with a simulated diesel exhaust containing $NH_3$, NO, $NO_2$, $O_2$, $H_2O$, and $N_2$. The influences of the space velocity and oxygen concentration on the standard-SCR reaction are analyzed, and it is shown that the low space velocity and high oxygen concentration promote the SCR activity by ammonia. The best $deNO_X$ efficiency is obtained with a $NO_2/NO_X$ ratio of 0.5 because of an enhanced chemical activity induced by the fast-SCR reaction, while at the $NO_2/NO_X$ ratios above 0.5 the $deNO_x$ activity decreases due to the slow-SCR reaction. The oxidation of ammonia begins to take place at about $300^{\circ}C$ and the reaction products, such as $N_2$, NO, $NO_2$, $N_2O$, and $H_2O$, are produced by the undesirable oxidation reactions of ammonia, particularly at high temperatures above $450^{\circ}C$. Also, $NO_2$ decomposes to NO and $O_2$ at temperatures above $240^{\circ}C$. Therefore, $NO_2$ decomposition and ammonia oxidation reactions deteriorate significantly the SCR catalytic activity at high temperatures.

• Clean Technology
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• v.21 no.3
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• pp.184-190
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• 2015

Most of LNT catalysts use noble metals such as Pt for low temperature NO_x oxidation but there is an economic weakness. For the purpose of overcoming this, this study is to develop DeNO_x catalyst for LNT excluding PGM (platinum group metal) such as Pt, Pd, Rh, etc. To do so, Al/Co/Ni catalyst selected as a preliminary test is used to study fundamental property and NO_x’s conversion according to calcined temperature. Ultimately, that is, Al/Co/Ni mixed metal oxide which does not use PGM is selected and physicochemical characterization is performed by way of XRD, EDS, SEM, BET and ramp test and NO_x conversion is also analyzed. This study shows that all samples consist of mixed oxides of spinel structure of Co₂AlO₄ and NiAl₂O₄ and have enough pore volume and size for redox. But as a result of NH₃-TPD test, it is desired that calcined temperature needs to be maintained at 700 ℃ or lower. Also only samples which are processed under 500 ℃ satisfied NO and NO_x conversion simultaneously through ramp test. Based on this study’s results, optimum calcined temperature for Al/Co/Ni=1.0/2.5/0.3 mixed metal oxide catalyst is 500 ℃.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.9
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• pp.1238-1246
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• 1998

Recently, the automobile industry has been faced with very serious problems related to the very restricted regulations of exhaust gas emissions. Therefore many researchers have been attracted to the development of oxygenated fuel for a solution to these problems. This paper deals with the effects of oxygenated fuel on exhaust emissions. An experimental study was conducted to investigate PM and $NO_X$ emission using dimethyl carbonate as an oxygenated fuel in a naturally aspirated DI diesel engine. With increased oxygenated fuel amounts. there were significant reductions in PM, HC and CO emissions mainly from depressed thermal cracking. while little increase in $NO_X$ was encountered concurrently. The effective reduction in PM with oxygenated fuel was maintained with the presence of $CO_2$. which suggested low $NO_X$ and PM obtained from the combination of using oxygenated fuel and cooled EGR. Thermal cracking and an analysis of the heat release rate were also studied in the experiment.

• Journal of the Korean Society of Tobacco Science
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• v.5 no.2
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• pp.77-82
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• 1983

The ventilation of cigarette samples made by the combination of various acetate tow denier and porous plug wrapping paper have been investigated The ventilation rate increased no longer in the acetate tow with high mono denier and low total denier but changed slightly in that with low mono denier and high total denier when the porosity of plug wrapping paper was more than 6500cm/min. cbar. Tip pressure drop ratio, Y, was significantly influenced by tip ventilation rate, X. i. e., Y = 1.0880-0.0042x The relationships of ventilation rate, $X_v$. and smoke delivery, Y, were as follows; Tar : $Y_r$= -14.0458-0.1650$X_v$ Nicotine : $Y_N$= - 1.1045-0.0125$X_v$ CO : $Y_{co}$=17.2806-0.2090$X_v$

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.1
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• pp.75-81
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• 2006

Lean premixed combustion is a well known method for low $NO_x$ gas turbine combustor. But lean combustion is usually accompanied by flame instability. To overcome this problem, the hydrogen ($H_2$) was added to main fuel methane to increase flammable limit. In this paper, the effects of hydrogen addition on lean premixed combustion of methane ($CH_4$) were investigated numerically. Results showed that the extinction stretch rate increases and the extinction temperature constant with relatively small amount of $H_2$ addition. The flame temperature and NO emission increase with $H_2$ addition at the same stretch rate and equivalence ratio but it could increase the range of lean extinction and extinction equivalence ratio limit. Eventually, the $H_2$ addition case showed almost same or lower NO emission than no addictive $CH_4$ case in the extinction condition.