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ZnO nanostructures for e-paper and field emission display applications

  • Sun, X.W.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.993-994
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    • 2008
  • Electrochromic (EC) devices are capable of reversibly changing their optical properties upon charge injection and extraction induced by the external voltage. The characteristics of the EC device, such as low power consumption, high coloration efficiency, and memory effects under open circuit status, make them suitable for use in a variety of applications including smart windows and electronic papers. Coloration due to reduction or oxidation of redox chromophores can be used for EC devices (e-paper), but the switching time is slow (second level). Recently, with increasing demand for the low cost, lightweight flat panel display with paper-like readability (electronic paper), an EC display technology based on dye-modified $TiO_2$ nanoparticle electrode was developed. A well known organic dye molecule, viologen, was adsorbed on the surface of a mesoporous $TiO_2$ nanoparticle film to form the EC electrode. On the other hand, ZnO is a wide bandgap II-VI semiconductor which has been applied in many fields such as UV lasers, field effect transistors and transparent conductors. The bandgap of the bulk ZnO is about 3.37 eV, which is close to that of the $TiO_2$ (3.4 eV). As a traditional transparent conductor, ZnO has excellent electron transport properties, even in ZnO nanoparticle films. In the past few years, one-dimension (1D) nanostructures of ZnO have attracted extensive research interest. In particular, 1D ZnO nanowires renders much better electron transportation capability by providing a direct conduction path for electron transport and greatly reducing the number of grain boundaries. These unique advantages make ZnO nanowires a promising matrix electrode for EC dye molecule loading. ZnO nanowires grow vertically from the substrate and form a dense array (Fig. 1). The ZnO nanowires show regular hexagonal cross section and the average diameter of the ZnO nanowires is about 100 nm. The cross-section image of the ZnO nanowires array (Fig. 1) indicates that the length of the ZnO nanowires is about $6\;{\mu}m$. From one on/off cycle of the ZnO EC cell (Fig. 2). We can see that, the switching time of a ZnO nanowire electrode EC cell with an active area of $1\;{\times}\;1\;cm^2$ is 170 ms and 142 ms for coloration and bleaching, respectively. The coloration and bleaching time is faster compared to the $TiO_2$ mesoporous EC devices with both coloration and bleaching time of about 250 ms for a device with an active area of $2.5\;cm^2$. With further optimization, it is possible that the response time can reach ten(s) of millisecond, i.e. capable of displaying video. Fig. 3 shows a prototype with two different transmittance states. It can be seen that good contrast was obtained. The retention was at least a few hours for these prototypes. Being an oxide, ZnO is oxidation resistant, i.e. it is more durable for field emission cathode. ZnO nanotetropods were also applied to realize the first prototype triode field emission device, making use of scattered surface-conduction electrons for field emission (Fig. 4). The device has a high efficiency (field emitted electron to total electron ratio) of about 60%. With this high efficiency, we were able to fabricate some prototype displays (Fig. 5 showing some alphanumerical symbols). ZnO tetrapods have four legs, which guarantees that there is one leg always pointing upward, even using screen printing method to fabricate the cathode.

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Suggestion of Modified Compression Index for secondary consolidation using by Nonlinear Elasto Viscoplastic Models (비선형 점탄소성 모델을 이용한 2차압밀이 포함된 수정압축지수개발)

  • Choi, Bu-Sung;Im, Jong-Chul;Kwon, Jung-Keun
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.10a
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    • pp.1115-1123
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    • 2008
  • When constructing projects such as road embankments, bridge approaches, dikes or buildings on soft, compressible soils, significant settlements may occur due to the consolidation of these soils under the superimposed loads. The compressibility of the soil skeleton of a soft clay is influenced by such factors as structure and fabric, stress path, temperature and loading rate. Although it is possible to determine appropriate relations and the corresponding material parameters in the laboratory, it is well known that sample disturbance due to stress release, temperature change and moisture content change can have a profound effect on the compressibility of a clay. The early research of Tezaghi and Casagrande has had a lasting influence on our interpretation of consolidation data. The 24 hour, incremental load, oedometer test has become, more or less, the standard procedure for determining the one-dimensional, stress-strain behavior of clays. An important notion relates to the interpretation of the data is the ore-consolidation pressure ${\sigma}_p$, which is located approximately at the break in the slope on the curve. From a practical point of view, this pressure is usually viewed as corresponding to the maximum past effective stress supported by the soil. Researchers have shown, however, that the value of ${\sigma}_p$ depends on the test procedure. furthermore, owing to sampling disturbance, the results of the laboratory consolidation test must be corrected to better capture the in-situ compressibility characteristics. The corrections apply, strictly speaking, to soils where the relation between strain and effective stress is time independent. An important assumption in Terzaghi's one-dimensional theory of consolidation is that the soil skeleton behaves elastically. On the other hand, Buisman recognized that creep deformations in settlement analysis can be important. this has led to extensions to Terzaghi's theory by various investigators, including the applicant and coworkers. The main object of this study is to suggestion the modified compression index value to predict settlements by back calculating the $C_c$ from different numerical models, which are giving best prediction settlements for multi layers including very thick soft clay.

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Examining Influences of Asian dust on SST Retrievals over the East Asian Sea Waters Using NOAA AVHRR Data (NOAA AVHRR 자료를 이용한 해수면온도 산출에 황사가 미치는 영향)

  • Chun, Hyoung-Wook;Sohn, Byung-Ju
    • Korean Journal of Remote Sensing
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    • v.25 no.1
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    • pp.45-59
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    • 2009
  • This research presents the effect of Asian dust on the derived sea surface temperature (SST) from measurements of the Advanced Very High Resolution Radiometer (AVHRR) instrument flown onboard NOAA polar orbiting satellites. To analyze the effect, A VHRR infrared brightness temperature (TB) is estimated from simulated radiance calculated from radiative transfer model on various atmospheric conditions. Vertical profiles of temperature, pressure, and humidity from radiosonde observation are used to build up the East Asian atmospheric conditions in spring. Aerosol optical thickness (AOT) and size distribution are derived from skyradiation measurements to be used as inputs to the radiative transfer model. The simulation results show that single channel TB at window region is depressed under the Asian dust condition. The magnitude of depression is about 2K at nadir under moderate aerosol loading, but the magnitude reaches up to 4K at slant path. The dual channel difference (DCD) in spilt window region is also reduced under the Asian dust condition, but the reduction of DCD is much smaller than that shown in single channel TB simulation. Owing to the depression of TB, SST has cold bias. In addition, the effect of AOT on SST is amplified at large satellite zenith angle (SZA), resulting in high variance in derived SSTs. The SST depression due to the presence of Asian dust can be expressed as a linear function of AOT and SZA. On the basis of this relationship, the effect of Asian dust on the SST retrieval from the conventional daytime multi-channel SST algorithm can be derived as a function of AOT and SZA.

Seismic Performance of Concrete Masonry Unit (CMU) Infills in Reinforced Concrete Moment Framing System (철근콘크리트 모멘트 골조시스템에서 조적 끼움벽의 내진성능)

  • Hong, Jong-Kook
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.1
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    • pp.19-26
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    • 2019
  • The masonry infill walls are one of the most popular components that are used for dividing and arranging spaces in building construction. In spite of the fact that the masonry infills have many advantages, the system needs to be used with caution when the earthquake load is to be considered. The infills tend to develop diagonal compression struts during earthquake and increase the demand in surrounding RC frames. If there are openings in the infill walls, the loading path gets even complicated and the engineering judgements are required for designing the system. In this study, a masonry infill system was investigated through finite element analysis (FEA) and the results were compared with the current design standard, ASCE 41. It is noted that the equivalent width of the compression strut estimated by ASCE 41 could be 32% less than that using detailed FEA. The global load resisting capacity was also estimated by 28% less when ASCE 41 was used compare to the FEA case. Rather than using expensive FEA, the adapting ASCE 41 for the analysis and design of the masonry infills with openings would provide a good estimation by about 25% conservatively.

A Case Study on Earthquake-induced Deformation of Quay Wall and Backfill in Pohang by 2D-Effective Stress Analysis (2차원 유효응력 해석에 의한 지진시 포항 안벽구조물의 변형 사례 분석)

  • Kim, Seungjong;Hwang, Woong-Ki;Kim, Tae-Hyung;Kang, Gi-Chun
    • Journal of the Korean Geotechnical Society
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    • v.35 no.7
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    • pp.15-27
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    • 2019
  • The purpose of this study is to investigate the mechanism about damages occurring at quay wall and backfill in Youngilman Port during Pohang earthquake (M5.4) on November 15, 2017. In the field investigation, the horizontal displacement of the caisson occurred between 5 cm and 15 cm, and the settlement at backfill occurred higher than 10 cm. 2D-effective Stress Analysis was performed to clarify the mechanism for the damage. The input earthquake motion used acceleration ($3.25m/s^2$) measured at bedrock of Pohang habor. Based on a numerical analysis, it was found that the effective stress decreased due to the increase of excess pore pressure in the backfill ground and the horizontal displacement of the caisson occurred by about 14 cm, and the settlement occurred by about 3 cm. In backfill, the settlements occurred between 6 cm and 9 cm. This is similar to field investigation results. Also, it was found that the backfill soil was close to the Mohr-Coulomb failure line due to the cyclic loading from the effective stress path and the stress-strain behavior. It may be related to decreasing of bearing capacity induced by the reduction of effective stress caused by the increase of the excess pore water pressure.

An Experiment on Redundancy in Continuous Span Two-Girder Bridge - Effects of Lateral Bracing (연속 2-거더교의 여유도 평가 실험 - 수평브레이싱의 효과)

  • Park, Yong-Myung;Joe, Woom-Do-Ji;Hwang, Min-Oh;Yoon, Tae-Yang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.4A
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    • pp.417-429
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    • 2008
  • This paper presents an experimental result to evaluate the redundancy in continuous span two plate-girder bridges which are generally classified as a non-redundant load path structure. The experiments were performed when one of the two girders is seriously cracked. To estimate the effects of bottom lateral bracing on the redundancy, the experiment variable was considered as the bottom lateral bracing, and two 1/5-scaled bridge specimens with and without lateral bracing system were fabricated. The ultimate loading tests were conducted on the damaged specimens with an induced crack at a girder in the side span. The test results showed that the load carrying capacity of damaged specimen with bracing was about 1.2 times higher than that without bracing. To evaluate the redundancy in each specimen, numerical analysis was performed to calibrate the difference of dead load between the actual bridge and the test specimens. When the dead load calibration is considered, the results showed that a continuous span two-girder bridges have a reasonable redundancy even without lateral bracing. Especially, the level of redundancy is increased by about 1.8 times when the lateral bracing is provided.

A New Detailed Assessment for Liquefaction Potential Based on the Liquefaction Driving Effect of the Real Earthquake Motion (실지진하중의 액상화 발생특성에 기초한 액상화 상세평가법)

  • 최재순;강한수;김수일
    • Journal of the Korean Geotechnical Society
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    • v.20 no.5
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    • pp.145-159
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    • 2004
  • The conventional method for assessment of liquefaction potential proposed by Seed and Idriss has been widely used in most countries because of simplicity of tests. Even though various data such as stress, strain, stress path, and excess pore water pressure can be obtained from the dynamic test, especially, two simple experimental data such as the maximum deviatoric stress and the number of cycles at liquefaction have been used in the conventional assessment. In this study, a new detailed assessment for liquefaction potential to reflect both characteristics of real earthquake motion and dynamic soil resistance is proposed and verified. In the assessment, the safety factor of the liquefaction potential at a given depth of a site can be obtained by the ratio of a resistible cumulative plastic shear strain determined through the performance of the conventional cyclic test and a driving cumulative plastic shear strain calculated from the shear strain time history through the ground response analysis. The last point to cumulate the driving plastic shear strain to initiate soil liquefaction is important for this assessment. From the result of cyclic triaxial test using real earthquake motions, it was concluded that liquefaction under the impact-type earthquake loads would initiate as soon as a peak loading signal was reached. The driving cumulative plastic shear strain, therefore, can be determined by adding all plastic shear strains obtained from the ground response analysis up to the peak point. Through the verification of the proposed assessment, it can be concluded that the proposed assessment for liquefaction potential can be a progressive method to reflect both characteristics of the unique soil resistance and earthquake parameters such as peak earthquake signal, significant duration time, earthquake loading type, and magnitude.