• Title/Summary/Keyword: Lithium-Polymer battery

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Design and Analysis of Large Capacity Lithium Polymer Battery Charger for Hybrid Electrical Vehicle (HEV용 중대형 2차전지 충전기 설계 및 해석)

  • Oh Dong-Seob;Oh Sung-up;Seong Se-jin;Choi Jae-dong
    • Proceedings of the KIPE Conference
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    • 2004.07a
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    • pp.87-91
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    • 2004
  • In this paper, the paralleled forward converter, that is generally used as the power supply for the low voltage, high current load, is described. The proposed forward converter for battery charging could be provided the power without failure not only in steady state but also in the transient period by the step load variation or the unexpected faults among the converter modules. Each converter nodule designed is operated alone with the self closed controller for the elevation of stability, performance, reliability, and maintainability. The frequency response of the designed converter module is analyzed, and the stability is confirmed in analytic method. And the experiments of the paralleled battery charger are carried out in steady state, in the step load variation.

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Development of a Radio Controlled Ornithopter 'Songgolmae' (무선조종 날개짓 비행체 '송골매' 개발)

  • Chang, Jo-Won
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.1993-1998
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    • 2004
  • The present study was carried out to develop highly efficient RC ornithopter 'Songgolmae' powered by motor and battery. Designed electric ornithopter weighs 277 grams and has 3 channels radio control. 1t runs on an electric motor by a lithium polymer battery and has a gear ratio of about $75{\sim}95$ to 1 to flap its 88 cm wingspan. The aerodynamic performance of the ornithopter, applied to a flapping motion only, was validated by flight tests. Flight times have exceeded 23 minutes until the battery was used up. The flight test results indicate that the ornithopter developed here has sufficient thrust to propel itself in a forward flight. From the economical point of view and the handling of the RC ornithopter, it can be said that the developed robot ornithopter is an effective RC ornithopter. This radio controlled ornithopter flies its way high into the sky just like a real bird flies.

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The Performance of Li/V6O13 Lithium Polymer Battery (Li/V6O13 리튬 폴리머 전지의 성능)

  • Kim, Hyung-Sun;Cho, Byung-Won;Yun, Kyung-Suk;Chun, Hai-Soo
    • Applied Chemistry for Engineering
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    • v.7 no.2
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    • pp.362-370
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    • 1996
  • The performance of The performance of $Li/V_6O_{13}$ cell and the electrochemical properties of polymer electrolyte based on poly(acrylonitrile)[PAN] was investigated. The ionic conductivity of polymer electrolyte showed $2.3{\times}10^{-3}S/cm$ and the compatibility with lithium electrode was excellent. Also, it showed the electrochemical stability up to 4.3V(vs. $Li^+/Li$). The cell reaction of $Li/V_6O_{13}$ was dominated by the interfacial resistance between $V_6O_{13}$ electrode and polymer electrolyte. The diffusion coefficient of lithium ion within $V_6O_{13}$ was $2.7{\times}10^{-9}{\sim}4.2{\times}10^{-8}cm^2/sec$. The utilization of $V_6O_{13}$ active material was 95% at C/8($50{\mu}A/cm^2$) and 82% at C/4($100{\mu}A/cm^2$), respectively.

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Cycling Performance of Li4Ti5O12 Electrodes in Ionic Liquid-Based Gel Polymer Electrolytes

  • Kim, Jin-Hee;Kang, Yong-Ku;Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.608-612
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    • 2012
  • We investigated the cycling behavior of $Li_4Ti_5O_{12}$ electrode in a cross-linked gel polymer electrolyte based on non-flammable ionic liquid consisting of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide and vinylene carbonate. The $Li_4Ti_5O_{12}$ electrodes in ionic liquid-based gel polymer electrolytes exhibited reversible cycling behavior with good capacity retention. Cycling data and electrochemical impedance spectroscopy analyses revealed that the optimum content of the cross-linking agent necessary to ensure both acceptable initial discharge capacity and good capacity retention was about 8 wt %.

Nanoscale Pattern Formation of Li2CO3 for Lithium-Ion Battery Anode Material by Pattern Transfer Printing (패턴전사 프린팅을 활용한 리튬이온 배터리 양극 기초소재 Li2CO3의 나노스케일 패턴화 방법)

  • Kang, Young Lim;Park, Tae Wan;Park, Eun-Soo;Lee, Junghoon;Wang, Jei-Pil;Park, Woon Ik
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.83-89
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    • 2020
  • For the past few decades, as part of efforts to protect the environment where fossil fuels, which have been a key energy resource for mankind, are becoming increasingly depleted and pollution due to industrial development, ecofriendly secondary batteries, hydrogen generating energy devices, energy storage systems, and many other new energy technologies are being developed. Among them, the lithium-ion battery (LIB) is considered to be a next-generation energy device suitable for application as a large-capacity battery and capable of industrial application due to its high energy density and long lifespan. However, considering the growing battery market such as eco-friendly electric vehicles and drones, it is expected that a large amount of battery waste will spill out from some point due to the end of life. In order to prepare for this situation, development of a process for recovering lithium and various valuable metals from waste batteries is required, and at the same time, a plan to recycle them is socially required. In this study, we introduce a nanoscale pattern transfer printing (NTP) process of Li2CO3, a representative anode material for lithium ion batteries, one of the strategic materials for recycling waste batteries. First, Li2CO3 powder was formed by pressing in a vacuum, and a 3-inch sputter target for very pure Li2CO3 thin film deposition was successfully produced through high-temperature sintering. The target was mounted on a sputtering device, and a well-ordered Li2CO3 line pattern with a width of 250 nm was successfully obtained on the Si substrate using the NTP process. In addition, based on the nTP method, the periodic Li2CO3 line patterns were formed on the surfaces of metal, glass, flexible polymer substrates, and even curved goggles. These results are expected to be applied to the thin films of various functional materials used in battery devices in the future, and is also expected to be particularly helpful in improving the performance of lithium-ion battery devices on various substrates.

Effect of $ZnCl_2$ on Formation of Carbonized Phenol Resin Anode

  • Kim Han-Joo;Hong Ji-sook;Son Won-Ken;Park Soo-Gil;Oyama Noboru
    • Journal of the Korean Electrochemical Society
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    • v.3 no.2
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    • pp.85-89
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    • 2000
  • For replacing Li metal at Lithium ion Battery(LIB) system, we used carbon powder material which prepared by Pyrolysis of Phenol resin as starting material. It became amorphous carbon by Pyrolysis through it's self condensation by thermal treatment. Amorphous carbon can be doped with Li intercalation and deintercalation because it has wide interlayer. However, it has a problem with structural destroy due to weak carbon-carbon bond. So, we used $ZnCl_2$ as the pore-forming agent. This inorganic salt was used together with the resin serves not only as the pore-forming agent to form open pores, which grow into a three-dimensional network structure in the cured material, but also as the microstructure-controlling agent to form a loose structure doped with bulky dopants. We used SEM in order to find to difference of structure, and can calculate the distance of interlayer by XRD analysis. CV test showed oxidation and reduction.

Electrochemical Characteristics of Microporous Polymer Electrolytes Based on Poly(vinylidene-co-hexafluoropropylene) (PVdF계 미세기공 고분자 전해질의 전기화학적 특성)

  • Jung Kang-Kook;Kim Jong-Uk;Ahn Jou-Hyeon;Kim Ki-Won;Ahn Hyo-Jun
    • Journal of the Korean Electrochemical Society
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    • v.7 no.4
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    • pp.183-188
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    • 2004
  • In order to develop polymer electrolyte for lithium/sulfur batteries, highly microporous P(VdF-HFP) membranes were prepared by phase inversion method. Porous structure was controlled by extracting NMP with mixture of deionized water and methanol. Porous structure of the membranes was observed with SEM. Polymer electrolytes were prepared by soaking the porous membranes in 1M $LiCF_3SO_3-TEGDME/EC$. The ionic conductivity of polymer electrolyte was found to be at high as $2\times10^{-3}S/cm$ when the polymer membrane extracted by $80\%$ methanol was used. The microporous polymer electrolyte optimized in this work displayed high ionic conductivity, uniform pore size, low interfacial resistance and stable ionic conductivity with storage time. The ionic conductivity of polymer electrolytes was measured with various lithium salts, and the conductivity showed $3.3\times10^{-3}S/cm$ at room temperature when $LiPF_6$ was used as a lithium salt.

Evaluation of Thermal Diffusivity and Electrochemical Properties of LiAlH4-PVDF Electrolyte Composites (LiAlH4-PVDF 전해질 복합체의 열확산 및 전기화학적 특성평가)

  • HWANG, JUNE-HYEON;HONG, TAE-WHAN
    • Journal of Hydrogen and New Energy
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    • v.33 no.5
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    • pp.574-582
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    • 2022
  • A lithium-ion battery exhibits high energy density but has many limitations due to safety issues. Currently, as a solution for this, research on solid state batteries is attracting attention and is actively being conducted. Among the solid electrolytes, sulfide-based solid electrolytes are receiving much attention with high ion conductivity, but there is a limit to commercialization due to the relatively high price of lithium sulfide, which is a precursor material. This study focused on the possibility of relatively inexpensive and light lithium hydride and conducted an experiment on it. In order to analyze the characteristics of LiAlH4, ion conductivity and thermal stability were measured, and a composites mixed with PVDF, a representative polymer electrolyte, was synthesized to confirm a change in characteristics. And metallurgical changes in the material were performed through XRD, SEM, and BET analysis, and ion conductivity and thermal stability were measured by EIS and LFA methods. As a result, Li3AlH6 having ion conductivity higher than LiAlH4 is formed by the synthesis of composite materials, and thus ion conductivity is slightly improved, but thermal stability is rapidly degraded due to structural irregularity.

Synthesis of $LiNi_{1-x}Co_xO_2$(x=0.1~0.3) by the polymer-precursor method and charge-discharge characteristics of the Lithium secondary battery (고분자 물질을 gelling agent로 사용하여 합성한 $LiNi_{1-x}Co_xO_2$ (x=0.1~0.3) 분말의 물리화학적 성질 및 Li-이차전지에서의 전기화학적 특성에 관한 연구)

  • 권호진;박용철;조재필;김근배;임홍섭;박동곤
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1998.05a
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    • pp.109-109
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    • 1998
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State-of-Charge Observation of Lithium Polymer Battery using SPKF (SPKF를 이용한 리튬 폴리머 배터리(LiPB)의 충전 상태(SOC) 관측)

  • Seo, Bo-Hwan;Lee, Dong-Choon;Lee, Kyo-Beum;Kim, Jang-Mok
    • Proceedings of the KIPE Conference
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    • 2011.07a
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    • pp.228-229
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    • 2011
  • 본 논문은 SPKF(Sigma-point Kalman Filter)를 이용한 리튬 폴리머 배터리(LiPB)의 충전 상태(SOC: State of Charge) 추정 방법을 제안한다. 배터리 모델은 단순화된 테브난 등가회로 모델과 Runtime 모델이 결합되어 있고, Runtime 모델의 양단 전압을 이용하여 SOC를 추정한다. 제안된 알고리즘은 시뮬레이션을 통해 그 타당성이 검증된다.

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