• 한국전기화학회:학술대회논문집
• /
• 한국전기화학회 2004년도 추계총회 및 학술발표회
• /
• pp.27-27
• /
• 2004

• 한국표면공학회:학술대회논문집
• /
• 한국표면공학회 2000년도 추계학술발표회 초록집
• /
• pp.68-69
• /
• 2000

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1999년도 추계학술대회 논문집 학회본부 C
• /
• pp.968-970
• /
• 1999

The trend of increasing of portable electric devices and demand for global environmental conservation have demands the development of high energy density rechargeable batteries. Lithium polymer battery has excellent theoretical energy density and energy conversion efficiency. Lithium polymer battery, included solid polymer electrolyte(SPE), can be viewed as a system suitable for wide applications from thin film batteries for microelectronics to electric vehicle batteries. The purpose of this paper is to research and development of flyash anode for lithium polymer battery. We investigated AC impedance response and charge/discharge characteristics of flyash/SPE/Li cells. The radius of semicircle associated with the interfacial resistance of flyash/SPE/Li cell increased very slowly during discharge process from 3.11V to 0.478V. And then the cell resistance was decreased at discharge process from 10% SOC to 0% SOC. Also, The radius of semicircle associated with the interfacial resistance of flyash/SPE/Li cell decreasing very slowly during charge process. And then the cell resistance was increased after 20th discharge precess. The discharge capacity based on flyash of 1st and 20th cycles was 276mAh/g and 143mAh/g.

• 대한임베디드공학회논문지
• /
• 제11권5호
• /
• pp.305-312
• /
• 2016

Modern embedded systems are typically operated by the rechargeable batteries in our daily life. Since charge of batteries is considered as an time consuming task, there have been extensive efforts to manage the charge time from the perspective of materials, circuits, and systems. Estimation of battery charge time is one of the essential information to design the charge circuitry. A compact macro model for the constant-current and constant-voltage charge protocol was recently introduced, which gives us a quick estimation of charge time with similar shape to the famous Peukert's law for discharge time estimation. The CC-CV charging protocol is widely used for Lithium-based batteries and Lead-acid batteries. In this paper, we characterize the lead-acid battery by measurement to extract the model coefficients, which was not covered by the previous studies. By our proposed model, the key coefficient Kcc results in 1.18-1.31, which is little bit higher than that of Lithium batteries. The accuracy of our model is within the range of ${\pm}10%$ error, which is compatible with the other studies such as Peukert's law.

• 센서학회지
• /
• 제18권1호
• /
• pp.28-32
• /
• 2009

Most portable mobile devices employ rechargeable lithium-ion batteries. This lithium-ion battery usually suffers from the possibility of explosion due to heat generation from surrounding atmosphere or internal deficiency during charging or at overuse. To solve these problems, most rechargeable batteries have a built-in protection circuit module (PCM). The resistance of a properly processed $VO_2$ critical temperature sensor (CTS) is changed dramatically at a critical temperature of around $68^{\circ}C$, which can replace some bi-metal, NTC, or PTC sensors embedded in PCM. Such $VO_2$ CTS consumes a very small current at the level of natural discharge. Experimental results showed that this CTS could be applied to a PCM as the PCM could protect the battery while keeping its power consumption at minimum.

• Journal of Electrochemical Science and Technology
• /
• 제2권4호
• /
• pp.193-197
• /
• 2011

The influences of the thickness and microstructure of Fe layer on the electrochemical performances of Fe/Si multilayer thin film anodes were investigated. The Fe/Si multilayer films were prepared by electron beam evaporation, in which Fe layer was deposited with/without simultaneous bombardment of Ar ion. The kinetics of Li insertion/extraction reactions in the early stage are slowed down with increasing the thickness of Fe layer, but such a slowdown seems to be negligible for thin Fe layers less than about $500{\AA}$. When the Fe layer was deposited with ion bombardment, even the $300{\AA}$ thick Fe layer significantly suppress Li diffusion through the Fe layer. This is attributed to the dense microstructure of Fe layer, induced by ion beam assisted deposition (IBAD). It appears that the Fe/Si multilayer films prepared with IBAD show good cyclability compared to the film deposited without IBAD.

• 공업화학
• /
• 제34권4호
• /
• pp.365-382
• /
• 2023

A lithium metal anode with high energy density has the potential to revolutionize the field of energy storage systems (ESS) and electric vehicles (EVs) that utilize rechargeable lithium-based batteries. However, the formation of lithium dendrites during cycling reduces the performance of the battery while posing a significant safety risk. In this review, we discuss various strategies for achieving dendrite-free lithium metal anodes, including electrode surface modification, the use of electrolyte additives, and the implementation of protective layers. We analyze the advantages and limitations of each strategy, and provide a critical evaluation of the current state of the art. We also highlight the challenges and opportunities for further research and development in this field. This review aims to provide a comprehensive overview of the different approaches to achieving dendrite-free lithium metal anodes, and to guide future research toward the development of safer and more efficient lithium metal anodes.

• Safety and Health at Work
• /
• 제15권1호
• /
• pp.114-117
• /
• 2024

A lithium-ion battery is a rechargeable battery that uses the reversible reduction of lithium ions to store energy and is the predominant battery type in many industrial and consumer electronics. The lithium-ion batteries are essential to ensure they operate safely. We conducted an exposure assessment five days after a fire in a battery-testing facility. We assessed some of the potentially hazardous materials after a lithium-ion battery fire.We sampled total suspended particles, hydrogen fluoride, and lithium with real-time monitoring of particulate matter (PM) 1, 2.5, and 10 micrometers (㎛). The area sampling results indicated that primary potential hazardous materials such as dust, hydrogen fluoride, and lithium were below the recommended limits suggested by the Korean Ministry of Labor and the American Conference of Governmental Industrial Hygienists Threshold Limit Values. Based on our assessment, workers were allowed to return to work.

• 한국인터넷방송통신학회논문지
• /
• 제24권2호
• /
• pp.127-132
• /
• 2024

최근 이차전지는 다양한 산업 분야에서 사용되고 있다. 특히 소형 및 경량의 특성으로 스마트폰, 노트북, 태블릿 등 다양한 휴대용 전자기기에서 높은 에너지 밀도와 충·방전 효율을 토대로 전기자동차와 에너지저장시스템(Energy Storage System, ESS)의 핵심 부품으로 사용되고 있다. 하지만 이차전지의 과도한 충·방전에 따른 수명감소, 파열, 손상, 화재 등의 문제점이 발생하고 있다. 따라서 BMS(Battery Management System)를 통하여 과도한 충·방전을 보호하고 성능을 향상시킨다. 하지만 실제 리튬이온 배터리를 사용하여 BMS의 차단 및 보호범위 설정하는 데 있어서 이차전지의 수명감소, 파열, 손상, 화재의 문제점이 따른다. 따라서 본 논문에서는 배터리 충방전기와 시뮬레이터를 활용하여 이차전지 중 사용이 높은 리튬이온 배터리와 납축전지의 충전 및 방전 특성을 살펴본다.

• Journal of Electrochemical Science and Technology
• /
• 제6권2호
• /
• pp.50-58
• /
• 2015

There is a great deal of current interest in the development of rechargeable batteries with high energy storage capability due to an increasing demand for electric vehicles (EVs) with driving ranges comparable to those of gasoline-powered vehicles. Among various types of batteries under development, a Li-O₂ battery delivers the highest theoretical energy density; thus, it is considered a promising energy storage technology for EV applications. Despite the fact that extensive research efforts have been made in the field of Li-O₂ batteries in recent years, there are still many technical challenges to be addressed, such as low round-trip efficiency, poor reversibility, and poor power capability. In this article, we provide a short review on the fundamental electrochemistry of Li-O₂ batteries with non-aqueous electrolytes and on electrode materials that have been employed in cathodes (oxygen electrodes). The major aim of this mini-review is to highlight the physical and electrochemical origins of scientific challenges facing Li-O₂ battery technology and to overview the strategies proposed to overcome them.