• Title/Summary/Keyword: Lithium polymer battery

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Development of hybrid system with fuel cell and lithium secondary battery (연료전지와 리튬 이차전지의 하이브리드 시스템 개발)

  • Hwang, Sangmoon;Jung, Eunmi;Son, Dongun;Shim, Taehee;Song, Hayoung
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.143.2-143.2
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    • 2010
  • Therefore, with this development assignment we'd like to develop the hybrid system combining 800W DMFC (Direct Methanol Fuel Cell) and 1.6kW of Lithium secondary battery pack which can be applied to the most common small cart. a scooter, to secure the development capability of hundreds of Watts DMFC, the high-capacity Lithium secondary battery pack, the technology of BMS (Battery Management System) and the development technology of hybrid system. DMFC, in fact, has lower energy efficiency than PEMFC (Polymer Electrolyte Membrane Fuel Cell); however, it has several advantages in terms of fuel storage and use. It is pretty easy to be stored and used without any additional colling and heating devices because of its insensitive liquid methanol to temperature. In conclusion, DMFC system is the most suitable device for small mobile vehicles.

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Performance Assessment of a Lithium-Polymer Battery for HEV Utilizing Pack-Level Battery Hardware-in-the-Loop-Simulation System

  • Han, Sekyung;Lim, Jawhwan
    • Journal of Electrical Engineering and Technology
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    • v.8 no.6
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    • pp.1431-1438
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    • 2013
  • A pack-level battery hardware-in-the-loop simulation (B-HILS) platform is implemented. It consists of dynamic vehicle models using PSAT and multiple control interfaces including real-time 3D driving and GPS mode. In real-time 3D driving mode, user can drive a virtual vehicle using actual drive equipment such as steering wheel and accelerator to generate the cycle profile of the battery. In GPS mode, actual road traffic and terrain effects can be simulated using GPS data while the trajectory is displayed on Google map. In the latter part of the paper, several performance tests of an actual lithium-polymer battery pack are carried out utilizing the developed system. All experiments are conducted as parts of actual development process of a commercial battery pack adopting 2nd generation Prius as a target vehicle model. Through the experiments, the low temperature performance and fuel efficiency of the battery are quantitatively investigated in comparison with the original nickel-metal hydride (NiMH) pack of the Prius.

Ion Conduction Properties of PMMA/PVDF based Polymer Electrolyte for Lithium Polymer Battery (리튬 폴리머전지용 PMMA/PVDF계 고분자 전해질의 이온 전도 특성)

  • 이재안;김종욱;구할본;이헌수;손명모
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.347-350
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    • 2000
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. The temperature dependence of conductivity, impedance spectroscopy and electrochemical properties of PMMA/PVDF electrolytes as a function of a mixed ratio were reported for PMMA/PVDF based polymer electrolyte films, which were prepared by thermal gellification method of preweighed PMMA/PVDF, plasticizer and Li salt. The ion conductivity of PMMA/PVDF electrolytes was 10$\^$-3/S/cm, which may be applicable to a constituent of lithium secondary battery. 5PMMA20PVDFLiC1O$_4$PC$\sub$8/EC$\sub$8/ electrolyte remains stable up to 5V vs. Li/Li$\^$+/. Steady state current method and AC impedance were used for the determination of transference numbers in PMMA/PVDF electrolyte film. The transference number of 5PMMA20PVDFLiC1O$_4$PC$\sub$8/EC$\sub$8/ electrolyte is 0.55.

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A Study on Urethane-Based Gel Polymer Electrolyte for Lithium ion Battery (리튬이온전지용 Urethane기 겔폴리머전해질에 관한 연구)

  • 김현수;김성일;최관영;문성인;김상필
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.12
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    • pp.1033-1038
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    • 2002
  • In this study, urethane acrylate macromer was synthesized and it was used in a gel polymer electrolyte (GPE), and then its electrochemical performances were evaluated. LiCoO$_2$/GPE/graphite cells were Prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor consisting of urethane acrylate (UA), hexanediol dimethacrylate (HDDA) and benzoyl peroxide (BPO) had a low viscosity relatively ionic conductivity of the gel polymer electrolyte with UA at room temperature and -20$\^{C}$ was ca. 4.5 $\times$ 10$\^$-3/S$.$cm$\^$-1/ and 1.7 x 10$\^$-3/ S$.$cm$\^$-1/, respectively GPR was stable electrochemically up to potential of 4.i V vs. Li/Li$\^$+/. LiCoO$_2$/GPE/graphite cells showed good a high-rate and a low-temperature performance.

The Design for Battery Management & Monitoring of Lithium Series (리튬 계열의 배터리 관리 및 모니터링을 위한 설계)

  • Kim, Nam-Sung;Bok, Young-Su
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2010.05a
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    • pp.651-654
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    • 2010
  • Green Growth and green consume culture is the international trend, the importance of Green Car in one of leading electric car, hybrid electric car are easily accessible from the surrounding. In Green Car, the level in research and development of technology to take advantage of the battery is activated beyond the interest. Accordingly, it is needed to manage and monitor the battery in order to use more efficiently and reliably about the secondary battery of lithium series. In this paper, we propose the design and how to take advantage of technology for managing and monitoring of lithium series battery.

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Charge/discharge Properties As a Function of Synthetic Conditions of $LiMnO_2$ for Lithium Polymer Batteries (리튬 폴리머 전지용 $LiMnO_2$의 합성조건에 따른 충방전 특성)

  • Cho, Young-Jai;Kim, Jong-Uk;Park, Gye-Choon;Wee, Sung-Dong;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.541-544
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    • 2001
  • Orthorhombic $LiMnO_2$ was synthesized by solid-state reaction using $LiOH{\cdot}H_{2}O$ and $Mn_{2}O_{3}$ as starting material. Its electrochemical properties as cathode in lithium batteries were examined. X-ray diiffraction revealed that the $LiMnO_2$ compound showed a well-defined orthorhombic phase of a space group with Pmnm. The capacity of $LiMnO_2$ agreed well with its specific surface area and grinding treatment was effective in improving cycling performance. For lithium polymer battery applications. the $LiMnO_2$ cell was characterized electrochemically by charge-discharge experiments. And the relationship between the characteristics of powder and electrochemical properties was studied in this research. A maximum discharge capacity of $160-170mAhg^{-1}$ for $LiMnO_2/Li$ cell was achieved.

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Charge/discharge Properties As a Function of Synthetic Conditions of LiMnO$_2$ for Lithium Polymer Batteries (리튬 폴리머 전지용 LiMnO$_2$의 합성조건에 따른 충방전 특성)

  • 조영재;김종욱;박계춘;위성동;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.541-544
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    • 2001
  • Orthorhombic LiMnO$_2$ was synthesized by solid-state reaction using LiOH$.$H$_2$O and Mn$_2$O$_3$ as starting material. Its electrochemical properties as cathode in lithium batteries were examined. X-ray diffraction revealed that the LiMnO$_2$ compound showed a well-defined orthorhombic phase of a space group with Pmnm. The capacity of LiMnO$_2$ agreed well with its specific surface area and grinding treatment was effective in improving cycling performance. For lithium polymer battery applications, the LiMnO$_2$ cell was characterized electrochemically by charge-discharge experiments. And the relationship between the characteristics of powder and electrochemical properties was studied in this research. A maximum discharge capacity of 160-170mAhg$^{-1}$ for LiMnO$_2$/Li cell was achieved

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The Polyaniline Electrode Doped with Li Salt and Protonic Acid in Lithium Secondary Battery

  • Ryu, Kwang-Sun;Kim, Kwang-Man;Hong, Young-Sik;Park, Yong-Joon;Jang, Soon-Ho
    • Bulletin of the Korean Chemical Society
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    • v.23 no.8
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    • pp.1144-1148
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    • 2002
  • We prepared the polyaniline (Pani) film and powder by chemical polymerization and doping with different dopants and also investigated the capability of Li//polyaniline cells after assembling. The oxidation/reduction potentials and electrochemical reaction of Li//polyaniline cells were tested by cyclic voltammetry technique. The Li//Pani-HCl cells with 10% and 20% conductors show a little larger specific discharge capacities than that without conductor. The highest discharge capacity of almost 50 mAh/g at 100th cycle is also achieved. However, Li//Pani-LiPF6 with 20% conductor shows a remarkable performance of ~90 mAh/g at 100th cycle. This is feasible value for using as the positive electrode material of lithium ion secondary batteries. It is also proved that the powder type electrode of Pani is better to use than the film type one to improve the specific discharge capacity and its stability with cycle.

Effect of Poly(ethylene glycol) dimethyl ether Plasticizer on Ionic Conductivity of Cross-Linked Poly[siloxane-g-oligo(ethylene oxide)] Solid Polymer Electrolytes

  • Kang, Yongku;Seo, Yeon-Ho;Kim, Dong-Wook;Lee, Chang-Jin
    • Macromolecular Research
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    • v.12 no.5
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    • pp.431-436
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    • 2004
  • Cross-linked network solid polymer electrolytes were prepared by means of in situ hydrosilylation between poly[hydromethylslioxane-g-oligo(ethylene oxide)] and diallyl or triallyl group-containing poly(ethylene glycols). The conductivities of the resulting polymer electrolytes were greatly enhanced upon the addition of poly(ethylene glycol) dimethyl ether (PEGDME) as an ion-conducting plasticizer. Conductivities of the cross-linked polymer electrolytes were more dependent on the molecular weight of PEGDME than on the cross-linkers. The maximum conductivity was found to be 5.6${\times}$10$\^$-4/ S/cm at 30$^{\circ}C$ for the sample containing 75 wt% of PEGDME (M$\_$n/ =400). These electrolytes exhibited electrochemical stability up to 4.5 V against the lithium reference electrode. We observed reversible electrochemical plating/stripping of lithium on the nickel electrode.