• Title/Summary/Keyword: Lithium molten salt

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Analysis of AM and AEM Oxides Behavior in a SF Electrolytic Reduction Process (사용후핵연료 전기환원 공정에서의 알카리, 알카리토 금속 산화물들의 거동 분석)

  • 박병흥;강대승;서중석;박성원
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.268-277
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    • 2004
  • process (ACP), electrochemical properties of high heat-generating alkali and alkali earth oxides in molten salt were measured and the behavior of those elements were analyzed. The reduction potentials of Cs, Sr, and Ba in a molten LiCl-$Li_2O$ system were more cathodic than that of Li and closely located one another. Thus, it is expected that the alkali and alkali earth would not hinder the reaction mechanism which is via lithium reduction. Alkali and alkali earth metals are likely to recycle into molten salt when the process is operated beyond metal reduction potentials and the effect of electric current on the mass transport is also determined by measuring the metal concentrations in the molten salt phase at different current conditions.

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Research Review of Sodium and Sodium Ion Battery (나트륨을 활용한 이차전지 연구동향)

  • Ryu, Cheol-Hwi;Kang, Seong-Gu;Kim, Jin-Bae;Hwang, Gab-Jin
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.1
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    • pp.54-63
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    • 2015
  • The secondary battery using sodium is investigating as one of power storage system and power in electric vehicles. The secondary battery using sodium as a sodium battery and sodium ion battery had merits such as a abundant resources, high energy density and safety. Sodium battery (sodium molten salt battery) is operated at lower temperature ($100^{\circ}C$) compared to NAS and ZEBRA battery ($300{\sim}350^{\circ}C$). Sodium ion battery is investigating as one of the post lithium ion battery. In this paper, it is explained for the principle and recent research trends in sodium molten salt and sodium ion battery.

Dissolution of degummed Antheraea yamamai silkworm cocoon

  • Jo, You-Young;Bae, Sung Min;Kweon, HaeYong
    • International Journal of Industrial Entomology and Biomaterials
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    • v.34 no.1
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    • pp.6-10
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    • 2017
  • Dissolution of Antheraea yamamai silkworm cocoon was carried out in various solvent systems with various dissolving conditions including dissolution salts, salt concentration, dissolving temperature, and time. General chaotropic salt for Bombyx mori silk fibroin does not work for A. yamamai silkworm cocoon. Lithium bromide 9.3 M at $100^{\circ}C$ also does not work to dissolve wild silkworm cocoon. However, 9 M of lithium thiocyanate treatment at $100^{\circ}C$ induced 100% dissolution of wild silkworm cocoon. But it could not be dissolved lower than $60^{\circ}C$. Like lithium thiocyanate, less than $60^{\circ}C$ treatment with molten calcium nitrate 4 hydrate could not dissolve wild silkworm cocoon. As the dissolution temperature increased up to $100^{\circ}C$, the solubility of wild one was reached over 90%. SDS-PAGE showed broad tailing stream pattern that means the molecule of wild silk was depolymerized with dissolution temperature and time. From the above results, the best chaotropic salt for A.yamamai silkworm cocoon is calcium nitrate 4 hydrate.

SEPARATION OF STRONTIUM AND CESIUM FROM TERNARY AND QUATERNARY LITHIUM CHLORIDE-POTASSIUM CHLORIDE SALTS VIA MELT CRYSTALLIZATION

  • WILLIAMS, AMMON N.;PACK, MICHAEL;PHONGIKAROON, SUPATHORN
    • Nuclear Engineering and Technology
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    • v.47 no.7
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    • pp.867-874
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    • 2015
  • Separation of cesium chloride (CsCl) and strontium chloride ($SrCl_2$) from the lithium chloride-potassium chloride (LiCl-KCl) salt was studied using a melt crystallization process similar to the reverse vertical Bridgeman growth technique. A ternary $SrCl_2-LiCl-KCl$ salt was explored at similar growth rates (1.8-5 mm/h) and compared with CsCl ternary results to identify similarities. Quaternary experiments were also conducted and compared with the ternary cases to identify trends and possible limitations to the separations process. In the ternary case, as much as 68% of the total salt could be recycled per batch process. In the quaternary experiments, separation of Cs and Sr was nearly identical at the slower rates; however, as the growth rate increased, $SrCl_2$ separated more easily than CsCl. The quaternary results show less separation and rate dependence than in both ternary cases. As an estimated result, only 51% of the total salt could be recycled per batch. Furthermore, two models have been explored to further understand the growth process and separation. A comparison of the experimental and modeling results reveals that the nonmixed model fits reasonably well with the ternary and quaternary data sets. A dimensional analysis was performed and a correlation was identified to semipredict the segregation coefficient.