• 제목/요약/키워드: Lithium molten salt

검색결과 43건 처리시간 0.042초

사용후핵연료 전기환원 공정에서의 알카리, 알카리토 금속 산화물들의 거동 분석 (Analysis of AM and AEM Oxides Behavior in a SF Electrolytic Reduction Process)

  • 박병흥;강대승;서중석;박성원
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2004년도 학술논문집
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    • pp.268-277
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    • 2004
  • 사용후핵연료 차세대 관리공정의 주된 단위 공정인 전기 환원에 의한 금속 전환 공정에서의 핵종 거동 및 분포에 관한 기초 연구의 일환으로 고방열성 핵종인 알카리, 알카리토 금속 산화물들의 고온 용융염에서의 전기 화학적 특성을 측정 분석함으로서 전기 환원 공정에서의 거동을 예상하였다. LiCl-$Li_2O$ 용융염계에서 Cs, Sr 및 Ba은 Li 보다 높은 진위에서 환원되며 환원 전위는 서로 근접해 있는 것으로 측정되었다. 이에 따라 사용후핵연료의 전기 환원 과정에 Li 환원을 매개로 한 반응 메카니즘에 저해를 일으키지 않을 것으로 예측되었다. 알카리, 알카리토 금속의 환원조건에서 공정이 운전될 경우 자유에너지 변화의 계산을 통해 알자리, 알카리토 금속이 용융염으로 재순환됨을 확인 하였으며 전류 범위에 따른 금속 원소의 농도 변화를 측정하여 알카리, 알카리토 금속의 물질 전달에 대한 전류의 영향을 평가하였다.

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나트륨을 활용한 이차전지 연구동향 (Research Review of Sodium and Sodium Ion Battery)

  • 유철휘;강성구;김진배;황갑진
    • 한국수소및신에너지학회논문집
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    • 제26권1호
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    • pp.54-63
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    • 2015
  • The secondary battery using sodium is investigating as one of power storage system and power in electric vehicles. The secondary battery using sodium as a sodium battery and sodium ion battery had merits such as a abundant resources, high energy density and safety. Sodium battery (sodium molten salt battery) is operated at lower temperature ($100^{\circ}C$) compared to NAS and ZEBRA battery ($300{\sim}350^{\circ}C$). Sodium ion battery is investigating as one of the post lithium ion battery. In this paper, it is explained for the principle and recent research trends in sodium molten salt and sodium ion battery.

Dissolution of degummed Antheraea yamamai silkworm cocoon

  • Jo, You-Young;Bae, Sung Min;Kweon, HaeYong
    • International Journal of Industrial Entomology and Biomaterials
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    • 제34권1호
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    • pp.6-10
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    • 2017
  • Dissolution of Antheraea yamamai silkworm cocoon was carried out in various solvent systems with various dissolving conditions including dissolution salts, salt concentration, dissolving temperature, and time. General chaotropic salt for Bombyx mori silk fibroin does not work for A. yamamai silkworm cocoon. Lithium bromide 9.3 M at $100^{\circ}C$ also does not work to dissolve wild silkworm cocoon. However, 9 M of lithium thiocyanate treatment at $100^{\circ}C$ induced 100% dissolution of wild silkworm cocoon. But it could not be dissolved lower than $60^{\circ}C$. Like lithium thiocyanate, less than $60^{\circ}C$ treatment with molten calcium nitrate 4 hydrate could not dissolve wild silkworm cocoon. As the dissolution temperature increased up to $100^{\circ}C$, the solubility of wild one was reached over 90%. SDS-PAGE showed broad tailing stream pattern that means the molecule of wild silk was depolymerized with dissolution temperature and time. From the above results, the best chaotropic salt for A.yamamai silkworm cocoon is calcium nitrate 4 hydrate.

SEPARATION OF STRONTIUM AND CESIUM FROM TERNARY AND QUATERNARY LITHIUM CHLORIDE-POTASSIUM CHLORIDE SALTS VIA MELT CRYSTALLIZATION

  • WILLIAMS, AMMON N.;PACK, MICHAEL;PHONGIKAROON, SUPATHORN
    • Nuclear Engineering and Technology
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    • 제47권7호
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    • pp.867-874
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    • 2015
  • Separation of cesium chloride (CsCl) and strontium chloride ($SrCl_2$) from the lithium chloride-potassium chloride (LiCl-KCl) salt was studied using a melt crystallization process similar to the reverse vertical Bridgeman growth technique. A ternary $SrCl_2-LiCl-KCl$ salt was explored at similar growth rates (1.8-5 mm/h) and compared with CsCl ternary results to identify similarities. Quaternary experiments were also conducted and compared with the ternary cases to identify trends and possible limitations to the separations process. In the ternary case, as much as 68% of the total salt could be recycled per batch process. In the quaternary experiments, separation of Cs and Sr was nearly identical at the slower rates; however, as the growth rate increased, $SrCl_2$ separated more easily than CsCl. The quaternary results show less separation and rate dependence than in both ternary cases. As an estimated result, only 51% of the total salt could be recycled per batch. Furthermore, two models have been explored to further understand the growth process and separation. A comparison of the experimental and modeling results reveals that the nonmixed model fits reasonably well with the ternary and quaternary data sets. A dimensional analysis was performed and a correlation was identified to semipredict the segregation coefficient.