• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.35 no.6
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• pp.631-638
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• 2022

Microgrid, which enables the production and consumption of electricity to be done independently on a small scale, has been studied on one of the solutions of reinforcement for flexibility of electronic system. This study examined the application effect of new microgrid by applying hybrid battery in electric power storage device. We designed the system to highlight the advantage of each battery and complement the disadvantage by using hybrid system with Lithium-ion battery and interval Redox flow battery. It runs with lithium-ion battery during the initial startup while the Redox flow battery operates for a long time at the end of excessive period, and it enables a discharge of Lithium-ion and Redox flow battery at the same time when the load has a large output. We chose Maldives as a subject of this study for organizing and optimizing independent microgrid. Maldives is the country to accomplish 100% domestic electricity in South Asia, but the whole electric power is supplied through diesel generation imported fossil fuel. We organized and optimized microgrid for energy independence on Malahini island to solve Maldives energy cost problem and global energy environment matters. We analyzed the daily power supply and accumulated the power supply from September 18, 2018~February 11, 2019. The accumulated power supply was about 120.4 MWh and the daily power supply was about 800~1000 kWh. Based on the collected information, we divided the cases into three models which are only diesel generator, solar generator as well as diesel generator, and solar+ESS+diesel generator. We analyzed the amount of oil consumption compared to the cost of construction and power output. The result showed that solar+ESS+diesel generator was most economically feasible. As well, we obtained that our considering hybrid battery system reduced the fuel consumption for diesel power generation about 10~15%.

• Journal of Electrochemical Science and Technology
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• v.11 no.1
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• pp.1-13
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• 2020

As research on secondary batteries becomes important, interest in analytical methods to examine the condition of secondary batteries is also increasing. Among these methods, the electrochemical impedance spectroscopy (EIS) method is one of the most attractive diagnostic techniques due to its convenience, quickness, accuracy, and low cost. However, since the obtained spectra are complicated signals representing several impedance elements, it is necessary to understand the whole electrochemical environment for a meaningful analysis. Based on the understanding of the whole system, the circuit elements constituting the cell can be obtained through construction of a physically sound circuit model. Therefore, this mini-review will explain how to construct a physically sound circuit model according to the characteristics of the battery cell system and then introduce the relationship between the obtained resistances of the bulk (R_b), charge transfer reaction (R_ct), interface layer (R_SEI), diffusion process (W) and battery characteristics, such as the state of charge (SOC), temperature, and state of health (SOH).

• Journal of the Korea Institute of Military Science and Technology
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• v.14 no.4
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• pp.732-739
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• 2011

A fuel cell/secondary battery hybrid power generation system could extend well beyond the efficiency and interoperability of the conventional diesel generator. The suggested power source system consists of 2.3 kW class PEMFC, 100 Ah lithium polymer battery, and two DC/DC converters by serial connection type. It was known that interoperability of sub-systems is the key factor for stable and optimal control of the hybrid power generation system. The modeling and simulation methods have been proposed to reduce the number of configurations and performance tests for components selection and select the optimized control condition of the power generation system. The control model for power source system is implemented based on the empirical formulation and carried out in the Matlab/Simulink environment. The results show that the simulation can be used to establish the algorism of prototype and increase the durability of the power source system.

• Bulletin of the Korean Chemical Society
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• v.32 no.3
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• pp.836-840
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• 2011

This study examines the effects of a carbon coating on the electrochemical performances of $LiFePO_4$. The results show that the capacity of bare $LiFePO_4$ decreased sharply, whereas the $LiFePO_4$/C shows a well maintained initial capacity. The Li ion diffusivity of the bare and carbon coated $LiFePO_4$ is calculated using cyclic voltammetry (CV) to determine the correlation between the electrochemical performance of $LiFePO_4$ and Li diffusion. The diffusion constants for $LiFePO_4$ and $LiFePO_4$/C measured from CV are $6.56{\times}10^{-16}$ and $2.48{\times}10^{-15}\;cm^2\;s^{-1}$, respectively, indicating considerable increases in diffusivity after modifications. The Li ion diffusivity (DLi) values as a function of the lithium content in the cathode are estimated by electrochemical impedance spectroscopy (EIS). The effects of the carbon coating as well as the mechanisms for the improved electrochemical performances after modification are discussed based on the diffusivity data.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.11a
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• pp.515-515
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• 2007

$LiCoO_2$ powder was synthesized by Sol-Gel method using inorganic materials. The starting materials, $CH_3COOLi^*2H_2O\;and\;Co(CH_3COO)_2{^*}4H_2O$, were mixed in the atomic ratio Li/Co of 1 and dissolved in i-propanol with acetic acid. The solution was dried for gelation, and finally obtained the pre-powder. The pre-powder were studied by thermal analysis. Based on the TGA result, heat treatment was performed at various temperature(500 to $800^{\circ}C$) for 2h in air atmosphere. The crystal structure, morphology, electrochemical property were carried out using XRD, SEM, cyclic voltammetry(CV).

• Journal of Electrochemical Science and Technology
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• v.12 no.1
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• pp.1-20
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• 2021

In-depth knowledge of electrode processes is crucial for determining the electrochemical performance of lithium-ion batteries (LIBs). In particular, the conduction mechanisms of charged species in the electrodes, such as lithium ions (Li+) and electrons, are directly correlated with the performance of the battery because the overall reaction is dependent on the charge transport behavior in the electrodes. Therefore, it is necessary to understand the different electrochemical processes occurring in electrodes in order to elucidate the charge conduction phenomenon. Thus, it is essential to conduct fundamental studies on electrochemical processes to resolve the technical challenges and issues arising during the ionic and electronic conduction. Furthermore, it is also necessary to understand the transport of charged species as well as the predominant factors affecting their transport in electrodes. Based on such in-depth studies, potential approaches can be introduced to enhance the mobility of charged entities, thereby achieving superior battery performances. A clear understanding of the conduction mechanism inside electrodes can help overcome challenges associated with the rapid movement of charged species and provide a practical guideline for the development of advanced materials suitable for high-performance LIBs.

• Journal of IKEEE
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• v.27 no.4
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• pp.477-485
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• 2023

In this paper, the effect of AC ripple on the lifetime of lithium-ion batteries is experimentally analyzed. Bidirectional power conversion system(PCS) is used to increase the efficiency of energy storage systems (ESS). When connected to the grid, a current ripple with a frequency twice the grid frequency is applied to the battery due to its structure. Therefore, to analyze the effect of AC ripple on Li-ion battery aging, cycle life test are performed by applying charge/discharge profiles of DC current and DC+AC current ripple specifications. Based on the experimental results, direct current internal resistance (DCIR), incremental capacitance (IC), and surface temperature were analyzed. As a result, it is confirmed that AC ripple does not directly affect degradation and that battery degradation slows down after a certain cycle. These results can serve as a guideline for optimizing filters to reduce ripple on the battery side in applications where AC ripple occurs.

• Journal of Power System Engineering
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• v.17 no.1
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• pp.110-115
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• 2013

The electrochemical performance and microstructure of Al-Si, Al-Si/C was investigated as anode for lithium ion battery. The Al-Si nano composite with 5 : 1 at% ratio was prepared by arc-discharge nano powder process. However, some of problem is occurred, when Al nano composite was synthesized by this manufacturing. The oxidation film is generated around Al-Si particles for passivating processing in the manufacture. The oxidation film interrupts electrical chemistry reaction during lithium ion insertion/extraction for charge and discharge. Because of the existence the oxidation film, Al-Si first cycle capacity is very lower than other examples. Therefore, carbon synthsized by glucose ($C_6H_{12}O_6$) was conducted to remove the oxidation film covered on the composite. The results showed that the first discharge cycle capacity of Al-Si/C is improved to 113mAh/g comparing with Al-Si (18.6mAh/g). Furthermore, XRD data and TEM images indicate that $Al_4C_3$ crystalline exist in Al-Si/C composite. In addition the Si-Al anode material, in which silicon is more contained was tested by same method as above, it was investigated to check the anode capacity and morphology properties in accordance with changing content of silicon, Si-Al anode has much higher initial discharge capacity(about 500mAh/g) than anode materials based on Aluminum as well as the morphology properties is also very different with the anode based Aluminum.

• Transactions of the Korean hydrogen and new energy society
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• v.33 no.5
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• pp.574-582
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• 2022

A lithium-ion battery exhibits high energy density but has many limitations due to safety issues. Currently, as a solution for this, research on solid state batteries is attracting attention and is actively being conducted. Among the solid electrolytes, sulfide-based solid electrolytes are receiving much attention with high ion conductivity, but there is a limit to commercialization due to the relatively high price of lithium sulfide, which is a precursor material. This study focused on the possibility of relatively inexpensive and light lithium hydride and conducted an experiment on it. In order to analyze the characteristics of LiAlH₄, ion conductivity and thermal stability were measured, and a composites mixed with PVDF, a representative polymer electrolyte, was synthesized to confirm a change in characteristics. And metallurgical changes in the material were performed through XRD, SEM, and BET analysis, and ion conductivity and thermal stability were measured by EIS and LFA methods. As a result, Li₃AlH₆ having ion conductivity higher than LiAlH₄ is formed by the synthesis of composite materials, and thus ion conductivity is slightly improved, but thermal stability is rapidly degraded due to structural irregularity.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.53 no.2
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• pp.53-61
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• 2004

Characteristics of half cells of graphite/lithium and LiCoO$_2$/lithium, and full cells of graphite/LiCoO$_2$/ were analyzed by the use of GISOC(the gradual increasing of the state of charge). GISOC analyses generated IIE(the initial intercalation efficiency), which represents lithium intercalation property of the electrode material, and IIC$_{s}$(the initial irreversible capacity by the surface), which represents irreversible reaction between the electrode surface and electrolyte. Linear-fit range of graphite and LiCo/O$_2$electrodes were respectively 370 and 150 mAh/g based on material weight. IIE of graphite and LiCo/O$_2$electrodes were respectively 93∼94 % and 94∼95 %, and IICs of graphite and LiCo/O$_2$electrodes were 15∼17 mAH/g and 0.3∼1.7 mAh/g, respectively. IIE of graphite/LiCo/O$_2$full cell for GX25 and DJG311 as graphite showed 89∼90 %, which IIE value was lower than IIE of half cell of the cathode and the anode. Parameters of IIE and IIC$_{s}$ can also be used to represent not only half cell but also full cell. The characteristics of the full cell can be simulated through the correlative interpretation of potential profile, IIE, and IIC$_{s}$ of half cells.cells.