• Title/Summary/Keyword: Liquids

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A Study on Surface Properties of Mechanical Interfacial Behavior of DGEBA/PMR-15 Blends (DGEBA/PMR-15 블렌드계의 표면특성 변화가 기계적 계면특성에 미지는 영향)

  • Park, Soo-Jin;Lee, Hwa-Young;Han, Mijeong;Hong, Sung-Kwon
    • Journal of Adhesion and Interface
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    • v.4 no.1
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    • pp.1-8
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    • 2003
  • In this work, the effect of PMR-15 content on the variation of surface free energy of the DGEBA/PMR-15 blend system was investigated in terms of contact angles and mechanical interfacial tests. Based on FT-IR result of the blend system. C=O (1,772, $1,778cm^{-1}$) and C-N ($1,372cm^{-1}$) peaks appeared with imidization of PMR-15 and -OH ($3,500cm^{-1}$) peak showed broadly at 10 phr of PMR-15 by ring-opening of epoxy. Contact angle measurements were performed by using deionized water and diiodomethane as testing liquids. As a result, the surface free energy of the blends gave a maximum value at 10 phr of PMR-15, due to the significant increasing of specific component. The mechanical interfacial properties measured from the critical stress intensity factor ($K_{IC}$) and the critical strain energy release rate ($G_{IC}$) showed a similar behavior with the results of surface energetics. This behavior was probably attributed to The improving of the interfacial adhesion between intermolecules, resulting from increasing the hydrogen bondings of the blends.

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Quality Changes in Peeled Lotus Roots Immersed in Electrolyzed Water Prior to Wrap- and Vacuum-Packaging (전기분해수 침지처리 박피연근의 랩 및 진공포장 저장 중의 품질변화)

  • Park, Kee-Jai;Jeong, Jin-Woong;Lim, Jeong-Ho;Kim, Bum-Kun;Jeong, Seong-Won
    • Food Science and Preservation
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    • v.15 no.5
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    • pp.622-629
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    • 2008
  • This study investigated changes in quality characteristics of wrap- and vacuum-packaged peeled lotus roots treated with strong acidic electrolyzed acid water (SAEW pH 2.58, ORP 1,128 mV, HClO 105.0 ppm) or low alkaline electrolyzed water (LAEW pH 8.56, ORP 660 mV, HClO 73.8 ppm) as immersion liquids prior to packaging and storage at 5C. Immersion of peeled lotus roots in SAEW and LAEW reduced initial microbial load by about 1 log compared to treatment with tap water (TW). Hardness differences on storage were observed. However, reduction in PPO activity by electrolyzed water was not reproducible. Changes in Hunter's color value and the color difference value ($\Delta$) of peeled lotus roots immersed in 0.5% (w/v) sodium metabisulfite (SMS) and electrolyzed water were smaller than those of roots treated with TW prior to storage. Sensory characteristics measured during storage were best-preserved in lotus roots previously immersed in 0.5% (w/v) SMS or electrolyzed water, compared to TW. Immersionin electrolyzed water and vacuum packaging preserves the quality of peeled lotus roots in terms of microbial, visual, and sensory aspects, at levels comparable to those offered by storage after treatment with 0.5% (w/v) SMS.

Optimum Geometry of Glass Lined HOMEBASE Impeller for Gas-Liquid System of Low Viscosity Liquid (저점도 액 통기 교반용 글라스라이닝 홈베이스 임펠러의 최적 형상)

  • Koh, Seung-Tae
    • Korean Chemical Engineering Research
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    • v.59 no.4
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    • pp.542-547
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    • 2021
  • Glass lined impellers are corrosion resistant to most chemicals, including strong acids, and also have a smooth, non-stick surface, easy to clean and free from impurities in the process. Glass lined home base impeller is a multi-purpose impeller designed to stir a wide viscosity range of liquids from low viscosity fluids to high viscosity fluids, among others, cell culture, yeast culture, and beer fermentation pots, especially used for air-water system breathable stirring. The glass lining for HB impellers, which are simple in structure and competitive in performance, is essential to have upper and lower division in order to make the joint area between the impeller and shaft as small as possible. The upper and lower division of the impeller hardly affects the mixing performance, but the aeration performance. In this study, in order to optimize the shape of the Glass Lining HB impeller, a study was conducted on the effect of the angle between the upper and lower impellers, the clearance between the impellers, and the number of baffles on the aeration power. The optimal shape and baffle plate conditions for the Glass lined HB impeller were derived through the study results that the angle and the clearance between the upper and lower impellers decreased the ration of the power consumption with aeration Pg and that without aeration P0, Pg/P0.

Assessment of the Risks of Fire and Explosion through the Spontaneous Ignition Temperature and Activation Energy of Sesame Seed Oil Cakes (참깻묵의 자연발화온도와 활성화 에너지를 통한 화재 및 폭발의 위험성 평가)

  • Byun, Sung-Ho;Choi, Yu-Jung;Yoo, Doo-Yeol;Kim, Kyoung-Su;Oh, Jae-Geun;Moon, Byung-Seon;Choi, Jae-Wook
    • Korean Chemical Engineering Research
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    • v.59 no.2
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    • pp.225-231
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    • 2021
  • Sesame seed oil cakes are classified as the animal or plant origin among the flammable liquids, and the fire occurs due to the spontaneous ignition through the accumulation of heat during the storage of residues after the extraction of sesame oil. In order to elucidate the cause of the spontaneous ignition of sesame seed oil cakes, the thickness (3 cm, 5 cm, 7 cm and 14 cm) of the sample container was varied, and the spontaneous ignition temperature was measured depending on the storage volume. Thus, the spontaneous ignition temperature was measured to be 180 ℃ at the thickness of 3 cm, 160 ℃ at 5 cm, 145 ℃ at 7 cm and 130 ℃ at 14 cm. As the thickness of the sample container increased, the critical ignition temperature decreased, and the induction time to spontaneous ignition and the time to reach the maximum temperature became longer. Furthermore, the apparent activation energy by the critical ignition temperature, which is the average temperature of ignition and non-ignition, was 97.10 [kJ/mol]. With these data, ignition characteristics of sesame seed oil cakes were determined.

Effect of Critical Cooling Rate on the Formation of Intermetallic Phase During Rapid Solidification of FeNbHfBPC Alloy

  • Kim, Song-Yi;Oh, Hye-Ryeong;Lee, A-Young;Jang, Haneul;Lee, Seok-Jae;Kim, Hwi-Jun;Lee, Min-Ha
    • Journal of Korea Foundry Society
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    • v.41 no.3
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    • pp.235-240
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    • 2021
  • We present the effect of the critical cooling rate during rapid solidification on the nucleation of precipitates in an Fe75B13P5Nb2Hf1C4 (at.%) alloy. The thermophysical properties of the rapidly solidified Fe75B13P5Nb2Hf1C4 liquids, which were obtained at various cooling rates with various sizes of gas-atomized powder during a high-pressure inert gas-atomization process, were evaluated. The cooling rate of the small-particle powder (≤20 ㎛) was 8.4×105 K/s, which was 13.5 times faster than that of the large-particle powder (20 to 45 mm; 6.2×104 K/s) under an atomized temperature. A thermodynamic calculation model used to predict the nucleation of the precipitates was confirmed by the microstructural observation of MC-type carbide in the Fe75B13P5Nb2Hf1C4 alloy. The primary carbide phase was only formed in the large-particle gas-atomized powder obtained during solidification at a slow cooling rate compared to that of the small-particle powder.

A study of /l/ velarization in American English based on the Buckeye Corpus (벅아이 코퍼스를 이용한 미국 영어의 /l/ 연구개음화 연구)

  • Sa, Jae-Jin
    • Phonetics and Speech Sciences
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    • v.13 no.2
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    • pp.19-25
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    • 2021
  • It has been widely recognized that there are two varieties of lateral liquid /l/, which are light /l/ (a non-velarized allophone) and dark /l/ (a velarized allophone). However, this categorical view has been challenged in recent studies, both on articulatory and acoustic aspects. The purpose of this study is to investigate whether to consider /l/ velarization as a continuum in American English and provide supporting data. A spontaneous American English speech database called the Buckeye Speech Corpus was used for the material. The formant frequencies of /l/ in each syllable position were measured and analyzed statistically. The formant frequencies of /l/ in each syllable position, especially F2 values, were significantly different from each other. The results showed that there were other significantly different varieties of /l/ in American English, which support the continuum view on /l/ velarization. Regarding the effect of the adjacent vowel, the backness of the adjacent vowels was shown to affect the degree of /l/ velarization, regardless of the syllable position of the lateral liquid. This result will help provide a solid ground for the continuum view.

Optimization of Submerged Culture Conditions for Protease Production and Its Enzymatic Properties (Protease 생산을 위한 최적 배양조건 및 생산된 Protease의 특성)

  • Cho, Hee-Yeon;Cho, Nam-Seok
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.5
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    • pp.12-19
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    • 2004
  • This study was performed to investigate the optimum condition of protease production from submerged culture of oak mushroom (Lentinula edodes, Sanlim No. 5) and its enzymatic features. Among several combinations of media, the combination of wheat bran, corn flour, water and corn oil (WB+CF+W+ CO) yielded 84.8 U/g of maximum protease activity. This combination of ingredients, in spite of not being particularly protein-rich in comparison to the other media, allowed for good growth of the fungus and maximal protease production. Comparison of different growth medium liquids indicated that demineralized water afforded the best growth of the fungus and the highest protease activity. Acetate buffer and acidified water negatively affected The protease production peaked around 72 hr of incubation, and decreased thereafter. The molecular weights of produced protease were about 45,000 by Sephadex G-75 chromatography. The pH optimum for protease activity was 4, while maximal activity incubated at 37℃ for 1 hr was observed between pH 4~6. The optimum temperature of this protease was 55℃, and the enzyme was active over a broad temperature range (30~60℃), indicating that this protease would be suitable for a wide range of applications where. different pH and temperature are necessary, such as digestive aids, food industry, beer and tannery industries.

Preparation of Bio-oil from Ginkgo Leaves through Fast Pyrolysis and its Properties (은행잎 바이오매스로부터 급속 열분해를 통한 바이오-오일 생산 및 특성 연구)

  • In-Jun Hwang;Jae-Rak Jeon;Jinsoo Kim;Seung-Soo Kim
    • Clean Technology
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    • v.29 no.3
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    • pp.200-216
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    • 2023
  • Ginkgo leaves are considered waste biomass and can cause problems due to the strong insecticidal actions of ginkgolide A, B, C, and J and bilobalide. However, Ginkgo leaf biomass has high organic matter content that can be converted into fuels and chemicals if suitable technologies can be developed. In this study, the effect of pyrolysis temperature, minimum fluidized velocity, and Ginkgo leaf size on product yields and product properties were systematically analyzed. Fast pyrolysis was conducted in a bubbling fluidized bed reactor at 400 to 550℃ using silica sand as a bed material. The yield of pyrolysis liquids ranged from 33.66 to 40.01 wt%. The CO2 and CO contents were relatively high compared to light hydrocarbon gases because of decarboxylation and decarbonylation during pyrolysis. The CO content increased with the pyrolysis temperature while the CO2 content decreased. When the experiment was conducted at 450℃ with a 3.0×Umf fluidized velocity and a 0.43 to 0.71 mm particle size, the yield was 40.01 wt% and there was a heating value of 30.17 MJ/kg, respectively. The production of various phenol compounds and benzene derivatives in the bio-oil, which contains the high value products, was identified using GC-MS. This study demonstrated that fast pyrolysis is very robust and can be used for converting Ginkgo leaves into fuels and thus has the potential of becoming a method for waste recycling.

Method to Derive the Optimal Vent Position when Flammable Liquid Leaks Based on CFD (CFD 기반 인화성 액체 누출 시 최적의 환기구 배치 도출 방안)

  • Eun-Hee Kim;Seung-Hyo An;Jun-Seo Lee;Byung-Chol Ma
    • Journal of the Korean Institute of Gas
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    • v.28 no.1
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    • pp.11-18
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    • 2024
  • If flammable liquid leaks, vapor evaporated from the pool can cause poisoning or suffocation to workers, leading to secondary accidents such as fires and explosions. To prevent such damage, ventilation facilities shall be installed when designing indoor workplaces. At this time, the behavior varies depending on the characteristics of the leaked chemical, so it is necessary to select a suitable vent location according to the material. Therefore, 3D CFD simulations were introduced to derive optimal vent position and ventilation efficiency was quantitatively evaluated by vent position. At this time, assuming a situation in which flammable liquids leak at indoor workplaces to form pools, the concentration of vapor evaporated from pools was compared to derive the optimal vent position. As a result of research on toluene with high vapor density, ventilation efficiency was confirmed to be the highest at the upper supply-lower exhaust, and it is judged that introducing it can achieve about 3.7 times ventilation effect at the same maintenance cost. Through this study, it is expected that the workplace will be able to secure workers' safety by applying simulation results and installing ventilation ports.

Reliability of a Questionnaire for Evaluation of Dry Mouth Symptoms (구강건조증 증상 평가를 위한 설문지의 신뢰도에 관한 연구)

  • Lee, Jeong-Yun;Lee, Young-Ok;Kho, Hong-Seop
    • Journal of Oral Medicine and Pain
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    • v.30 no.4
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    • pp.383-389
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    • 2005
  • Xerostomia is defined as a subjective complaint of dry mouth that may be perceived when there is insufficient mucosal wetting. However, the diagnosis and treatment of xerostomia is not that simple because of the fact that the subjective awareness of dry mouth is not always correlated with a diminution in the flow of saliva and there is always a difference between individuals in salivary flow rates needed for normal oral function. In the present study, the aim was to develop a questionnaire to evaluate the dry mouth symptoms and to analyze its reliability and usability as a diagnostic and analytic tool for xerostomia. The questionnaire which consists of 6 Visual Analogue Scale(VAS) type questions to evaluate the subjective oral dryness and 4 questions to evaluate behavior to avoid oral dryness was developed and administered twice with 1 week's interval to the healthy 88 young adults without dry mouth symptoms(44 males and 44 females; mean age was $25.6{\pm}3.1$ years in male and $24.3{\pm}2.1$ years in female). The results were as follows. 1 The intraclass correlation coefficients of 6 questions to evaluate the subjective oral dryness were as significantly high as 0.767 for the degree of oral dryness at other times of the day, 0.850 for the amount of saliva in the mouth, and 0.791 for the degree of effect on daily life due to oral dryness and as high as 0.563 for the degree of oral dryness at night or on awakening, 0.674 for the degree of oral dryness during eating, and 0.641 for the degree of difficulty in swallowing foods. 2. Cronbach's alpha value of 6 questions was 0.982. It can be concluded that the series of questions to evaluate the subjective oral dryness has high internal consistency. 3. Cohen's kappa values of 4 questions to evaluate behavior to relieve oral dryness were as significantly high as 0.850 for the frequency of keeping a glass of water at the bedside and as high as 0.506 the frequency of awakening during sleeping due to oral dryness, 0.419 for the frequency of sipping liquids to aid in eating dry foods, and 0.407 for the frequency of using a candy or chewing gum due to oral dryness. From the results, it can be concluded that the questionnaire consisting of 6 VAS type questions to evaluate the subjective oral dryness and 4 questions to evaluate behavior to relieve oral dryness has reliability of good to excellent level, and that the series of 6 VAS type questions has significantly high internal consistency to evaluate the subjective oral dryness.