• Bulletin of the Korean Chemical Society
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• 제19권10호
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• pp.1047-1054
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• 1998

We present the results of molecular dynamics simulations for three different systems of bilayers of long-chain alkyl thiol [S(CH2)15CH3] molecules on an solid-solid interface using the extended collapsed atom model for the chain-molecule. It is found that there exist two possible transitions: a continuous transition characterized by a change in molecular interaction between sites of different chain molecules with increasing area per molecule and a sudden transition from an ordered lattice-like state to a liquid-like state due to the lack of interactions between sites of chain molecules on different surfaces with increasing distance between two solid surfaces. The third system displays a smooth change in probability distribution characterized by the increment of gauche structure in the near-tail part of the chain with increasing area per molecule. The analyses of energetic results and chain conformation results demonstrate the characteristic change of chain structure of each system.

• Wind and Structures
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• 제36권2호
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• pp.91-103
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• 2023

Tuned liquid dampers (TLDs) are increasingly being used as efficient dynamic vibration absorbers to mitigate wind-induced vibration in super high-rise buildings. However, the damping characteristics of screens and the control effectiveness of actual structures must be investigated to improve the reliability of TLDs in engineering applications. In this study, a numerical TLD model is developed using computational fluid dynamics (CFD) and a simulation method for achieving the coupled vibration of the structure and TLD is proposed. The numerical results are verified using shaking table tests, and the effects of the solidity ratio and screen position on the TLD damping ratios are investigated. The TLD control effectiveness is obtained by simulating the wind-induced vibration response of a full-scale structure-TLD system to determine the optimal screen solidity ratio. The effects of the structural frequency, damping ratio, and wind load amplitude on the TLD performance are further analyzed. The TLD damping ratio increases nonlinearly with the solidity ratio, and it increases with the screens towards the tank center and then decreases slightly owing to the hydrodynamic interaction between screens. Full-scale coupled simulations demonstrated that the optimal TLD control effectiveness was achieved when the solidity ratio was 0.46. In addition, structural frequency shifts can significantly weaken the TLD performance. The control effectiveness decreases with an increase in the structural damping ratio, and is insensitive to the wind load amplitude within a certain range, implying that the TLD has a stable damping performance over a range of wind speed variations.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2241-2247
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• 2007

A new series of chiral bent-shaped liquid crystals with an asymmetric central core based on 1,6- dihydroxynaphthalene and chiral terminal chain prepared from (S)-(?)-2-methyl-1-butanol, 1,6-naphthalene bis[4-(4-alkoxyphenyliminomethyl)]benzoates [N(1,6)-n-O-PIMB(n-2)*-(n-4)O (n = 8-11)] were synthesized. Their mesomorphic properties and phase structures were investigated by means of electro-optical, polarization reversal current, and second harmonic generation measurements in order to confirm the relationship between the molecular structure and phase structure. All odd n (n = 9 and 11) compounds, N(1,6)-9-O-PIMB7*-5O and N(1,6)-11-O-PIMB9*-7O exhibit antiferroelectric phase, whereas even n (n = 8 and 10) compounds was flexible, N(1,6)-10-O-PIMB8*-6O exhibits the ferroelectric phase but N(1,6)-8-O-PIMB6*-4O exhibits the antiferroelectric phase. These results come from the decrease of the closed packing efficiency within a layer and the lack of uniform interlayer interaction between adjacent layers, which were caused by the asymmetrical naphthalene central core. Thus, we concluded that the structure of central core as well as the terminal chain plays an important role for the emergence of particular polar ordering in phase structures.

• 대한토목학회논문집
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• 제14권5호
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• pp.1033-1042
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• 1994

2차원 경계요소-유한요소 연계법을 사용하여 구형 수조구조물의 동적거동 특성을 파악하였다. 비점성, 비압축성 이상유체의 운동은 경계요소법으로 모델링하였으며 구조물의 운동은 유한요소법으로 모델링하였다. 경계요소법의 적용시 Singularity를 소거한 경계적분식을 사용하였다. 유체와 구조물의 경계면에서 적합조건과 평형조건을 만족시킴으로써 경계요소와 유한요소를 연계하였다. 유체-구조물 상호작용의 영향은 유체의 부가질량행렬과 유체 유동에 의한 강성행렬로 연계된 유체-구조물계에 반영된다. 연계된 유체-구조물계의 고유치 문제로부터 수조구조물의 고유진동수외 고유모드를 구하였으며 수평 및 수직 자바운동에 의하여 수조구조물에 발생하는 유체동압력과 자유수면의 유동도 산출하였다.

• 대한화학회지
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• 제32권5호
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• pp.458-463
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• 1988

역상 액체크로마토그래피법으로 페놀류에 대한 분리현상을 용해도파라미터이론에 의해 알아 본 결과 예측한 용리거동이 제한된 범위내에서만 일치하고 있었다. 이 용해도 파라미터이론에 의한 용리현상의 설명은 실제 실험의 결과와 상당히 상이하게 나타났고 많은 예외가 있었다. 그러므로 새로운 용질-용매상호작용파라미터 ${\delta}_{im}$ 을 첨가하여 실제 실험값에 가까운 용해도파라미터 이론식으로 수정하였다. 이 새로운 용질-용매상호작용파라미터, ${\delta}_{im}$ 는 용매의 종류, 용매분율과 용질의 구조에 의존하고 있으며 이 파라미터, ${\delta}_{im}$와 혼합이동상의 용해도파라미터, ${\delta}_{im}$ 와는 직선의 관계가 있었다. 이것은 머무름거동을 예측하는데 이전의 Schoenmakers의 식보다 더 좋은 결과로 나타났다.

• Structural Engineering and Mechanics
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• 제68권1호
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• pp.1-15
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• 2018

In ocean industry, free surface type ART (Anti Roll tank) system has been widely used to suppress the roll motion of floating structures. In those, various obstacles have been devised to obtain the sufficient damping and to enhance the controllability of freely rushing water inside the tank. Most of previous researches have paid on the development of simple mathematical formula for coupled ship-ARTs analysis although other numerical and experimental approaches exist. Little attention has been focused on the use of 3D panel method for preliminary design of free surface type ART despite its advantages in computational time and general capacity for hydrodynamic damping estimation. This study aims at developing a potential theory based hydrodynamic code for the analysis of floating structure with baffled ARTs. The sloshing in baffled tanks is modeled through the linear potential theory with FE discretization and it coupled with hydrodynamic equations of floating structures discretized by BEM and FEM, resulting in direct coupled FE-BE formulation. The general capacity of proposed formulation is emphasized through the coupled hydrodynamic analysis of floating structure and sloshing inside baffled ARTs. In addition, the numerical methods for natural sloshing frequency tuning and estimation of hydrodynamic damping ratio of liquid sloshing in baffled tanks undergoing wave exiting loads are developed through the proposed formulation. In numerical examples, effects of natural frequency tuning and baffle ratios on the maximum and significant roll motions are investigated.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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• pp.562-564
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• 2001

Transformation of molecular film occurs only usually in air-water interface, 2 dimensions domain's growth and crash are achieved. Organic matter thin film that accumulate molecular film in archaism board only that consist of growth of domain can understand correct special quality of accumulation film supplying information about fine structure and properties of matter of device observing information and so on that is surface forward player and optic enemy using AFM one of SPM application by nano electronics. The stable images are probably due to a strong interaction between the monolayer film and glass substrate. We are unable to obtain molecule resolution in images of the films but did see a marked contrast between images of the bare substrate and those with the network structure film deposited onto it. Formation that prevent when gas phase state and liquid phase state measure but Could know organic matter that molecules form equal and stable film when molecules were not distributed evenly. and accumulated in solid state only.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 하계학술대회 논문집 C
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• pp.1618-1620
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• 2002

Transformation of molecular film occurs only usually in air-water interface, 2 dimensions domain's growth and crash are achieved. Organic matter thin film that accumulate molecular film in archaism board only that consist of growth of domain can understand correct special quality of accumulation film supplying information about fine structure and properties of matter of device observing information and so on that is surface forward player and optic enemy using AFM one of SPM application by nano electronics. The stable images are probably due to a strong interaction between the monolayer film and glass substrate. We are unable to obtain molecule resolution in images of the films but did see a marked contrast between images of the bare substrate and those with the network structure film deposited onto it. Formation that prevent when gas phase state and liquid phase state measure but Could know organic matter that molecules form equal and stable film when molecules were not distributed evenly, and accumulated in solid state only.

• Journal of Welding and Joining
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• 제33권1호
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• pp.49-53
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• 2015

An experimental study was conducted to investigate the effect of carbon nanotubes on the zinc corrosion resistance of sealing layer formed on the Tungsten Carbide spray coating. Using the nanotubes, a sealing agent in the form of solid-liquid suspensions was made and applied to the surface of spray coating. A series of experiments, consisted of three stages such as preparation of test piece, molten-pot immersion test, and evaluation of micro structure, were undertaken to demonstrate complicated interaction existing between zinc ions and sealing layer containing the nanotubes. Experimental results showed newly developed sealing layer were less susceptible to corrosion and thus coated layer was well protected even in the case of 10 days exposure. Comparison of the micro structure after molten pot test also indicated that carbon nanotubes still remained in the matrix and organized more reliable frame work constituted with boron nitride and chromium compound. It was revealed that carbon nanotubes in the sealing layer played positive role to enhance zinc corrosion resistance in the perspective of both fibrous structure and inherent chemical stability.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집
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• pp.562-564
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• 2001

Transformation of molecular film occurs only usually in air-water interface, 2 dimensions domain's growth and crash are achieved. Organic matter thin film that accumulate molecular film in archaism board only that consist of growth of domain can understand correct special quality of accumulation film supplying information about fine structure and properties of matter of device observing information and so on that is surface forward player and optic enemy using AFM one of SPM application by nano electronics. The stable images are probably due to a strong interaction between the monolayer film and glass substrate. We are unable to obtain molecule resolution in images of the films but did see a marked contrast between images of the bare substrate and those with the network structure film deposited onto it. Formation that prevent when gas phase state and liquid phase state measure but Could know organic matter that molecules form equal and stable film when molecules were not distributed evenly, and accumulated in solid state only.