• Title/Summary/Keyword: Liquid structure

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Hot Fire Tests of the KSR-III Sub.(I) Engines (KSR-III 축소형(I) 엔진의 연소 시험)

  • Kim, Y.H.;Kim, Y.W.;Moon, I.Y.;Ko, Y.S.;Lee, S.Y.;Ryu, C.S.;Seol, W.S.
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.8
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    • pp.120-125
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    • 2002
  • In the preceding tests using the KSR-III Sub.(I) engines, it was observed that the heat resistant capability of the engines was not enough for the mission. So Sub.(I) Mod. engines were designed and tested. The Sub.(I) Mod. engines have three major design parameters - the arrangement of main injectors, the impinging angle of main injectors and thermal barrier coating. More than twenty experiments were carried on to evaluate engine performance and heat resistance capability with respect to design parameters. In this study, the test results are introduced. Analysing the result of Sub.(I) engine tests, it is found that decreasing the impinging angle, adopting the H-type arrangement(rather than radial type arrangement) and adopting the thermal barrier coating can increase heat resistance capacity substantially. Also, engine performance evaluation is conducted using specific impulse and characteristic velocity parameter. The results show that the performance variation is small(about 5%) and the performance is better in the case of radial arrangement. It is suspected that these phenomena are caused by the change of flame structure atomization mixing characteristic of sprays and the distortion of recirculation zone. Also from the low frequency instability point of view, it is observed that reducing the impinging angle and adopting the H type arrangement can increase the instability characteristics.

Conversion of Ginseng Saponin with the Enzyme Produced by Rhizopus sp. (Part 1) Confirmation of Conversion of Ginsenoside- Rb$_1$to Ginsenoside-Rd (Rhizopus sp.가 생산하는 효소에 의한 인삼 Saponin의 전환 (제1보) Ginsenoside-Rb$_1$에서 Ginsenoside-Rd로의 전환확인)

  • 김상달;서정훈
    • Microbiology and Biotechnology Letters
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    • v.10 no.4
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    • pp.267-273
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    • 1982
  • Among 12 kinds of ginsenosides in ginseng saponin, ginsenoside-Rb$_1$was contained the most abundantly. But ginsenoside-Rd which is similar to ginsenoside-Rb$_1$in structure, was known to be superior to ginsenoside-Rb$_1$pharmaceutically. In order to convert ginsenoside-Rb$_1$into ginsenoside-Rd by microbial enzyme treatment, a Rhizopus sp. was selected among various strais of molds found in rotten ginseng roots. Enzyme was prepared from the extract of wheat bran koji culture by ammonium sulfate precipitation (1.0 sat'd) and succeeding ammonium sulfate fractionation method (0.6-0.9 sat'd). For the purpose of use as substrate, saponins were purified by the several purification steps from alcohol extract of red ginseng roots. We obtained the total saponin which was composed of 36.5% of ginsenoside Rb$_1$, 12.2% of ginsenoside-Rd and other ginsenosides. For increase of ginsenoside-Rb$_1$ component ratio, we also obtained further purified ginsenoside-Rb group saponin containing 54.5% of ginsenoside-Rb$_1$, 1.1% of ginsenoside- Rd and other ginsenosides from purified the total saponin. In the enzymatic reaction system including the total saponin or the ginsenoside-Rb group saponin, we confirmed the specific conversion of ginsenoside-Rb$_1$to ginsenoside-Rd proportionally and no change of any other ginsenoside patterns by thin layer chromatography and high performance liquid chromatography.

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Identification of a Bioactive Compound, Violacein, from Microbulbifer sp. Isolated from a Marine Sponge Hymeniacidon sinapium on the West Coast of Korea (한국 서해안에 서식하는 주황해변해면에서 분리된 해양세균 Microbulbifer sp.으로부터 생리활성물질 비올라세인의 규명)

  • Won, Nam-Il;Lee, Ga-Eun;Ko, Keebeom;Oh, Dong-Chan;Na, Yang Ho;Park, Jin-Sook
    • Microbiology and Biotechnology Letters
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    • v.45 no.2
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    • pp.124-132
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    • 2017
  • Microbial secondary metabolites of marine organisms are regarded as major sources of structurally and biologically novel compounds with numerous potential uses. Sponge-microbe associations are among the most interesting sources for exploring bioactive compounds. In this study, the bacterial strain Microbulbifer sp. (127CP7-12) was isolated from the Asian marine sponge Hymeniacidon sinapium collected at an intertidal zone on the west coast of Korea. Cultured bacteria produced a violet pigment, and optimal culture conditions for violet pigment production were investigated. Maximum production of the violet pigment from the strain culture was observed under the conditions of $25^{\circ}C$, pH 6.0, and 3% NaCl. Acetone provided better extraction of the pigment from fermented broth compared with ethanol and methanol. The proposed structure of the major component in the extracted crude pigment was determined via high-performance liquid chromatography, nuclear magnetic resonance, mass spectrometry, and UV spectra analyses, which showed that the metabolite was the promising bioactive compound violacein. This study describes the examination of marine bioactive materials from microbe-engaged metabolites and the ecological implications of the sponge-microbe association in a changing ocean.

Alteration of the Stability in Training Ship Pusan 403 (실습선 부산403호의 복원성 변화)

  • KIM Sam-Kon;KIM Jong-Hwa;CHOE Jong-Hwa;KIM Yeong-Sik
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.18 no.2
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    • pp.94-100
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    • 1985
  • M/S Pusan 403(GT 243, 1000ps) was originally built as a research vessel on skipjack pole and line fishing in 1972. She had begun to serve as a fishing training ship of National Fisheries University of Pusan from 1974, since the interior structure has been remodelled and some weight articles have been removed, her stability is in doubt. The authors carried out an inclining experiment by using two pendulums at fore and aft with two weights on both sides. Each value obtained was compared with the IMO safety code for fishing vessels and safety regulation for fishing vessels of Korea. 1. The GZ value, being 0.207 m under light ship condition and 0.325 m under departure condition with full load, can be assumed as no impediment on her stability, 2. Under the light ship condition, GM decreased by 0.046 m and KG increased by 0.141 m, compared with the values determined at the time of official sea trial. Therefore, no impediment on the stability exists. 3. The GM decreased by 0.163 m and the KG increased by 0.173 m, compared with the values determined at the time of official sea trial. In no consideration of the free surface effects of liquid in the oil and fresh water tanks, no impediment on the stability exists. But, in consideration of the free surface effect, it may be regarded that some impediment exists.

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Fabrication of patterned substrate by wet process for biochip (습식 공정법에 의한 바이오칩 용 패터닝 기판 제조)

  • Kim, Jin-Ho;Lee, Min;Hwang, Jong-Hee;Lim, Tae-Young;Kim, Sae-Hoon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.6
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    • pp.288-292
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    • 2009
  • Hydrophobic/hydrophilic patterned substrates were fabricated on a glass substrate by a liquid phase deposition (LPD) method. Hydrophobic surface was obtained by modifying ZnO thin films with a rough surface using a fluoroalkyltrimethoxysilane (FAS) and hydrophilic surface was prepared by decomposing FAS on an exposed to UV light. The hexagonal ZnO rods were perpendicularly grown by LPD method on glass substrates with a ZnO seed layer. The diameter and thickness of hexagonal ZnO rods were increased as a function of increases of immersion time. The surface morphology, thickness, crystal structure, transmittance and contact angle of prepared ZnO thin films were measured by field emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), UV-visible spectrophotometer (UV-vis) and contact angle measurement. Hydrophilic ZnO thin films with a contact angle of $20^{\circ}{\sim}30^{\circ}$ were changed to a hydrophobic surface with a contact angle of $145^{\circ}{\sim}161^{\circ}$ by a FAS surface treatment. Prepared hydrophobic surface was pattered by an irradiation of UV light using shadow mask with $300\;{\mu}m$ or 3 mm dot size. Finally, the hydrophobic surface exposed to UV light was changed to a hydrophilic surface.

A Study on the Effects of Biodegradation for Organic Soils (유기질토에 대한 생분해처리 효과에 관한 연구)

  • Song, Yeong-U;Park, Jun-Beom;Kim, Hyeong-Seok
    • Geotechnical Engineering
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    • v.14 no.4
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    • pp.151-162
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    • 1998
  • The compressibility and the permeability of organic soil are so high that they cause many engineering problems when constructing a structure on the soil. If the organic content of the soil could be reduced by any applicable engineering technique, the engineering properties of the soils can be improved to some extent. The purpose of this study would thus be focused on how to decrease the amount of organic matters by applying aerobic biodegradation for eliminating post-construction settlement problems. To enhance the aerobic decomposition, oxygen was supplied to the soil samples prepared by the mixture of kaolinite and sawdust as organic matter. The dissolved oxygen and the organic content of the soil samples were measured, in accordance with the passage of time through the bests. As oxygen suppliers, HaOa liquid and pure oxygen gas were compared to meet the requirement of the test purposes. Newly manufactured oedometer with the diameter of 130 mm and the height of 300 mm was used for 100 days to perform the compressibility tests for the soils. Based on the results of this experiment, the oxygen gas-treated samples with nutrient settled 30% more than the samples untreated. This confirmed the efficiency of the aerobic biodegradation. $NaNO_3$ added into the soils as nutrients was proved more effective than $K_2HP0_4$. To confirm the activity of micro-organisms, sodium azide was also added to the soils.

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Preparation of TiO2 Nanoparticles from Titanium Tetraisopropoxide Using an Aerosol Microreactor (에어로졸 마이크로반응기에 의한 Titanium Tetraisopropoxide로부터 TiO2 나노입자 제조)

  • Choi, Jae Gil;Park, Kyun Young
    • Korean Chemical Engineering Research
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    • v.43 no.5
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    • pp.609-615
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    • 2005
  • $TiO_2$ particles, 30-300 nm in diameter, were prepared by thermal decomposition of titanium tetraisopropoxide (TTIP) using an aerosol microreactor, by which about $1{\mu}l$ of the liquid precursor is injected into an evaporator, 1 cc in volume, and vaporized precursor is then transported by nitrogen as a bolus to a tubular reactor 4 mm in diameter and 35 cm in length. Investigated were the effects of the reactor temperature and the concentration of TTIP vapor on the morphology, particle size distribution and crystalline structure of produced $TiO_2$ particles. With TTIP vapor concentration kept constant at 1 mol%, the reactor temperature was varied from 300 to 500 and $700^{\circ}C$. The primary particle size decreased with increasing the temperature, and the size distributions were mono-modal at 300 and $500^{\circ}C$, but bi-modal at $700^{\circ}C$. The TTIP vapor concentration was increased from 1 to 3.5 and 7 mol%, holding the reactor temperature at $700^{\circ}C$. The bi-modal distribution seen at the concentration of 1 mol% disappeared and the number of particles composing an agglomerate increased at the higher concentrations. These effects of the reactor temperature and the precursor concentration were discussed in comparison with experimental results reported earlier.

Progress of Nanofiltration Hollow Fiber Membrane (NF용 중공사 분리막의 발전)

  • Jang, Hanna;Kim, Seongjoong;Lee, Yongtaek;Lee, Kew-Ho
    • Applied Chemistry for Engineering
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    • v.24 no.5
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    • pp.456-470
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    • 2013
  • Hollow-fiber membranes, is one of the new technologies that is growing rapidly in the past few decades. In addition, separation membranes using polymer materials, have attracted attentions in various fields including gas separation, fuel cells, water treatment, wastewater treatment, and organic separation. Nanofiltration (NF) membranes having the separation characteristics in the intermediate range between ultrafiltration and reverse osmosis (RO) membranes for liquid separation, with relatively low investment cost and operating pressure lower than that of RO membranes, have high permeance and rejection performance of multivalent ions as well as organic compounds of molecular weight between $200{\sim}1000gmol^{-1}$. In this paper, we would like to review the research trends on the various structure control and characterization of NF hollow fiber membranes with respect to materials and the methods of preparation (phase inversion method and interfacial polymerization method). Currently, most of NF membranes have been manufactured by plate and frame types or spiral wound types. But hollow fiber types have delayed in commercial products, because of the weak strength when to produce on the basis of the existing materials, therefore the development of new materials or improvement of existing materials will be needed. If improving manufacturing technology is available, hollow fiber types will replace spiral wound types and gradually show a higher market share.

Effect of Surfactant on Reductive Dechlorination of Trichloroethylene by Zero-Valent Iron (양이온-비이온 혼합계면활성제의 첨가가 영가철을 이용한 TCE환원에 미치는 영향)

  • Shin, Min-Chul;Choi, Hyun-Dock;Yang, Jung-Seok;Baek, Ki-Tae
    • Journal of Soil and Groundwater Environment
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    • v.12 no.6
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    • pp.38-45
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    • 2007
  • Trichloroethylene (TCE) is a representative dense non-aqueous phase liquid (DNAPL) and has contaminated substance environments including soil and groundwater due to leakage and careless. DNPAL, has been treated by surfactant-enhanced aquifer remediation (SEAR). After application of SEAR, groundwater contains still surfactant as well as little amount of residual TCE. Permeable reactive barrier using zero-valent iron (ZW) is a very effective technology to treat the residual TCE in groundwater. In this study, the effect of the residual surfactant on the reductive dechlorination of residual TCE was investigated using ZVI. Mixed surfactant composed of nonioinic surfactant and cationic surfactant was used as a residual surfactant because of toxicity and enhancement of dechlorination rate. Structure of surfactant affected significantly the decrhlorination rate of TCE. Mixed surfactant system with relatively short polyethylene oxide (PEO) chain in nonionic surfactant, cationic surfactant did not affect TCE dechlorination rate. However, mixed surfactant system with relatively long PEO chain in nonionic surfactant shows that TCE dechlorination rate was significantly dependent on fraction of cationic surfactant and HLB of nonionic surfactant. Cationic surfactant with trimethyl ammonium group enhanced reductive dechlorination rate compared to that surfactant with pyridinium group.

Development of LTCC Materials for RF Module (RF 모듈용 LTCC 소재 개발)

  • 김용철;이경호
    • Journal of the Microelectronics and Packaging Society
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    • v.10 no.2
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    • pp.13-17
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    • 2003
  • In this study, new LTCC materials of $ZnWO_4$-LiF system were developed for the application to RF Module fabrication. Pure $ZnWO_4$ must be sintered above $1050^{\circ}C$ in order to obtain up to 98% of full density. The measured dielectric constant ($\epsilon_r$)quality factor ($Q{\times}f0$), and temperature coefficient of resonant frequency ($\tau_f$ were 15.5, 74000 GHz, and $-70ppm^{\circ}C$, respectively. LiF addition resulted in a liquid phase formation at 81$0^{\circ}C$ due to interaction between ZnWO$_4$ and LiF. Therefore, ZnWO$_4$ with 0.5∼1.5 wt% LiF could be densified at $850^{\circ}C$. In the given LiF addition range, the sintering shrinkage increased with increasing LiF content. Addition of LiF slightly lowered the dielectric constant from 15.5 to 14.2∼15 due to lower dielectric constant of LiF. Qxfo value decreased with increasing LiF content. This can be explained in terms of the interaction between LiF and $ZnWO_4$, and inhomogeneity of grain structure.

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