• Title/Summary/Keyword: Liquid structure

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Supramolecular Liquid Crystals Containing Hydrogen Bond between Carboxylic Acid and Pyridyl Moieties and their Thermotropic Mesomorphism

  • Lee, Seung-Jun;You, Mi-Kyoung;Lee, Ji-Won;Lee, Shin-Woo;Jho, Jae-Young
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.297-297
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    • 2006
  • Recently columnar liquid crystals have been studied due to their possible application to organic conducting materials. Supramolecular columnar liquid crystals consist of mesogenic unit which can aggregate into discs that will make up the columns which associate to form a two-dimensional network. In this study, we prepared supramolecular columnar liquid crystals containing hydrogen bonding between carboxylic acid and, pyridine moieties. Thermal and structural properties of prepared complexe were investigated, and it exhibited hexagonal columnar structure ($Col_{h}$) at room temperature.

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A study on the construction characteristic of bath cryostat (Bath cryostat의 제작특성에 관한 연구)

  • Kim, G.Y.
    • Journal of the Korean Society for Precision Engineering
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    • v.10 no.2
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    • pp.138-145
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    • 1993
  • The bath cryostat of cryogenic apparatuses which are generally used to study physical phenomena under low temperature and ultra low temperature has been desigened and constructed. The practical use of the cryostat is verified by the measurement of the storage life of liquid heloum and liquid nitrogen vessels. The cryostat consists of triple structure of high vacuum environment in order to minimize the evaporation rate of liquid helium and liquid nitrogen by thermal conductivity and radiant heat. The minimum thickness which can stand against inner and outer pressures is calculated from considering the strength of the material.

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A Generalized Method applied to the Analysis on the Longitudinal Instability of Liquid Propulsion System (액체 추진기관 시스템 축방향불안정성 해석을 위한 동특성 모델링 일반화 기법)

  • Lee, Han-Ju;Kim, Ji-Hoon;Jung, Dong-Hoon;Oh, Seung-Hyub
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.424-427
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    • 2008
  • The longitudinal instability (POGO) of the rocket should not be occurred during the whole flight time for the large class liquid propulsion system to complete a mission successfully. The longitudinal instability is caused by the resonance between the propulsion system and rocket structure in the low frequency range below 50Hz, ordinarily. We can consider various types of propulsion system in the early stage of rocket development. So the longitudinal instability analysis tool is needed for corresponding to each propulsion system. This article deals the generalized method applied to the analysis on the low frequency dynamic characteristics of various types of liquid propulsion system.

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A Liquid Theory. Nature of Liquid by Roulette Model (액체론. Roulette 모델로 설명되는 액체의 본질)

  • D. Chio;H. Park;M. Kim
    • Journal of the Korean Chemical Society
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    • v.22 no.1
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    • pp.1-6
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    • 1978
  • Feeling the potential field within a cell for various environments, every liquid molecule moves to minimize its potential energy. With this simple and fundamental concept, liquid molecules may be treated as a combination of three kinds of typical molecules characterized by Lennard-Jones and Devonshire's earlier work. We can get a partition function which has better functional from and less defects compared to the cell theory and the significant structure theory.

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Numerical study of sway motion of a rectangular floating body with inner sloshing phenomena (내부 슬로싱 현상을 이용한 사각상자 형태의 부유체 Sway 거동 모사에 대한 수치적 고찰)

  • Ha, Minho;Cheong, Cheolung
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2013.04a
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    • pp.161-165
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    • 2013
  • In this paper, possibility of controlling motion of a floating structure using a tuned liquid damper (TLD) is numerically investigated. A TLD is a tank partially filled with liquid. Sloshing phenomena of liquid inside a tank can suppress movement of the tank subject to external excitations at specific frequency. The effects of sloshing phenomena inside a rectangular floating body on its sway motion are investigated by varying excitation frequency. First, a grid-refinement study is carried out to ensure validity of grid independent numerical solutions using present numerical techniques. Then, sway motion of the floating body subjected to wave with five different frequencies are simulated. The normalized amplitudes of sway motion of the target floating body are compared over the frequency, for cases with and without water inside the floating body. It is shown that the motion of the floating body can be minimized by matching the sloshing natural frequency to excitation frequency.

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Electrochemical Characterization of Electric Double Layer Capacitors Assembled with Pyrrolidinium-Based Ionic Liquid Electrolytes

  • Cho, Jinhyun;Shin, Won-Kyung;Kim, Dong-Won;Kim, Young Rae;Lee, Byung Jun;Kim, Sang-Gil
    • Journal of Electrochemical Science and Technology
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    • v.7 no.3
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    • pp.199-205
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    • 2016
  • We present the electrochemical performance of electric double layer capacitors (EDLCs) assembled with pyrrolidinium (Pyr)-based ionic liquid electrolytes at 55 ℃. Cations with various alkyl chain lengths were employed in Pyr-based ionic liquids to investigate the effect of cation structure on the cycling stability of EDLCs. The EDLCs exhibited initial specific capacitances ranging from 122.4 to 131.6 F g−1 based on activated carbon material at 55 ℃. Cycling data and XPS results demonstrate that Pyr-based ionic liquid with longer alkyl chain is more effective for enhancing the cycling stability of EDLC by suppressing the reductive decomposition of pyrrolidinium cations during cycling at high temperatures.

Effects of Particle Size of Alumina on Densification Behaviors of Alumina-Talc System During Liquid-Phase Sintering (알루미나-활석계의 액상소결에서 알루미나 입자크기가 치밀화 거동에 미치는 영향)

  • 김호양;이정아;김정주
    • Journal of the Korean Ceramic Society
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    • v.35 no.12
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    • pp.1308-1315
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    • 1998
  • Effects of particle size of alumina on densification behavior during liquid-phase sintering of alumina-talc system were investigated with emphasis on particle rearrangement process. In the case of using coarse alu-mina powder densiication of specimens was rapidly accelerated after formation of liquid phase due to easy particle rearrangement process with addition of talc and increase of sintering temperature. On the contrary when fine alumina powder was used premature densification of alumina matrix region formed before for-mation of liquid phase rigid skeleton structure and then it seemed to inhibit rearrangement process during crease of sintering temperature. As results the densification of specimens using coarse alumina powder was higher than that of the case of using fine one.

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Adsorption on Solid Surface from Binary Liquid Solution (이성분 용액에서의 고체 표면에 대한 흡착)

  • Seihun Chang;Hyungsuk Pak;Sangyoun Park
    • Journal of the Korean Chemical Society
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    • v.17 no.2
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    • pp.80-84
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    • 1973
  • In treating solid-liquid interfaces, it is assumed that the adsorbed layer consists of monolayer and the molecules of the adsorbed layer behave as two dimensional liquid and oscillate harmonically in the vertical direction to the adsorbent. Applying the transition state theory of significant liquid structure to the adsorbed molecules, the adsorption isotherm, entropy and heat of adsorption for cyclohexane-benzene solutions adsorbed on silica-gel G are calculated. The calculated values are in good agreements with those of the observed ones.

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Vibration Analysis for IHTS Piping System of LMR Conveying Hot Liquid Sodium (고온소듐 내부유동을 갖는 액체금속로 중간열전달계통 배관에 대한 진동특성 해석)

  • Koo, Gyeong-Hoi;Lee, Hyeong-Yeon;Lee, Jae-Han
    • Proceedings of the KSME Conference
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    • 2001.06b
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    • pp.386-391
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    • 2001
  • In this paper, the vibration characteristics of IHTS(Intermediate Heat Transfer System) piping system of LMR(Liquid Metal Reactor) conveying hot liquid sodium are investigated to eliminate the pipe supports for economic reasons. To do this, a 3-dimensional straight pipe element and a curved pipe element conveying fluid are formulated using the dynamic stiffness method of the wave approach and coded to be applied to any complex piping system. Using this method, the dynamic characteristics including the natural frequency, the frequency response functions, and the dynamic instability due to the pipe internal flow velocity are analyzed. As one of the design parameters, the vibration energy flow is also analyzed to investigate the disturbance transmission paths for the resonant excitation and the non-resonant excitations.

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Seismic analysis and modeling of isolated elevated liquid storage tanks

  • Seleemah, Ayman A.;El-Sharkawy, Mohamed
    • Earthquakes and Structures
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    • v.2 no.4
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    • pp.397-412
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    • 2011
  • In this paper, the seismic response of elevated broad and slender liquid storage tanks isolated by elastomeric or sliding bearings was investigated. The accuracy of predictions of SAP2000 vs. 3D-BASIS-ME programs was examined. A comparative study of the performance of base isolated tanks when isolation bearings are placed at the top or at the bottom of the supporting tower structure was conducted. It was found that base isolation is quite effective in reducing the earthquake response of elevated liquid storage tanks in which high reductions of base shear and shaft displacement were achieved. Modeling the isolated tanks in SAP2000 was very successful in producing results that are nearly identical to those of program 3D-BASIS-ME. Placing the isolators at the top of the shaft in elevated tanks proved to be much better than placing them at the bottom.