• Title/Summary/Keyword: Liquid sodium

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Microbial Degradation of Alkane Components in Crude Oil (미생물에 의한 원유중 Alkane 성분의 분해)

  • 김성희;김창숙;조인선;최순영;민경희
    • Korean Journal of Microbiology
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    • v.28 no.1
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    • pp.71-75
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    • 1990
  • The isolates biodigrading crude oil were examined to characterize thier properties. Isolates which were identified as Acinetobacter lwoffii G1, Klebsiella pneumoniae L25, Pseudomonas maltophilia N246, Xanthomonas campestris M12, and Xanthomonas sp. M28. The optimum concentration of crude oil was 0.15% for the bacterial growth. X. campestris M12, Xanthomonas sp. M28, and K. penumoniae L25 showed the maximal growth at the concentration of 3.5% sodium chloride, indicating that they were derived from sea water. Among the isolates, X. campestris M12, Xanthomonas sp. M28 specially utilized hexadecane and octane, and P. maltophilia N246 utilized octane with optimum concentration of 0.2-0.3% as sole carbon source. The utilization of components of saturate fraction by K. pneumoniae L25 was examined by gas-liquid chromatography. The short-chain saturates are used before the long chain ones although they almost disappear within 8 days of incubation at $30^{\circ}C$.

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Isolation of Iron and Calcium-Binding Peptides from Cottonseed Meal Protein Hydrolysates (면실박 단백질로부터 가수분해물 제조 및 철분, 칼슘 결합 펩타이드의 분리)

  • Choi, Dong-Won;Kim, Nam-Ho;Song, Kyung Bin
    • Journal of Applied Biological Chemistry
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    • v.55 no.4
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    • pp.263-266
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    • 2012
  • Isolation of iron and calcium-binding peptides derived from cottonseed meal protein (CMP) hydrolysates was investigated. The degree of hydrolysis of CMP by Flavourzyme was monitored using trinitrobenzenesulfonic acid method and sodium dodecyl sulfate-polyacrylamide gel electrophoresis. Enzymatic hydrolysis of CMP for 12 h was sufficient for the preparation of CMP hydrolysates, and the hydrolysates were membrane-filtered under 3 kDa as a molecular weight. The filtered solution was fractionated using Q-Sepharose fast flow, Sephadex G-15, and reversed phase-high performance liquid chromatography for iron and calcium-binding peptides. As a result, F51 fraction was obtained as the best candidate for calcium and iron chelation, and the isolated iron and calcium-binding peptides can be used as functional food additives, similar to iron and calcium supplements.

The effects of replacement fly ash with diatomite in geopolymer mortar

  • Sinsiri, Theerawat;Phoo-ngernkham, Tanakorn;Sata, Vanchai;Chindaprasirt, Prinya
    • Computers and Concrete
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    • v.9 no.6
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    • pp.427-437
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    • 2012
  • This article presents the effect of replacement fly ash (FA) with diatomite (DE) on the properties of geopolymer mortars. DE was used to partially replace FA at the levels of 0, 60, 80 and 100% by weight of binder. Sodium silicate ($Na_2SiO_3$) and sodium hydroxide (NaOH) solutions were used as the liquid portion in the mixture in order to activate the geopolymerization. The NaOH concentrations of 15M, $Na_2SiO_3$/NaOH ratios of 1.5 by weight, and the alkaline liquid/binder (LB) ratios by weight of 0.40, 0.50, 0.60 and 0.70 were used. The curing at temperature of $75^{\circ}C$ for 24 h was used to accelerate the geopolymerization. The flows of all fresh geopolymer mortars were tested. The compressive strengths and the stress-strain characteristics of the mortar at the age of 7 days, and the unit weights were also tested. The results revealed that the use of DE to replace part of FA as source material in making geopolymer mortars resulted in the increased in the workability, and strain capacity of mortar specimens and in the reductions in the unit weights and compressive strengths. The strain capacity of the mortar increased from 0.0028 to 0.0150 with the increase in the DE replacement levels from 0 to 100%. The mixes with 15M NaOH, $Na_2SiO_3$/NaOH of 1.5, LB ratio of 0.50, and using $75^{\circ}C$ curing temperature showed 7 days compressive strengths 22.0-81.0 MPa which are in the range of normal to high strength mortars.

Cell Wall Micropore Loading of Pulp Fibers (펄프 섬유의 세포벽 미세공극 충전)

  • Lee, Jong-Man;Jo, Byoung-Muk
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.4
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    • pp.57-64
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    • 1992
  • The unique cell wall micropores of pulp fiber can be utilized as loading site in variety of important practical application which could be the basis of new papermaking technologies. One of these includes the manufature of paper containing higher levels of in situ filler precipitated. Hardwood pulp fiber were first impregnated with the solution of sodium carbonate($Na_2CO_3$). The micropores in cell wall of pulp fibers were filled with the liquid salt solution. The second calcium nitrate($Ca(NO_3)_2$) solution formed an insoluble calcium carbonate($CaCO_3$) precipitate within the cell wall micropores by interacting with the first sodium carbonate solution. The effects of chemical concentration and dryness of pulp fibers on the retention of cell wall micropore loaded filler were investigated. The paper properties of cell wall micropore loaded pulp fibers were compared with those of conventionally loaded and lumen loaded pulp fibers. Also the presense of the fillers within the cell wall micropore was observed by SEM. Increasing the chemical concentration to generate the calcium carbonate increased the retention of filler in cell wall micropore loaded pulp fibers. The particle size distribution of precipitated calcium carbonate ranged from $0.1{\mu}m$ to $80{\mu}m$. But, the average particle size of cell wall micropore loaded calcium carbonate was $4{\mu}m$. The paper made from never dried pulp fibers, the cell wall micropores which were filled with calcium carbonate, had better mechanical and optical properties than those of conventionally loaded or lumen loaded pulp fibers.

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Study on Leaching Characteristics of $^{137}Cs\;and\;^{90}Sr$ from Cement-Solidified Radwastes (방사성 폐기물 시멘트 고화체로 부터의 $^{137}Cs$$^{90}Sr$ 용출특성 연구)

  • Hwang, Sun-Tae;Lee, Kyung-Ju;Choi, Kil-Oung;Park, Hun-Whee;Kim, Hwan-Young
    • Journal of Radiation Protection and Research
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    • v.10 no.2
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    • pp.113-121
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    • 1985
  • For the safety assessment of radwaste treatment and disposal, the leaching characteristics of $Cs^+\;and\;Sr^{++}$ from the cement-solidified radwastes was investigated by means of the survey and analysis of the activity leach rate and cumulative leach fraction of $^{137}Cs\;and\;^{90}Sr$ leaching from solidified radwastes. The cylindrical cement-solidified samples were made by the sodium silicate method and neutralization method changing the mole density of simulated liquid radwaste, type of cement, adding material and concentration of boric acid. The leaching study was carried out by the method using simulated PWR concentrated liquid radwaste solidified in cement that had been processed following the recommendations of IAEA. All the experimental results are in well accordance with the research data reported previously, but the watertight cement-solidified radwastes show rather high leach rate of radioactivity. It is learned, therefore, that the watertight cement is not adequate as the material for the solidified radwastes.

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Decay Resistance and Anti-mold Efficacy of Wood Treated with Fire Retardants (난연처리 목재의 방미 및 방부성능)

  • Son, Dong Won;Kang, Mee Ran;Lee, Dong-Heub;Park, Sang-Bum
    • Journal of the Korean Wood Science and Technology
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    • v.41 no.6
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    • pp.559-565
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    • 2013
  • This study evaluated the ability of white and brown rot fungi to decompose fire retardant-treated wood by measuring mass loss. Anti efficacy of FRT against sapstain and mold fungi was evaluated. Wood was treated with liquid sodium silicate and boric acid, ammonium borate, di-ammonium phosphate. Retardant treated wood was then subjected to fungal decay resistance tests performed according to KS standard method using a brown-rot fungus, Fomitopsis palustris and white rot fungus Trametes versicolor. Aspergillus niger, Penicillium funiculosum, Rhizopus nigricans, Aureobasidium pullulans, Tricoderma virede fungi were used anti-sapstain and mold test. Boron and phosphorus chemicals used in this study increased the resistance of fire retardant treated wood against both fungal attack. Anti mold and sapstain efficacy of the fire retardant treated wood was excellent but there were difference depend on mold. After the liquid sodium silicate treatment, the second chemical treatment process could lead chemical fixation into wood, which effects decay resistance.

Effect of chemical input during wet air oxidation pretreatment of rice straw in reducing biomass recalcitrance and enhancing cellulose accessibility

  • Morone, Amruta;Chakrabarti, Tapan;Pandey, R.A.
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2403-2412
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    • 2018
  • The present study was aimed at evaluating the effect of variable sodium carbonate ($Na_2CO_3$) loading during wet air oxidation (WAO) pretreatment of rice straw in reducing biomass recalcitrance. The research study was intended to increase the cellulose recovery, hemicellulose solubilization, lignin removal in the solid fraction and limiting the generation of inhibitors in the liquid fraction while reducing the chemical input. The operating condition of $169^{\circ}C$, 4 bar, 18 min and 6.5 g/L $Na_2CO_3$ loading resulted in maximum cellulose recovery of 82.07% and hemicellulose solubilization and lignin removal of 85.43% and 65.42%, respectively, with a total phenolic content of 0.36 g/L in the liquid fraction. The crystallinity index increased from 47.69 to 51.25 along with enzymatic digestibility with an increase in $Na_2CO_3$ loading from 0 to 6.5 g/L as a result of removal of barriers for saccharification via effective cleavage of ether and ester bonds cross-linking the carbohydrates and lignin as indicated by FT-IR spectroscopy. A further increase in the $Na_2CO_3$ loading to 9.5 g/L did not significantly increase the sugar release. Thus, it was concluded that 6.5 g/L $Na_2CO_3$ during WAO is sufficient to increase the delignification and deacetylation, leading to significant changes in apparent cellulose crystallinity inter alia improvement in cellulose accessibility and digestibility of rice straw.

Preparation of Hydrated Liquid Crystalline Vesicles Containing High Content of Ceramide using a Solubilizer (가용화제를 활용한 세라마이드 고함량의 수화 액정형 베시클 개발)

  • Park, Min Seon;Jin, Byung Suk
    • Applied Chemistry for Engineering
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    • v.32 no.5
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    • pp.541-546
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    • 2021
  • Hydrated liquid crystalline vesicles containing a high content of ceramide were prepared by constituting an optimal composition in which ceramides can be mutually self-associated with phospholipid and cholesterol. From the result of manufacturing various vesicles with different component composition, when the edge activator sodium deoxycholate (SDOC) and the solubilizer PEG-60 hydrogenated castor oil (HCO 60) were mixed to form vesicles, the smallest nano-sized particles were produced and the vesicle dispersion solution was weakly acidic and maintained the most stable state. In addition, it was confirmed through polarized light microscopy and thermal analysis that the addition of SDOC and HCO 60 had an effect on the inhibition of crystallinity of lipid components such as ceramide. The stability of the vesicle dispersion solution was maintained without change in appearance and viscosity even after long-term storage at high temperature for eight weeks.

A Low Irritant Liquid Cleanser Composition Developed by Multi-Screening Methods (다탐색(多探索)법을 통한 저자극성 액체 세정제 조성물 개발)

  • Kim Peter;Hyeon Ki-An;Chung Ji-Youn;Yoon Sam-Sook;Kang Han Chyul;Park Sun Hee;Ko King Il;Kim Ki Ho
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.31 no.1 s.49
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    • pp.51-58
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    • 2005
  • Alkyl ethoxy sulfate type surfactants, widely used in commercial cleansers, are easily adsorbed to skin to often cause skin irritation and inflammation if not thoroughly rinsed nut. In order to replace or complement existing surfactants, we screened the existing surfactants through protein denaturation method, cell cytotoxicity assay and human IL-1$\alpha$ assay, etc. Fourteen surfactants have been chosen from among too irritant anionic, cationic and/or zwitter-ionic ones and investigated for cell cytotoxicity in human fibroblast cell lines using monolayer culture with the thirteen commercially available cleansers for sensitive skin. From these results, we selected 5 surfactants and 2 commercial cleansers (names not shown), such as sodium laureth sulfate (anionic), sodium cocoyl isethionate (anionic), sodium lauroamphoacetate (zwitter-ionic), and cocamidopropyl betaine (zwitter-ionic), alkyl polyglycoside (non-ionic). 20 formulations were made out of 5 surfactants and five of them were chosen through a protein denaturation method (lower than 3 M sodium dodecyl sulfate solution ($13.2\%$)), cell cytotoxicity and human patch test. These five selected formulations containing preservatives were compared to two selected commercial cleansers by cell cytotoxicity and human IL-1$\alpha$ ELISA assay using dermal equivalent. Finally, we selected the best formulation. To this formulation, fructan ($3\%$ or $5\%$) or/and portulaca extract ($3\%$ or $5\%$) well known for its anti-inflammatory and moisturizing effects were added and investigated for cell cytotoxicity using dermal equivalent. In cytotoxicity assay using dermal equivalent, two formulations containing $5\%$ fructan and $3\%$ or $5\%$ portulaca extract were less toxic than the others. In cytotoxicity assay and human IL-1$\alpha$ ELISA using 3D culture, the selected formulation containing $5\%$ fructan and $5\%$ portulaca extract showed better efficiency than those of the others and 2 commercial cleansers. As a result, we could develop a low irritant and safe liquid cleanser.

Development of Liquid Metal Passive Cooling Flow Simulation System (액체금속 피동냉각유동모사 실증설비의 개발)

  • Ryu, Kyung-Ha;Kim, Jae-Hyoung;Lee, Tae-Hyun;Lee, Sang-Hyuk;Bahn, Byoung-Min
    • Transactions of the KSME C: Technology and Education
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    • v.3 no.4
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    • pp.257-264
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    • 2015
  • To maintain sustainability of nuclear energy as an important energy source, both safety problem and Spent Nuclear Fuels(SNFs) problem should be solved. In case of Gen-IV reactors such as fast reactor, SNFs can be used as fuels by using fast neutrons. It can be a suitable treatment method of high-level waste in near future. Liquid metals such as Sodium or Lead-Bismuth Eutectic (LBE) can be possibly used as a coolant to use fast neutrons. In this paper, it was described that natural circulation parameter studies, design analyses, material selections and a completion of facilities. To develop a natural circulation facility, thermal hydraulic analyses were performed. Installation technique of liquid metal natural circulation were secured.