• 제목/요약/키워드: Liquid sodium

검색결과 524건 처리시간 0.051초

소듐냉각고속로 원자로 내부구조물의 소듐내부가시화를 위한 웨이브가이드 초음파센서의 적용 가능성 연구 (Feasibility Study on Ultrasonic Waveguide Sensor for Under-Sodium Viewing of Reactor Internals in Sodium-Cooled Fast Reactor)

  • 주영상;임사회;박창규;이재한
    • 비파괴검사학회지
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    • 제28권4호
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    • pp.364-371
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    • 2008
  • 소듐냉각고속로 원자로 내부구조물의 소듐내부가시화를 위한 새로운 웨이브가이드 초음파센서를 개발하였다. 소듐냉각고속로에 적용할 수 있는 웨이브가이드 초음파센서 어셈블리의 구조 설계 개념을 제시하고 그 적용 타당성을 평가하였다. 길이가 10 m인 웨이브가이드 초음파센서 어셈블리를 제작하고 성능평가 시험을 수행하였다. $A_0$ 모드 판파의 장거리 전파 성능을 확인하였으며, 수중 C-스캔 분해능 성능시험을 수행하여 웨이브가이드 초음파센서의 적용 가능성을 실험적으로 검증하였다.

액상 또는 분말망초 Type에 따른 Cellulose섬유의 균염성 연구 (The Effect of Sodium Sulfate in Liquid or Solid Form on Leveling Properties of Cellulose Fibers)

  • 김미리;이혜정;남창우
    • 한국염색가공학회:학술대회논문집
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    • 한국염색가공학회 2011년도 제44차 학술발표회
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    • pp.89-89
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    • 2011
  • Cellulose섬유의 염색시 섬유가 물속에 침지되면 섬유표면은 음전하가 형성되어, 용액 속에서 음이온으로 존재하는 염료와의 반발력으로 인해 염료가 섬유에 접근하기가 어려워지며 따라서 염색이 원활하게 이루어지지 않는다. 그러나 염욕에 염화나트륨(sodium chloride, NaCl)이나 망초 즉, 황산나트륨(Glauber's salt, sodium sulfate, Na2SO4)과 같은 전해질을 첨가하면, 양이온인 sodium 이온이 섬유표면과 음이온 염료사이의 반발력을 감소시킨다. 따라서 음이온의 염료는 섬유표면에 접근할 수 있고, 고유한 인력으로 염색이 가능하게 된다. 현재 Cellulose섬유의 상업적인 반응성염료 염색공정뿐만 아니라 최근 연구에서는 전해질 중 대부분 분말망초를 대부분 사용하고 있다. 그러나 분말망초는 별도의 용해과정이 필요할 뿐 아니라, 과량 사용시 용해되지 않은 분말이 섬유 표면에 흡착될 경우 불균염을 초래할 우려 등의 단점이 있다. 이와 같이 작업효율성을 향상시키고 염색을 효율적으로 진행시키기 위해 최근 액상형의 망초가 도입되고 있다. 이 연구에서는 분말 및 액상 망초를 조제로 사용하여 3종류의 Cellulose섬유를 반응성염료로 염색하였다. 담색, 중색, 농색 3가지 염료 농도에 대해 투입하는 망초의 type에 따라 각각의 Cellulose섬유별 균염성 정도에 대하여 비교해 보았다.

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고농도 과산화수소와 수소화물의 지속적인 반응에 대한 연구 (Feasibility of Energy Generation from Chemical Reaction between Hydrogen Peroxide/Hydride)

  • 서성현
    • 한국수소및신에너지학회논문집
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    • 제26권3호
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    • pp.271-277
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    • 2015
  • The present paper discusses about noble idea on various reactions including hydrides, hydrogen peroxide and nano-sized metal powders, which do not emit toxic materials as well as carbon dioxide. Here in this paper, the very first-ever concept that heat energy can be generated from the direct reaction between sodium borohydride and hydrogen peroxide is presented. Sodium hydride as fuel can supply hydrogen reacting with oxygen provided by the decomposition of hydrogen peroxide solution. Solid sodium borohydride can be resolved in water and treated as liquid solution for the easy handling and the practical usage although its solid powder can be directly mixed with hydrogen peroxide for the higher reactivity. The thermodynamic analysis was conducted to estimate adiabatic reaction temperatures from these materials. The preliminary experiment on the reactions conducted using sodium borohydride powder and hydrogen peroxide water solution revealed that the self-propagating reaction can occur and that its reactivity increases with an increase of hydrogen peroxide concentration.

상온형 나트륨/유황 이차전지 개발 동향 (Development of Room Temperature Na/S Secondary Batteries)

  • 유호석;김인수;박진수
    • 한국수소및신에너지학회논문집
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    • 제27권6호
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    • pp.753-763
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    • 2016
  • High temperature sodium/sulfur battery(Na/S battery) has good electrochemical properties, but, the battery has some problems such as explosion and corrosion at al. because of using the liquid electrodes at high temperature and production of high corrosion. Room temperature sodium/sulfur batteries (NAS batteries) is developed to resolve of the battery problem. To recently, room temperature sodium/sulfur batteries has higher discharge capacity than its of lithium ion battery, however, cycle life of the battery is shorter. Because, the sulfur electrode and electrolyte have some problem such as polysulfide resolution in electrolyte and reaction of anode material and polysulfide. Cycle life of the battery is improved by decrease of polysulfide resolution in electrolyte and block of reaction between anode material and polysulfide. If room temperature sodium/sulfur batteries (NAS batteries) with low cost and high capacity improves cycle life, the batteries will be commercialized batteries for electric storage, electric vehicle, and mobile electric items.

Quantitative analysis and validation of naproxen tablets by using transmission raman spectroscopy

  • Jaejin Kim;Janghee Han;Young-Chul Lee;Young-Ah Woo
    • 분석과학
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    • 제37권2호
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    • pp.114-122
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    • 2024
  • A transmission Raman spectroscopy-based quantitative model, which can analyze the content of a drug product containing naproxen sodium as its active pharmaceutical ingredient (API), was developed. Compared with the existing analytical method, i.e., high-performance liquid chromatography (HPLC), Raman spectroscopy exhibits high test efficiency owing to its shorter sample pre-treatment and measurement time. Raman spectroscopy is environmentally friendly since samples can be tested rapidly via a nondestructive method without sample preparation using solvent. Through this analysis method, rapid on-site analysis was possible and it could prevent the production of defective tablets with potency problems. The developed method was applied to the assays of the naproxen sodium of coated tablets that were manufactured in commercial scale and the content of naproxen sodium was accurately predicted by Raman spectroscopy and compared with the reference analytical method such as HPLC. The method validation of the new approach was also performed. Further, the specificity, linearity, accuracy, precision, and robustness tests were conducted, and all the results were within the criteria. The standard error of cross-validation and standard error of prediction values were determined as 0.949 % and 0.724 %, respectively.

Etchant for Dissolving Thin Layer of Ag-Cu-Au Alloy

  • Utaka, Kojun;Komatsu, Toshio;Nagano, Hiroo
    • Corrosion Science and Technology
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    • 제6권6호
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    • pp.304-307
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    • 2007
  • As to the reflection electrode of LCD (liquid crystal displays), silver-copper-gold alloy (hereafter, it is called as ACA (Ag98%, Cu1%, Au1%)) is an effective material of which weathering resistance can be improved more compared with pure silver. However, there is a problem that gold remains on the substrate as residues when ACA is etched in cerium ammonium nitrate solution or phosphoric acid. Gold can not be etched in these etchants as readily as the other two alloying elements. Gold residue has actually been removed physically by brushing etc. This procedure causes damage to the display elements. Another etchant of iodine/potassium iodide generally known as one of the gold etchants can not give precise etch pattern because of remarkable difference in etching rates among silver, copper and gold. The purpose of this research is to obtain a practical etchant for ACA alloy. The results are as follows. The cyanogen complex salt of gold generates when cyanide is used as the etchant, in which gold dissolves considerably. Oxygen reduction is important as the cathodic reaction in the dissolution of gold. A new etchant of sodium cyanide / potassium ferricyanide whose cathodic reduction is stronger than oxygen, can give precise etch patterns in ACA alloy swiftly at room temperature.