• 제목/요약/키워드: Liquid sodium

검색결과 524건 처리시간 0.024초

시멘트 수용액에서 흡수 지연을 위한 Crosslinked Poly(sodium acrylate)의 표면 가교 (Synthesis of Surface Crosslinked Poly(sodium acrylate) for Delayed Absorption in Cement Solution)

  • 황기섭;장석수;정용욱;이승한;하기룡
    • 폴리머
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    • 제35권4호
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    • pp.363-369
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    • 2011
  • 콘크리트 제조 시 사용되는 잉여수를 지연 흡수시키기 위하여 역유화중합법으로 중합된 가교 poly(sodium acrvlate) (cPSA)를 ethylene glycol dimethacrylate(EGDMA)로 표면 가교시켰다. cPSA의 제조에서 연속상은 paraffin liquid, 단량제는 8 M 농도의 NaOH 수용액으로 90% 중화된 acrylic acid(AA), 가교제는 N,N-methylene bisacrylamide(MBA), redox 개시제는 ammonium persulfate(APS)와 sodium metabisulfite(SMBS)를 사용하여 역유화중합법으로 제조하였다. 제조된 cPSA는 EGDMA플 사용하여 표면 가교 반응을 수행하였다. 시멘트 수용액에서 $Ca^{2+}$ 이온과 cPSA의 상호 작용을 관찰하기 위하여 FTIR spectroscopy 분석법을 사용하였다. 제조된 흡수제들을 탈이온수 $Ca(OH)_2$ 수용액(pH 12) 및 시멘트 포화 수용액에서의 팽윤비를 측정하였으며, cPSA는 2시간만에 팽윤이 완료되었지만, 표면이 가교된 cPSA-EGDMA는 3시간 후 팽윤이 거의 완료되는 것을 관찰하였다. 또한 합성한 cPSA-EGDMA를 첨가함으로써 시멘트의 응결시간과 모르타르의 압축강도 증가를 관찰하였다.

염분에 따른 변압기유의 유전특성 (I) (The Dielectric Characteristics of Transformer Oil due to the Sodium Chloride (I))

  • 조경순;송병기;이수원;신종열;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 춘계학술대회 논문집
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    • pp.206-210
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    • 1996
  • In order to investigate the electrical properties for transformer oils which contains a Pure sodium chloride, the dielectric properties is made researches. To measure the dielectric loss of specimen, a coaxial cylindrical liquid electrode is used, and its geometric capacitance is confirmed to 16[pF]. And the dielectric dissipation factor, tan$\delta$, is measured by using the Video Bridge 2150. The thermal static oven with an automatically static temperature controller is used so as to support specific temperature to the specimen. This experiments for measuring the dielectric lass is performed at 20-120[$^{\circ}C$] in the temperature range, 30∼1.5x10$\^$5/[Hz] in the frequency range and 300∼1500[mV] in the voltage range. The result of experiment for the movement of carrier and the physical constants to contribute dielectric properties of specimen with a pure sodium chloride.

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인산나트륨계 염화암모늄 pH저감제의 반응성 검토 (Study on the Reactivity of Sodium Phosphate Ammonium Chloride pH Reduction Agents)

  • 신기돈;고산;이건철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 추계 학술논문 발표대회
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    • pp.105-106
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    • 2017
  • Previous studies have confirmed the performance of pH reduction agents using liquid sodium phosphate based ammonium chloride as a pH reduction agent. In this study, the pH reduction performance considering economical and applicability as a practical stage and the property change analysis for the identification of the reaction mechanism of the pH reduction agent were carried out. As a result, the pH reduction performance at a low rate of the pH reducing agent was confirmed. The specific gravity of CaO decreased significantly after XRF analysis. It is also believed that this reduces the amount of Ca(OH)2 produced and contributes to pH reduction.

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A Calculation Model for Fuel Constituent Redistribution and Temperature Distribution on Metallic U-10Zr Fuel Slug of Liquid Metal Reactors

  • Nam, Cheol;Hwang, Woan
    • Nuclear Engineering and Technology
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    • 제30권6호
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    • pp.507-517
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    • 1998
  • Unlike conventional fuel types, fuel constituent redistribution and sodium intrusion into the fuel slug are the unique phenomena of the irradiated metallic fuel. A thermal calculation model on metallic U-10 wt.%Zr fuel rod for LMRs is developed with considerations given to these phenomena. The amount of constituent redistribution is estimated based on the thermotransport process. The temperature profile of fuel slug is predicted by taking into account of Zr redistribution, porosity formation and sodium logging effects. A sample calculation is performed and compared to experimental data in literature. As a result, the predicted redistribution and temperature profile are well agreed with experimental data, assuming that 15 times increment of ex-reactor diffusivity, $Q_{r}$ $^{*}$ is -50 kJ/mole and sodium is infiltrated only outside of the fuel slug. Furthermore, the redistribution effects on fuel integrity and fuel temperature profile are discussed.d.

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Robust technique using magnetohydrodynamics for safety improvement in sodium-cooled fast reactor

  • Lee, Jong Hui;Park, Il Seouk
    • Nuclear Engineering and Technology
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    • 제54권2호
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    • pp.565-578
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    • 2022
  • Among Generation IV reactors, the sodium-cooled fast reactor (SFR) is attracting attention as a system having great potential for commercial use. Gas entrainment is a thermal-hydraulic issue related to the safety problem of the reactor core in the SFR. Typically, a dipped plate or baffles are installed under the free surface to suppress gas entrainment. However, these approaches can cause gas entrainment in other locations and require many trial-and-error and verifications. In this study, a new strategy using magnetohydrodynamics to suppress gas entrainment in the SFR is proposed. In a counter-flow model, a judgment criterion of gas entrainment occurrence was developed for both water and liquid metal. Moreover, the gas entrainment can be completely suppressed by applying a magnetic field.

Experimental Results of Turbulent Thermal Mixing Phenomena Using Sodium Parallel Jets

  • Lee, Y.B.;Park, S.K.;J.S. Hwang;Kim, Y.K.;H.Y. Nam
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1996년도 춘계학술발표회논문집(2)
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    • pp.199-204
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    • 1996
  • In the present the mean temperature and the temperature fluctuation of non-isothermal parallel liquid sodium jets were measured and analyzed changing the temperature difference and mean velocity of the hot and cold sodium. The sampling frequency and sampling time were 420Hz and three seconds, respectively. The wave-form characteristics were discussed in regard to the peak-to-peak amplitudes and the periods provided by a wave analysis. And also the correlations of the temperature fluctuation in rms value and the peak amplitude are derived. The overall mean accuracy ratios of the correlations are 1.07 and 1.08 with a standard deviation of 0.17 and 0.15, respectively.

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Laboratory investigation for engineering properties of sodium alginate treated clay

  • Cheng, Zhanbo;Geng, Xueyu
    • Structural Engineering and Mechanics
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    • 제84권4호
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    • pp.465-477
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    • 2022
  • The formation of biopolymer-soil matrices mainly depends on biopolymer type and concentration, soil type, pore fluid and phase transfer to influence its strengthening efficiency. In this study, the physical and mechanical properties of sodium alginate (SA) treated kaolinite are investigated through compaction test, thread rolling teat, fall cone test and unconfined compression test with considering biopolymer concentration, curing time, initial water content, mixing method. The results show that the liquid limit slightly decreases from 69.9% to 68.3% at 0.2% SA and then gradually increases to 98.3% at 5% SA. At hydrated condition, the unconfined compressive strength (UCS) of SA treated clay at 0.5%, 1%, 2% and 3% concentrations is 2.57, 4.5, 7.1 and 5.48 times of untreated clay (15.7 kPa) at the same initial water content. In addition, the optimum biopolymer concentration, curing time, mixing method and initial water content can be regarded as 2%, 28 days, room temperature water-dry mixing (RD), 50%-55% to achieve the maximum unconfined compressive strength, which corresponds to the UCS increment of 593%, compared to the maximum UCS of untreated clay (780 kPa).

대구지역 사업체급식 메뉴 유형별 염도 및 소금함량 측정 (Measurements of Salinity and Salt Content by Menu Types Served at Industry Foodservice Operations in Daegu)

  • 김지애;김윤화;안문영;이연경
    • 대한지역사회영양학회지
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    • 제17권5호
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    • pp.637-651
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    • 2012
  • The purpose of this study was to investigate salinity and sodium content in foods served at industry foodservice operations in selected workplaces in Daegu. The researcher collected 1,142 food items categorized into 22 menu item groups from lunch samples served at 100 industry foodservice operations and measured the salinity of the food items, and calculated sodium and salt contents from the salinity. In terms of salt content of one meal at each workplace, 46% of the meals were 3-<5 g, and only 3.0% of them were 1.7 g or less, which is one third of the daily target intake (5 g) presented by the Dietary Reference Intakes for Koreans. In terms of sodium content, 35.3% of the meals were 1,000-< 1,500 mg (most), and only 2.5% of them were 667 mg or less, which is, again, one third of the daily target intake. As to the salinity of each menu item group, side dishes such as sauces, kimchi, seasoned vegetables, hardboiled foods, and stir-fried foods were significantly higher, but the sodium content was not higher, because their quantity per serving was small. The salinity of foods with liquid such as stews, noodles, soups, and broths was relatively lower, but the sodium content was higher, because their quantity per serving was large. This indicates that an education program should be developed for foodservice workers who prepare food for the workplace regarding the development and promotion of various menus for reducing sodium content, in order to reduce sodium content in meals served by food service in the workplace.

Sodium Glycinate 수용액의 CO$_2$ 흡수특성 및 반응 메커니즘 해석 (Absorption Characteristics of Aqueous Sodium Glycinate Solution with Carbon Dioxide and Its Mechanistic Analysis)

  • 심재구;김준한;장경룡
    • 대한환경공학회지
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    • 제30권4호
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    • pp.430-438
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    • 2008
  • 본 논문에서는 아미노산염의 일종인 글리신산나트륨(sodium glycinate) 수용액을 이산화탄소(CO$_2$) 흡수제로 사용하여 이산화탄소 분리회수 특성평가 실험을 수행하였다. 흡수제와 이산화탄소의 기-액 흡수평형 실험을 통하여 흡수제 농도 20 wt%와 30 wt%에서 글리신산나트륨과 상용 흡수제인 MEA의 분압에 따른 몰부하비(mol loading ratio)를 측정하여 이산화탄소 흡수능을 평가하였다. 또한, 기-액 흡수평형 결과를 바탕으로 2 t-CO$_2$/day 용량의 파일럿플랜트 실험을 수행한 결과, 이산화탄소 탈거가 MEA에 비하여 용이하게 일어나지 않아 상대적으로 낮은 이산화탄소 제거율을 얻었다. 이는 글리신산나트륨 고유의 입체구조에 기인하는 것으로 판단된다. 본 논문은 이산화탄소 흡수제로 아미노산염 계열 흡수제를 이용하여 실제 공정에 적용한 우리나라 최초의 연구결과로서 아미노산염의 흡수제로서의 가능성 파악에 큰 의의가 있다고 할 수 있다.