• Title/Summary/Keyword: Liquid core

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Synthesis and Properties of Hexyl End-Capped Thiophene Oligomers Containing Anthracene Moiety in the Center

  • Choi, Jung-Hei;Cho, Dae-Won;Jin, Sung-Ho;Yoon, Ung-Chan
    • Bulletin of the Korean Chemical Society
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    • 제28권7호
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    • pp.1175-1182
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    • 2007
  • A series of new organic semiconductors hexyl end-capped thiophene-anthracene oligomers containing the anthracene moiety in the center of the oligomers are synthesized. The target oligomers have been obtained by Stille coupling reactions as key step reactions. The synthesized thiophene-anthracene oligomers were characterized by 1H-NMR, 13C-NMR and high-resolution mass spectroscopy, respectively. All of the oligomers are soluble in chlorinated solvents. Their optical, thermal and electrochemical properties were measured. The hexyl end-capped oligomers and their unsubstituted oligomers exhibit the same absorption behavior in dilute toluene solution. Hexyl end-capped bis-terthienylanthracene oligomer is observed to show liquid crystalline mesophase at 166 oC in heating process. The thermal analyses as well as the electrochemical measurement data indicate that the designed materials show better thermal and oxidation stability than the corresponding oligothiophenes without anthracene core. Fluorescence lifetimes and fluorescence quantum yields of the thiophene-anthracene oligomers are measured to be 10-14 ps and 3.4-9.9 × 10?3 which are much shorter and lower than those of oligothiophenes respectively.

초전도 마이크로 프로세서개발을 위한 RSFQ ALU 회로의 타이밍 분석 (Timing analysis of RSFQ ALU circuit for the development of superconductive microprocessor)

  • 김진영;백승헌;김세훈;강준희
    • 한국초전도ㆍ저온공학회논문지
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    • 제7권1호
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    • pp.9-12
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    • 2005
  • We have constructed an RSFQ 4-bit Arithmetic Logic Unit (ALU) in a pipelined structure. An ALU is a core element of a computer processor that performs arithmetic and logic operation on the operands in computer instruction words. We have simulated the circuit by using Josephson circuit simulation tools. We used simulation tools of XIC, $WRspice^{TM}$, and Julia. To make the circuit work faster, we used a forward clocking scheme. This required a careful design of timing between clock and data pulses in ALU. The RSFQ 1-bit block of ALU used in constructing the 4-bit ALU was consisted of three DC current driven SFQ switches and a half-adder. By commutating output ports of the half adder, we could produce AND, OR, XOR, or ADD functions. The circuit size of the 4-bit ALU when fabricated was 3 mm x 1.5 mm, fitting in a 5 mm x 5mm chip. The fabricated 4-bit ALU operated correctly at 5 GHz clock frequency. The chip was tested at the liquid-helium temperature.

3상 10kVA 더블 팬케익 코일형 고온초전도 변압기 특성시험 결과 (Test Results of a Three Phase 10㎸A HTS Transformer With Double Pan Cake Coils)

  • 이승욱;이희준;차귀수;이지광;최경달;류경우;한송엽
    • 대한전기학회논문지:전기기기및에너지변환시스템부문B
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    • 제52권3호
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    • pp.101-106
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    • 2003
  • The high temperature superconductor transformers gain interests from the industries. This paper described construction and test results of 10㎸A HTS transformer Three phase transformer with double pancake windings were constructed. To reduce the leakage magnetic field, secondary coil were placed between the two primary coils. BSCCO-2223 wire. silicon sheet steel core and FRP cryostats were used to construct the transformer. Three coils were stacked in one cryostat. Two double pancake coils were connected in series for the primary coil and one double pancake coil was used for the secondary coil. Total number of turns of the primary winding and the secondary winding were 112turns and 98urns, respectively, The rated voltages of each winding were 440/220V. The rated currents of each winding were 13.1/26.2A. After the tests of basic properties of the three phase HTS transformer using no-load test, short-circuit test and full-load test, continuous operation of 100 hours with pure resistive load has been carried out. Test results proved over-load capability and reliability of the HTS transformer.

RSFQ 4-bit ALU 개발 (Development of an RSFQ 4-bit ALU)

  • 김진영;백승헌;김세훈;정구락;임해용;박종혁;강준희;한택상
    • Progress in Superconductivity
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    • 제6권2호
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    • pp.104-107
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    • 2005
  • We have developed and tested an RSFQ 4-bit Arithmetic Logic Unit (ALU) based on half adder cells and de switches. ALU is a core element of a computer processor that performs arithmetic and logic operations on the operands in computer instruction words. The designed ALU had limited operation functions of OR, AND, XOR, and ADD. It had a pipeline structure. We have simulated the circuit by using Josephson circuit simulation tools in order to reduce the timing problem, and confirmed the correct operation of the designed ALU. We used simulation tools of $XIC^{TM},\;WRspice^{TM}$, and Julia. The fabricated 4-bit ALU circuit had a size of $\3000{\ cal}um{\times}1500{\cal}$, and the chip size was $5{\cal} mm{\times}5{\cal}mm$. The test speeds were 1000 kHz and 5 GHz. For high-speed test, we used an eye-diagram technique. Our 4-bit ALU operated correctly up to 5 GHz clock frequency. The chip was tested at the liquid-helium temperature.

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하니컴 샌드위치 Panel을 이용한 LCD/PDP생산공정용 고기능성 복합 신소재 파렛트의 최적설계 (The Optimum Design of the Light-weight Composite Pallet Plank for Assembly Line of LCD/PDP by using Honeycomb Sandwich Panel)

  • 김윤해;최병근;손진호;조영대;엄수현;우병훈
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2005년도 전기학술대회논문집
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    • pp.388-394
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    • 2005
  • A typical honeycomb sandwich panel consists of two thin, high-strength facings bonded to a thick, light-weight core. Each component by itself is relatively weak and flexible, but when it combind in a sandwich panel they produce a structure that is stiff, strong, and lightweight. In addition to use in honeycomb sandwich panels, honeycomb is used for energy absorption, radio frequency shielding, light diffusion, and to direct air flow.Accordingly, the usage of honeycomb sandwich structure is very widely applied to the aircraft, the automobile, and marine industry, etc., because of these advantages. Generally, this honeycomb sandwich structure is manufactured by autoclave process.In this study, the honeycomb sandwich structure was produced by prepreg. To prove the suitability the honeycomb sandwich structure with prepreg, The optimum design of the skin materials and honeycomb sandwich structure were evaluated with the theory of stress analysis.

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Micro CPL 제작을 위한 LIGA & MEMS 공정개발 (The development of LIGA & MEMS precess for fabricating micro CPL)

  • 조진우;정석원;박준식;박순섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 하계학술대회 논문집 C
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    • pp.1976-1978
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    • 2002
  • micro CPL 제작을 위한 LICA 및 MEMS 공정을 개발하였으며 양산화를 위한 새로운 방법으로 ${\mu}$MIM(micro Metal Injection Molding) 기술을 제안하였다. 먼저 LIGA 기술을 이용하여 Cu 도금 구조물로 이루어진 micro CPL 구조물을 제작하였다. 각각 상판과 하판 구조물로 나누어 제작하였으며 상, 하판 Cu 구조물을 brazing 방법을 이용하여 접합하였다. 또한 micro CPL 내부에서 일어나는 냉매의 흐름 및 상변화(liquid ${\leftrightarrow}$ vapor) 거동을 관찰할 수 있는 새로운 개념의 Si/glass 투명 micro CPL을 제작하였다. 상기 공정을 이용하여 냉각 능력이 10w/$cm^2$ 이상인 micro CPL을 제작하였다. 상기 연구 결과를 바탕으로 양산화를 위한 새로운 정밀복제기술인 ${\mu}$MIM(Micro Metal Injection Molding) 공정을 개발하였다. LISA 공정으로 제작된 정밀 금형을 core금형으로 사용하였고 $1{\mu}m$ 이하의 W-Cu(10%) powder와 binder가 혼합된 흔합분말을 이용하여 micro channel 구조물(선폭 $100{\mu}m$)의 성형 복제에 성공함으로서 양산화를 향한 기반기술을 확립하였다.

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액체 및 초임계 이산화탄소를 이용한 제염법 (Decontaminatin Techniques using Liquid/Supercritical $CO_2$)

  • 박광헌;김홍두;김학원;고문성;윤청현
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2003년도 가을 학술논문집
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    • pp.650-654
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    • 2003
  • 원자력분야에서 방사성폐기물 처리 및 처분은 해결해야 할 중요한 문제가 된다. 보다 청정한 방법을 사용한 제염법이 요구되고 있다. 이산화탄소를 이용한 제염법은 두가지로 나눠지는데-킬레이트제를 이용한 방법과 에멀젼을 이용한 방법이다. 킬레이트제 방법은 시너지효과를 낼 수 있는 방안이 중요하다. 마이크로 에멀젼을 사용한 방법은 에멀젼 코어속에 산을 넣어 금속표면이나 토양에서 오염물질을 직접 꺼내는 방법이다. 표면제거율을 QCM을 사용하여 측정하였다. 에멀젼을 만드는데 사용된 계면활성제의 회수 방법에 대하여 아울러 논의하였다.

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인공경량골재의 표피층 구조가 흡수된 물의 방출속도에 미치는 영향 (Effect of Shell Structure of Artificial Lightweight Aggregates on the Emission Rate of Absorbed Water)

  • 강승구
    • 한국세라믹학회지
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    • 제45권11호
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    • pp.750-754
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    • 2008
  • The artificial aggregates with dense surface layer (shell) was fabricated and the dependence of water emission rate upon the shell structures was studied. The EAF dust containing many flux components and waste white clay with ignition loss of above 48% were used as for liquid phase and gas forming agents during a sintering process respectively. In addition, the shell structure was modified with various processes and the modification effect on water emission rate was analyzed. The pores under $10{\mu}m$ were found in the sintered artificial light aggregates and disappeared by incorporating to a bigger pore during re-sintering. The water emission rate in an initial step depended on a void content of aggregates filled in a bottle rather than a shell structure. But, after 7 days where the water emission of the aggregate with a shell is above 40%, the shell of aggregates suppressed the water emission. The core of aggregates was exposed and most shell was lost when crushed to smaller size so, the ability for suppressing water emission of the crushed aggregates decreased. The activation energy for the water emission was $3.46{\pm}0.25{\times}10^{-1}$J/mol for the most specimens showing that the activation energy is irrelevant to the pore size distribution and shell structure.

$Bi_2O_3$와 CaO 첨가에 따른 PLC용 자심 재료의 물성 (Dependence of the physical properties for magnetic core materials on the concentrations of $Bi_2O_3$ and CaO)

  • 안용운;이해연;김종령;김현식;오영우
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 초전도 자성체
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    • pp.64-67
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    • 2002
  • The Physical and magnetic properties such as microstructure, permeability and power loss of Ni-Zn ferrite with composition of $Ni_{0.8}Zn_{0.2}Fe_2O_4$, were investigated as the function of $Bi_2O_3$ and CaO contents. The power loss increased in proportion to the amount of $Bi_2O_3$ up to 0.3 wt% but it decreased over than 0.3 wt% addition. The highest permeability of 134 was obtained to the specimen added 1.0 wt% $Bi_2O_3$ since $Bi_2O_3$ contents were strongly dominant to grain growth and size than that of CaO. $Bi_2O_3$ liquid phase created during sintering process promoted sintering and grain growth so that grain size and permeability increased compared to that of the specimens which were sintered with free-additive and CaO. Also, lots of pores existed in the specimen which was added $Bi_2O_3$ wt% with the biggest grain size.

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EVALUATION OF THE APPLICABLE REACTIVITY RANGE OF A REACTIVITY COMPUTER FOR A CANDU-6 REACTOR

  • Lee, Eun Ki;Park, Dong Hwan;Lee, Whan Soo
    • Nuclear Engineering and Technology
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    • 제46권2호
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    • pp.183-194
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    • 2014
  • Recently, a CANDU digital reactivity computer system (CDRCS) to measure the worth of the liquid zone controller in a CANDU-6 was developed and successfully applied to a physics test of refurbished Wolsong Unit 1. In advance of using the CDRCS, its measureable reactivity range should be investigated and confirmed. There are two reasons for this investigation. First, the CANDU-6 has a larger reactor and smaller excore detectors than a general PWR and consequently the measured reactivity is likely to reflect the peripheral power variation only, not the whole core. The second reason is photo neutrons generated from the interaction of the moderator and gamma-rays, which are never considered in a PWR. To evaluate the limitations of the CDRCS, several tens of three-dimensional steady and transient simulations were performed. The simulated detector signals were used to obtain the dynamic reactivity. The difference between the dynamic reactivity and the static worth increases in line with the water level changes. The maximum allowable reactivity was determined to be 1.4 mk in the case of CANDU-6 by confining the difference to less than 1%.