• Title/Summary/Keyword: Liquefaction system

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Effect of Various Types of Acid Catalysts on Phenol Liquefaction of Pinus densiflora Bark (소나무 수피의 페놀액화에 대한 다양한 산 촉매의 효과)

  • 문성필;로경란;이종문
    • Journal of Korea Foresty Energy
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    • v.21 no.3
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    • pp.1-9
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    • 2002
  • Various types of acids, such as mineral acids, organic acids, and organic sulfonic acids, were used as catalysts in order to investigate their effectiveness during phenol liquefaction of pine bark. Hydrochloric arid was the most effective acid catalyst of the mineral acids used in this experiment for the phenol liquefaction, but the amount of the acid needed for more than 90% liquefaction was at least 11 mmol. Among the carboxylic acids used triflouroacetic acid (TFA) was effective for the liquefaction, but it was not possible to obtain liquefaction of more than 80%. Organic sulfonic acids, p-toluenesulfonic acid (PTSA) and methanesulfonic acid (MSA), showed remarkable effects for liquefaction, even in small amounts and at low liquefaction temperatures. Especially in the case of PTSA, a 92% liquefaction yield was obtained at the liquefaction condition of 14$0^{\circ}C$ for 2 h. Therefore, it was evident that the PTSA is a good acid catalyst for the phenol-pine bark liquefaction system.

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Performance Improvement on the Re-Liquefaction System of Ethylene Carrier using Low-Global Warming Potential Refrigerants (Low - Global Warming Potential 냉매를 이용한 에틸렌 수송선의 재액화 시스템 성능개선)

  • Ha, Seong-Yong;Choi, Jung-Ho
    • Journal of the Society of Naval Architects of Korea
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    • v.55 no.5
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    • pp.415-420
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    • 2018
  • The development of sail gas has increased the production of ethane as well as natural gas. The decline in the market price for ethane has led to a change in the petroleum-based ethylene production process into an ethane-based ethylene production process and an increase in the ethane/ethylene trade volume. Large-scale ethane/ethylene carrier have been needed due to an increase in long-distance trade from the US, and cargo type change have leaded to consider a liquefaction process to re-liquefy Boil-Off gas generated during the voyage. In this paper, the liquefaction system of Liquefied Ethane Gas carrier was evaluated with Low-GWP (Low-Global Warming Potential) refrigerant and process parameters, Boil-Off Gas pressure and expansion valve outlet pressure, were optimized. Low-GWP refrigerants were propane (R290), propylene(R1270), carbon dioxide(R744) was considered at two type of liquefaction process such as Linde and cascade cycle. The results show that the optimal pressure point depends on the individual refrigerant and the highest liquefaction efficiency of carbon dioxide (R744) - propane (R290) refrigerant.

Physical modelling of soil liquefaction in a novel micro shaking table

  • Molina-Gomez, Fausto;Caicedo, Bernardo;Viana da Fonseca, Antonio
    • Geomechanics and Engineering
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    • v.19 no.3
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    • pp.229-240
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    • 2019
  • The physical models are useful to understand the soil behaviour. Hence, these tools allow validating analytical theories and numerical data. This paper addresses the design, construction and implementation of a physical model able to simulate the soil liquefaction under different cyclic actions. The model was instrumented with a piezoelectric actuator and a set of transducers to measure the porewater pressures, displacements and accelerations of the system. The soil liquefaction was assessed in three different grain size particles of a natural sand by applying a sinusoidal signal, which incorporated three amplitudes and the fundamental frequencies of three different earthquakes occurred in Colombia. In addition, such frequencies were scaled in a micro shaking table device for 1, 50 and 80 g. Tests allowed identifying the liquefaction susceptibility at various frequency and displacement amplitude combinations. Experimental evidence validated that the liquefaction susceptibility is higher in the fine-grained sands than coarse-grained sands, and showed that the acceleration of the actuator controls the phenomena trigging in the model instead of the displacement amplitude.

Comparison of Liquefaction Assessment Results with regard to Geotechnical Information DB Construction Method for Geostatistical Analyses (지반 보간을 위한 지반정보DB 구축 방법에 따른 액상화 평가 결과 비교)

  • Kang, Byeong-Ju;Hwang, Bum-Sik;Bang, Tea-Wan;Cho, Wan-Jei
    • Journal of the Korean Geotechnical Society
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    • v.38 no.4
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    • pp.59-70
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    • 2022
  • There is a growing interest in evaluating earthquake damage and determining disaster prevention measures due to the magnitude 5.8 earthquake in Pohang, Korea. Since the liquefaction phenomena occurred extensively in the residential area as a result of the earthquake, there was a demand for research on liquefaction phenomenon evaluation and liquefaction disaster prediction. Liquefaction is defined as a phenomenon where the strength of the ground is completely lost due to a sudden increase in excess pore water pressure caused due to large dynamic stress, such as an earthquake, acting on loose sand particles in a short period of time. The liquefaction potential index, which can identify the occurrence of liquefaction and predict the risk of liquefaction in a targeted area, can be used to create a liquefaction hazard map. However, since liquefaction assessment using existing field testing is predicated on a single borehole liquefaction assessment, there has been a representative issue for the whole targeted area. Spatial interpolation and geographic information systems can help to solve this issue to some extent. Therefore, in order to solve the representative problem of geotechnical information, this research uses the kriging method, one of the geostatistical spatial interpolation techniques, and constructs a geotechnical information database for liquefaction and spatial interpolation. Additionally, the liquefaction hazard map was created for each return period using the constructed geotechnical information database. Cross validation was used to confirm the accuracy of this liquefaction hazard map.

Thermodynamic Analysis of Re-liquefaction Cycle of LNG Boil-off Gas (LNG 증발기체의 재액화 사이클에 대한 열역학 해석)

  • Chin, Young-Wook;Moon, Jeong-Woo;Lee, Yoon-Pyo;Chang, Ho-Myung
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.19 no.7
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    • pp.485-490
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    • 2007
  • The LNG BOG re-liquefaction system for LNG carriers was designed based on the Claude refrigeration cycle and the thermodynamic analysis was carried out in order to find the design point of the three heat exchangers constituting the system. The thermodynamic analysis revealed that the system state could be defined by the three cold endpoint temperatures of the three-pass heat exchanger. Hence the iso-lines of the specific liquefaction work, taken as the performance indicator, were presented in terms of those three temperatures and discussed. The system was found most economical when those three temperatures approached a single temperature of $-140^{\circ}C$ and thus this system state could be taken as the design point for the heat exchangers.

Process Simulation of the BOG Re-Liquefaction system for a Floating LNG Power Plant using Commercial Process Simulation Program (상용 공정시뮬레이션 프로그램을 이용한 부유식 LNG 발전설비의 BOG 회수시스템 공정모사)

  • Seo, Ju-Wan;Yoo, Seung-Yeol;Lee, Jae-Chul;Kim, Young-Hun;Lee, Soon-Sup
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.6
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    • pp.732-741
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    • 2020
  • Environmental regulations have recently been strengthened. Consequently, floating LNG(Liquefied Natural Gas) power plants are being developed, which are new power generation plants that generate electricity by utilizing LNG. A floating LNG power plant generates BOG(Boil-Off Gas) during its operation, and the system design of such a plant should be capable of removing or re-liquefying BOG. However, the design of an offshore plant differs according to the marine requirements. Hence, a process simulation model of the BOG re-liquefaction system is needed, which can be continuously modified to avoid designing the floating LNG power plant through trial and error. In this paper, to develop a model appropriate for the floating LNG power plant, a commercial process simulation program was employed. Depending on the presence of refrigerants, various BOG re-liquefaction systems were modeled for comparing and analyzing the re-liquefaction rates and liquid points of BOG. Consequently, the BOG re-liquefaction system model incorporating nitrogen refrigerants is proposed as the re-liquefaction system model for the floating LNG power plant.

Performance Analysis of a Hydrogen Liquefaction System using Commercial Cryogenic Refrigerators for Precooling (상용 극저온 냉동기를 예냉기로 채택한 수소액화 시스템의 성능 해석)

  • Kim, Seung-Hyun;Chang, Ho-Myung;Kang, Byung Ha
    • Transactions of the Korean hydrogen and new energy society
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    • v.9 no.2
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    • pp.53-64
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    • 1998
  • Thermal analysis on a Linde-Hampson hydrogen liquefaction system using cryogenic refrigerators as precooling has been carried out. Three commercially available models of cryogenic refrigerators, such as CTI l020CP, CVI CGR009 and CVI CGR011, are considered in the performance analysis. The effect of ortho-para conversion process during hydrogen liquefaction is also studied in detail. The results obtained indicate that the optimal hydrogen mass flow rate and the optimal compressed pressure exist for the maximum hydrogen liquefaction rate. The optimal compressed pressure is increased in the range of 80 - 120 bar with an increase in the hydrogen mass flow rate. It is also found that better performance could be obtained with a cryogenic refrigerator, which produces high cooling capacity at precooling temperature in the range of 80 - 100 K.

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Information Geo-Technology for Seismic Analysis (내진해석을 고려한 정보화 시공)

  • Park, Inn-Joon;Kim, Soo-Il;Seo, Kyung-Bum;Park, Seong-Yong
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.10a
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    • pp.92-104
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    • 2005
  • Over the past decade, major advances have occurred in both understanding and practice with regard to assessment and mitigation of hazard area associated with seismically induced soil liquefaction. In this paper, assessment of liquefaction resistance of soil are reviewed from the recent researches. In addition site characteristics investigation methods and tests for seismic design and liquefaction analysis are reviewed. Finally, introduction and characteristics of remedial measures against soil liquefaction are reviewed briefly.

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Development of Mapping Method for Liquefaction Hazard in Moderate Seismic Region Considering the Uncertainty of Big Site Investigation Data (빅데이터 지반정보의 불확실성을 고려한 중진지역에서의 액상화 위험도 작성기법 개발)

  • Kwak, Minjung;Ku, Taijin;Choi, Jaesoon
    • Journal of the Korean GEO-environmental Society
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    • v.16 no.1
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    • pp.17-27
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    • 2015
  • Recently, Korean government has tried out to set up earthquake hazards prevention system. In the system, several geotechnical hazard maps including liquefaction hazard map and landslide hazard map for the whole country have drawn to consider the domestic seismic characteristics. To draw the macro liquefaction hazard map, big data of site investigations in metropolitan areas and provincial areas has to be verified for its application. In this research, we carried out site response analyses using 522 borehole site investigation data in S city during a desirable earthquake. The soil classification was separately compared to shear wave velocity considering the uncertainty of site investigation data. Probability distribution and statistical analysis for the results of site response analyses was applied to the feasibility study. Finally, we suggest a new site amplification coefficient, hereby presented with the similar results of liquefaction hazard mapping using the calculated liquefaction potential index by the site response analyses. Above-mentioned study will be expected to help to follow research and draw liquefaction hazard map in moderate seismic region.

Assessment of Liquefaction Potential on Non-Plastic Silty Soil Layers Using Geographic Information System(GIS) and Standard Penetration Test Results (지리정보시스템 및 표준관입시험 결과를 이용한 비소성 실트질 지반의 액상화 평가)

  • Yoo, Si-Dong;Kim, Hong-Taek;Song, Byung-Woong;Lee, Hyung-Kyu
    • Journal of the Korean GEO-environmental Society
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    • v.6 no.2
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    • pp.5-14
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    • 2005
  • In the present study, the liquefaction potential in the area of the Incheon international airport was assessed by applying the data of both standard penetration tests and laboratory tests to the modified Seed & Idriss method. The analysis was performed against the non-plastic silty soil layer and silty sand soil layer existing within the depth of 20m and under the ground water level, having the standard penetration value(N) of below 20. Also, each set of data was mapped using the GIS(Geographic Information System) and the safety factor against the liquefaction potential ($FS_{liquefaction}$) was obtained by overlapping those layers. Throughout the analysis, it was found that there exists a potential hazard zone for the liquefaction, showing partially that the safety factor against the liquefaction potential is 1.0 to 1.5 below the standard safety factor criterion. It is further thought to be necessary that the liquefaction potential for the corresponding hazard zone be additionally assessed in detail.

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