• Title/Summary/Keyword: Liquefaction process

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Comparative Research on the Carbon Dioxide Liquefaction Using Several Refrigerants (몇 가지 냉매를 사용한 이산화탄소 액화에 대한 비교 연구)

  • ILSU PARK;PHILSUNG HWANG;KICHEOL JUNG;JUNESHU ANH;JUNGHO CHO
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.2
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    • pp.226-233
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    • 2023
  • In this study, we compared the performance of several refrigeration cycles using different refrigerants and utilizing the cold heat of liquefied natural gas (LNG) for the liquefaction of carbon dioxide. The final conditions for the liquefied CO2 were set to -20℃ and 20 bar. The refrigerants used included R404a, ammonia, propane, and propylene using a vapor recompression refrigeration cycle. For the refrigeration cycle, the CO2 at room temperature and pressure was compressed in a two-stage compression process with an intermediate cooling stage using a refrigeration unit. To compare with the liquefaction process using refrigeration, we compressed the CO2 to 8 bar in a single compression stage and cooled it to around -50℃ using the cold heat of the LNG before liquefying it. Results showed that using ammonia as the refrigerant required the least amount of compressor power for the liquefaction process, and the heat transfer area of the evaporator was the smallest when using propylene as the refrigerant. Using the cold heat of LNG instead of refrigeration using R404a resulted in approximately 69% less energy consumption.

Design and Analysis of Hydrogen Production and Liquefaction Process by Using Liquefied Natural Gas (액화천연가스(LNG)를 사용한 수소 생산 및 액화 공정 개발)

  • Noh, Wonjun;Park, Sihwan;Lee, Inkyu
    • Korean Chemical Engineering Research
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    • v.59 no.2
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    • pp.200-208
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    • 2021
  • Compare to the gaseous hydrogen, liquid hydrogen has various advantages: easy to transport, high energy density, and low risk of explosion. However, the hydrogen liquefaction process is highly energy intensive because it requires lots of energy for refrigeration. On the other hand, the cold energy of the liquefied natural gas (LNG) is wasted during the regasification. It means there are opportunities to improve the energy efficiency of the hydrogen liquefaction process by recovering wasted LNG cold energy. In addition, hydrogen production by natural gas reforming is one of the most economical ways, thus LNG can be used as a raw material for hydrogen production. In this study, a novel hydrogen production and liquefaction process is proposed by using LNG as a raw material as well as a cold source. To develop this process, the hydrogen liquefaction process using hydrocarbon mixed refrigerant and the helium-neon refrigerant is selected as a base case design. The proposed design is developed by applying LNG as a cold source for the hydrogen precooling. The performance of the proposed process is analyzed in terms of energy consumption and exergy efficiency, and it is compared with the base case design. As the result, the proposed design shows 17.9% of energy reduction and 11.2% of exergy efficiency improvement compare to the base case design.

Process Simulation of the BOG Re-Liquefaction system for a Floating LNG Power Plant using Commercial Process Simulation Program (상용 공정시뮬레이션 프로그램을 이용한 부유식 LNG 발전설비의 BOG 회수시스템 공정모사)

  • Seo, Ju-Wan;Yoo, Seung-Yeol;Lee, Jae-Chul;Kim, Young-Hun;Lee, Soon-Sup
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.6
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    • pp.732-741
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    • 2020
  • Environmental regulations have recently been strengthened. Consequently, floating LNG(Liquefied Natural Gas) power plants are being developed, which are new power generation plants that generate electricity by utilizing LNG. A floating LNG power plant generates BOG(Boil-Off Gas) during its operation, and the system design of such a plant should be capable of removing or re-liquefying BOG. However, the design of an offshore plant differs according to the marine requirements. Hence, a process simulation model of the BOG re-liquefaction system is needed, which can be continuously modified to avoid designing the floating LNG power plant through trial and error. In this paper, to develop a model appropriate for the floating LNG power plant, a commercial process simulation program was employed. Depending on the presence of refrigerants, various BOG re-liquefaction systems were modeled for comparing and analyzing the re-liquefaction rates and liquid points of BOG. Consequently, the BOG re-liquefaction system model incorporating nitrogen refrigerants is proposed as the re-liquefaction system model for the floating LNG power plant.

Study on the Improvement of Efficiency in Dehydration Process of LNG Liquefaction Plant Using Molecular Sieve (분자체를 이용한 LNG 액화 플랜트 탈수 공정의 효율성 향상에 관한 연구)

  • JONGHWA PARK;DONSANG YU;DAEMYEONG CHO
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.1
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    • pp.105-113
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    • 2024
  • The natural gas dehydration process plays a central role in liquefying LNG. This study proposes two natural gas dehydration process systems applicable to liquefied natural gas (LNG) liquefaction plants, and compares and analyzes energy optimization measures through simulation. The fuel gas from feed stream (FFF) case, which requires additional equipment for gas circulation, disadvantages are design capacity and increased energy. On the other hand, the end flash gas (EFG) case has advantages such as low initial investment costs and no need for compressors, but has downsides such as increased power energy and the use of gas with different components. According to the process simulation results, the required energy is 33.22 MW for the FFF case and 32.86 MW for the EFG case, confirming 1.1% energy savings per unit time in the EFG case. Therefore, in terms of design pressure, capacity, device configuration, and required energy, the EFG case is relatively advantageous. However, further research is needed on the impact of changes in the composition of regenerated gas on the liquefaction process and the fuel gas system.

Case Studies for Optimizing Energy Efficiency of Propane Cycle Pressure Levels on C3-MR Process (C3-MR 공정의 프로판 사이클 압력 레벨에 따른 에너지효율 최적화를 위한 사례연구)

  • Lee, In-Kyu;Tak, Kyung-Jae;Lim, Won-Sub;Moon, Il;Kim, Hak-Sung;Choi, Kwang-Ho
    • Journal of the Korean Institute of Gas
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    • v.15 no.6
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    • pp.38-43
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    • 2011
  • Natural gas liquefaction process runs under cryogenic condition, and it spends large amount of energy. Minimizing energy consumption of natural gas liquefaction process is an important issue because of its physical characteristics. Among many kinds of natural gas liquefaction processes, C3-MR(Propane Pre-cooled Mixed Refrigerant) process uses two kind of refrigerants. One is the propane as the pure refrigerant(PR) and the other is the mixed refrigerant(MR). In this study, to find the optimal compressing level, propane cycle is simulated on different pressure level. The case study result shows relationship between energy consumption and pressure level. As a result, the conclusion is that at a higher pressure level, process consumes lower energy. At 5 pressure-levels, energy consumption is 23.7% lower than 3 pressure-levels.

Basic Design of 36 MTD Class Natural Gas BOG Re-Liquefaction System (36 MTD급 천연가스 BOG 재액화 플랜트 기본설계)

  • Ko, Junseok;Park, Seong-Je;Kim, Ki-Duck;Hong, Yong-Ju;Koh, Deuk-Yong;Kim, Hyobong;Yeom, Hankil
    • Transactions of the KSME C: Technology and Education
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    • v.1 no.1
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    • pp.99-105
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    • 2013
  • In this paper, we carried out the basic design of 36 MTD natural gas BOG re-liquefaction system to recover the generated natural gas during performance test of LNG pump and natural gas compressor. The re-liquefaction process of natural gas is designed to have 1500 kg/h of liquefaction rate with reverse Brayton refrigeration cycle. With the designed process, the variation of liquefaction rate is calculated for various inlet conditions of feed gas. From results, the liquefaction rate is more sensitive for inlet temperature than gas composition. The specifications of equipments such as gas blower, natural gas compressor, cryogenic heat exchanger and nitrogen compander are determined on the basis of the designed process. The requirement of power consumption and cooling water are also determined through the basic design.

Multi-floor Layout for the Liquefaction Process Systems of LNG FPSO Using the Optimization Technique (최적화 기법을 이용한 LNG FPSO 액화 공정 장비의 다층 배치)

  • Ku, Nam-Kug;Lee, Joon-Chae;Roh, Myung-Il;Hwang, Ji-Hyun;Lee, Kyu-Yeul
    • Journal of the Society of Naval Architects of Korea
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    • v.49 no.1
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    • pp.68-78
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    • 2012
  • A layout of an LNG FPSO should be elaborately determined as compared with that of an onshore plant because many topside process systems are installed on the limited area; the deck of the LNG FPSO. Especially, the layout should be made as multi-deck, not single-deck and have a minimum area. In this study, a multi-floor layout for the liquefaction process, the dual mixed refrigerant(DMR) cycle, of LNG FPSO was determined by using the optimization technique. For this, an optimization problem for the multi-floor layout was mathematically formulated. The problem consists of 589 design variables representing the positions of topside process systems, 125 equality constraints and 2,315 inequality constraints representing limitations on the layout of them, and an objective function representing the total layout cost. To solve the problem, a hybrid optimization method that consists of the genetic algorithm(GA) and sequential quadratic programming(SQP) was used in this study. As a result, we can obtain a multi-floor layout for the liquefaction process of the LNG FPSO which satisfies all constraints related to limitations on the layout.

Liquefaction and Saccharification Conditions of Potatoes for Alcohol Fermentation Using Potatoes (감자 알콜발효를 위한 액화 및 당화조건)

  • 정용진;서지형;윤성란;이진만;이기동;김옥미;방광웅
    • Food Science and Preservation
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    • v.7 no.1
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    • pp.94-98
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    • 2000
  • To produce liquor and vinegar using potatoes needs to liquefy and sacchrify potatoes . So selecting the efficient fermenter for proceeding these process successfully is very important . This study was investigated several fermenter and crush types of potatoes for alcohol fermentation. Final sugar contents was high in pottoes saccharificatiion by nuruk or crude enzyme. But pure enzyme and blucoamylase ended liquefaction and saccharificatiion within short ime. So complex type fermenter mixed several fermenters was superior to single type fermenter. Complexfermenter III using crude enzyme and glucoamyulase saccharificed excellently potatoes with 150% of water contents by treatment of 3 hours. Through alcohol fermentation using pressure steamed potatoes (PSP), it could be obtained 6.4% , 150%, of alcohol content and yield. However to perform a series process efficiently , crush steamed pottoes (CSP) was suitable. When it was fermented after saccharification using crush steamed potatoes and complex fermenter III, it could be obtained 6.6% of alcohol and 6.7% of acidity.

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Design of BOG re-liquefaction system of 20,000 m3 liquid hydrogen carrier

  • Byeongchang Byeon;Hwalong You;Dongmin Kim;Keun Tae Lee;Mo Se Kim;Gi Dock Kim;Jung Hun Kim;Sang Yoon Lee;Deuk Yong Koh
    • Progress in Superconductivity and Cryogenics
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    • v.25 no.3
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    • pp.49-55
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    • 2023
  • This paper presents the design of a re-liquefaction system as a BOG (boil-off gas) handling process in liquid hydrogen transport vessels. The total capacity of the re-liquefaction system was assumed to be 3 ton/day, with a BOR (boil-off rate) of 0.2 %/day inside the cargo. The re-liquefaction cycle was devised using the He-Brayton Cycle, incorporating considerations of BOG capacity and operational stability. The primary components of the system, such as compressors, expanders, and heat exchangers, were selected to meet domestically available specifications. Case studies were conducted based on the specifications of the components to determine the optimal design parameters for the re-liquefaction system. This encompassed variables such as helium mass flow rate, the number of compressors, compressor inlet pressure and compression ratio, as well as the quantity and composition of expanders. Additionally, an analysis of exergy destruction and exergy efficiency was carried out for the components within the system. Remarkably, while previous design studies of BOG re-liquefaction systems for liquid hydrogen vessels were confined to theoretical and analytical realms, this research distinguishes itself by accounting for practical implementation through equipment and system design.

Performance Analysis of a Hydrogen Liquefaction System using Commercial Cryogenic Refrigerators for Precooling (상용 극저온 냉동기를 예냉기로 채택한 수소액화 시스템의 성능 해석)

  • Kim, Seung-Hyun;Chang, Ho-Myung;Kang, Byung Ha
    • Transactions of the Korean hydrogen and new energy society
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    • v.9 no.2
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    • pp.53-64
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    • 1998
  • Thermal analysis on a Linde-Hampson hydrogen liquefaction system using cryogenic refrigerators as precooling has been carried out. Three commercially available models of cryogenic refrigerators, such as CTI l020CP, CVI CGR009 and CVI CGR011, are considered in the performance analysis. The effect of ortho-para conversion process during hydrogen liquefaction is also studied in detail. The results obtained indicate that the optimal hydrogen mass flow rate and the optimal compressed pressure exist for the maximum hydrogen liquefaction rate. The optimal compressed pressure is increased in the range of 80 - 120 bar with an increase in the hydrogen mass flow rate. It is also found that better performance could be obtained with a cryogenic refrigerator, which produces high cooling capacity at precooling temperature in the range of 80 - 100 K.

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