• Bulletin of the Korean Chemical Society
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• 제34권11호
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• pp.3199-3205
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• 2013

The inclusion behavior of sulfobutylether-${\beta}$-cyclodextrin (SBE-${\beta}$-CD) with perphenazine (PPH) was first studied by flow injection (FI)-chemiluminescence (CL) analysis with proposed $lg[(I_0-I_s)/I_s]=lgK_{P-CD}+nlg[C_{PPH}]$ model and molecular docking. Results showed that a 1:1 complex of SBE-${\beta}$-CD/PPH could online form, with the formation constant $K_{P-CD}$ of $2.57{\times}10^7Lmol^{-1}$ at 298 K. The thermodynamic parameters showed that the inclusion behavior of SBE-${\beta}$-CD/PPH was a spontaneous process by hydrophobic interaction. The molecular docking results revealed PPH entered into the larger cavity of SBE-${\beta}$-CD with two hydrogen bonds. Based on the linear relationship of the decrement of luminol/SBE-${\beta}$-CD/PPH CL intensity against the logarithm of PPH concentration ranging from 0.03 to 30.0 ng $mL^{-1}$, the present FI-CL analysis using luminol/SBE-${\beta}$-CD/PPH system was successfully applied to PPH determination in biological fluids and tablets with recoveries from 94.5 to 105.6% and RSDs less than 2.6% (n = 5).

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2011년도 정기 학술대회
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• pp.531-538
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• 2011

멤브레인형 LNG 탱크의 구조적 안전성을 확보하기 위해서는 슬로싱에 의한 작용 압력과 구조응답을 정확히 평가할 수 있어야 한다. 탱크 방열구조에 작용하는 슬로싱 충격하중은 매우 불규칙적이며 이로 인한 구조 응답 역시 유탄성 거동을 포함하는 매우 복잡한 물리 현상이기 때문에 최신의 이론적 실험적 접근 방법을 동원하더라도 정확한 평가가 어렵다. 본 연구에서는 실험이나 수치해석으로부터 얻어진 슬로싱 압력 시계열을 이용하여 탱크 방열 구조의 구조응답을 간편하게 해석할 수 있는 방안을 제안하였다. 이 간이 해석법은 기본적인 삼각형 impulse 형태의 충격 압력에 대한 구조응답을 시간영역에서 과도응답해석법으로 계산한 후, 이렇게 구해진 구조물의 삼각형 응답함수를 조합하여 임의 형상의 압력 시계열에 대한 구조 응답을 구하는 방식이다. 여러 가지 예제 해석을 통하여 제안된 해석법의 타당성을 검토하였고, 이를 이용하여 실제 모형실험에서 얻어진 압력시계열을 바탕으로 구조응답을 계산하고 그 결과를 고찰하였다.

• Nuclear Engineering and Technology
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• 제46권6호
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• pp.837-846
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• 2014

A lead slowing down spectrometer (LSDS) is under development for analysis of isotopic fissile material contents in pyro-processed material, or spent fuel. Many current commercial fissile assay technologies have a limitation in accurate and direct assay of fissile content. However, LSDS is very sensitive in distinguishing fissile fission signals from each isotope. A neutron spectrum analysis was conducted in the spectrometer and the energy resolution was investigated from 0.1eV to 100keV. The spectrum was well shaped in the slowing down energy. The resolution was enough to obtain each fissile from 0.2eV to 1keV. The detector existence in the lead will disturb the source neutron spectrum. It causes a change in resolution and peak amplitude. The intense source neutron production was designed for ~E12 n's/sec to overcome spent fuel background. The detection sensitivity of U238 and Th232 fission chamber was investigated. The first and second layer detectors increase detection efficiency. Thorium also has a threshold property to detect the fast fission neutrons from fissile fission. However, the detection of Th232 is about 76% of that of U238. A linear detection model was set up over the slowing down neutron energy to obtain each fissile material content. The isotopic fissile assay using LSDS is applicable for the optimum design of spent fuel storage to maximize burnup credit and quality assurance of the recycled nuclear material for safety and economics. LSDS technology will contribute to the transparency and credibility of pyro-process using spent fuel, as internationally demanded.

• Bulletin of the Korean Chemical Society
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• 제34권10호
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• pp.2983-2988
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• 2013

Second-order rate constants ($k_N$) have been measured spectrophotometrically for the reactions of 4-chloro-2-nitrophenyl X-substituted-benzoates (1a-1h) with a series of cyclic secondary amines in 80 mol % $H_2O$/20 mol % DMSO at $25.0{\pm}0.1^{\circ}C$. The Hammett plot for the reactions of 1a-1h with piperidine consists of two intersecting straight lines, while the Yukawa-Tsuno plot exhibits an excellent linear correlation with ${\rho}_X $ = 1.25 and r = 0.58, indicating that the nonlinear Hammett plot is not due to a change in the rate-determining step (RDS) but is caused by ground-state stabilization through resonance interactions for substrates possessing an electron-withdrawing group in the benzoyl moiety. The Br${\o}$nsted-type plot for the reactions of 4-chloro-2-nitrophenyl benzoate (1d) with a series of cyclic secondary amines curves downward with ${\beta}_2$ = 0.85, ${\beta}_1$ = 0.24, and $pK_a{^o}$ = 10.5, implying that a change in RDS occurs from the $k_2$ step to the $k_1$ process as the $pK_a$ of the conjugate acid of the amine exceeds 10.5. Dissection of $k_N$ into the microscopic rate constants $k_1$ and $k_2/k_{-1}$ ratio associated with the reaction of 1d reveals that $k_2$ is dependent on the amine basicity, which is contrary to generally held views.

• 전산구조공학
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• 제11권1호
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• pp.205-216
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• 1998

본 논문에서는 중복근을 갖는 비비례 감쇠시스템의 고유치 해석 방법을 제안하였다. 2차 고유치 문제의 행렬 조합을 통한 선형 방정식에 수정된 Newton-Raphson기법과 고유벡터의 직교성을 적용하여 제안방법의 알고리즘을 유도하였다. 벡터 반복법 또는 부분공간 반복법과 같은 기존의 반복법에서는 수렴성을 향상시키기 위해 변위법을 적용하였으며, 이 값이 시스템의 고유치에 근사하게 되면 행렬분해 과정에서 특이성이 발생한다. 그러나 제안방법은 구하고자 하는 고유치가 중복근이 아닐 경우에, 변위값이 시스템의 고유치 일지라도 항상 정칙성을 유지하며, 이것을 해석적으로 증명하였다. 제안방법은 수정된 Newton-Raphson기법을 이용하기 때문에 초기값을 필요로 한다. 제안방법의 초기값으로는 반복법의 중간결과나 근사법의 결과를 사용할 수 있다. 이들 방법중 Lanczon방법이 가장 효율적으로 좋은 초기값을 제공하기 때문에 Lanczon방법의 결과를 제안방법의 초기값으로 사용하였다. 제안방법의 효율성을 증명하기 위하여 두가지 예제 구조물에 대해 해석시간 및 수렴성을 가장 많이 사용하고 있는 부분공간 반복법과 Lanczon방법의 결과와 비교하였다.

• 한국전산구조공학회:학술대회논문집
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• 한국전산구조공학회 2007년도 정기 학술대회 논문집
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• pp.577-582
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• 2007

A variational formulation for plane elasticity problems is derived based on an isogeometric approach. The isogeometric analysis is an emerging methodology such that the basis functions in analysis domain arc generated directly from NURBS (Non-Uniform Rational B-Splines) geometry. Thus. the solution space can be represented in terms of the same functions to represent the geometry. The coefficients of basis functions or the control variables play the role of degrees-of-freedom. Furthermore, due to h-. p-, and k-refinement schemes, the high order geometric features can be described exactly and easily without tedious re-meshing process. The isogeometric sensitivity analysis method enables us to analyze arbitrarily shaped structures without re-meshing. Also, it provides a precise construction method of finite element model to exactly represent geometry using B-spline base functions in CAD geometric modeling. To obtain precise shape sensitivity, the normal and curvature of boundary should be taken into account in the shape sensitivity expressions. However, in conventional finite element methods, the normal information is inaccurate and the curvature is generally missing due to the use of linear interpolation functions. A continuum-based adjoint sensitivity analysis method using the isogeometric approach is derived for the plane elasticity problems. The conventional shape optimization using the finite element method has some difficulties in the parameterization of boundary. In isogeometric analysis, however, the geometric properties arc already embedded in the B-spline shape functions and control points. The perturbation of control points in isogeometric analysis automatically results in shape changes. Using the conventional finite clement method, the inter-element continuity of the design space is not guaranteed so that the normal vector and curvature arc not accurate enough. On tile other hand, in isogeometric analysis, these values arc continuous over the whole design space so that accurate shape sensitivity can be obtained. Through numerical examples, the developed isogeometric sensitivity analysis method is verified to show excellent agreement with finite difference sensitivity.

• Macromolecular Research
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• 제17권6호
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• pp.378-387
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• 2009

This research compared three methods for producing and processing nanocomposite polypropylene filament yarns with permanent antimicrobial efficiency. The three methods used to mix antimicrobial agents based on silver nano particles with PP were as follows: 1) mixing of PP powder and inorganic nanocomposite filler with the appropriate concentration using a twin-screw extruder and preparing granules, 2) method 1 with a singlerather than twin-screw extruder, and 3) producing the masterbatch by a twin-screw extruder and blending it with PP in the melt spinning process. All pure polypropylene samples and other combined samples had an acceptable spinnability at the spinning temperature of $240^{\circ}C$ and take-up speed of 2,000 m/min. After producing as-spun filament yarns by a pilot plant, melt spinning machine, the samples were drawn, textured and finally weft knitted. The physical and structural properties (e.g., linear density, tenacity, breaking elongation, initial modulus, rupture work, shrinkage and crystallinity) of the as-spun and drawn yarns with constant and variable draw ratios (the variable draw ratio was used to gain a constant breaking elongation of 50%) were investigated and compared, while DSC, SEM and FTIR techniques were used to characterize the samples. Finally, the antibacterial efficiency of the knitted samples was evaluated. The experimental results revealed that the crystallinity reduction of the as-spun yarn obtained from method 1 (5%) was more than that of method 2 (3%), while the crystallinity of the modified as-spun yarns obtained with method 3 remained unchanged compared to pure yarn. However, the drawing procedure compensated for this difference. By applying methods 2 and 3, the drawing generally improved the tenacity and modulus of the modified fibers, whereas method 1 degraded the constant draw ratio. Although the biostatic efficiency of the nanocomposite yarns was excellent with all three methods, the modified fabrics obtained from methods 1 and 2 showed a higher bioactivity.

• 한국운동역학회지
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• 제20권2호
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• pp.139-148
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• 2010

The purpose of this study was to comparatively analyze the kinematic variables between the squash backhand and racquetball backhand strokes through three-dimensional cinematography. Three expert racquetball players and three expert squash players were involved in the data gathering process. The horizontal, vertical and lateral displacement of racket and trunk segment, intersegmental angular velocity of the wrist, elbow and shoulder joints, and the linear velocity of the racket were descriptively analyzed, and the followings were concluded. The racket of the squash backhand stroke showed an 'U' shaped movement where the racket moved rapidly downward and moved forward to make an impact and followed through to a front-top finish, while the racket of racquetball backhand stroke showed an 'O' shaped movement where the racket showed circular movement through the rear and bottom positions for the impact, and showed rotation through the lower-front and upper front to a upper-rear-ward finish during the follow-through. The peak velocity of racket was found before the impact point in the squash backhand stroke and at the impact point in the racquetball backhand stroke. For the final conclusion, for the squash backhand stoke, instructors might be better to make the racket move downward to make highest velocity before the impact and finished short follow-through, while for the racquetball backhand stroke, to make the racket move forward to make highest velocity at the impact and finished rather long follow-through.

• 한국자동차공학회논문집
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• 제14권3호
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• pp.125-132
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• 2006

Transient kinetics of $NH_3$ adsorption/desorption and of SCR(selective catalytic reduction) of NO with $NH_3$ were studied over vanadium based catalysts, such as $V_2O_5/TiO_2$ and $V_2O_5-WO_3/TiO_2$. In the present catalytic reaction process, NO adsorption is neglected while $NH_3$ is strongly chemisorbed on the catalytic surface. Accordingly, it is ruled out the possibility of a reaction between strongly adsorbed $NH_3$ and NO species in line with the hypothesis of an Eley-Rideal mechanism. The present kinetic model assumes; (1) non-activated $NH_3$ adsorption, (2) Temkin-type $NH_3$ coverage dependence of the desorption energy, (3) non-linear dependence of the SCR reaction rate on the $NH_3$ surface coverage. Thus, the surface heterogeneity for adsorption/desorption of $NH_3$ is taken into account in this model. The present study extends the pure chemical kinetic model based on a powdered-phase catalytic system to the chemico-physical one applicable to a realistic monolith reactor.

• Journal of Astronomy and Space Sciences
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• 제29권2호
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• pp.103-113
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• 2012

The ButterStar Observatory at the Dongducheon High School has been working for photographic observations of the Sun since October 16, 2002. In this study, we observed the Sun at the ButterStar observatory for 3,364 days from October 16, 2002 to December 31, 2011, and analyzed the photographic sunspot data obtained in 1,965 days. The correction factor $K_b$ for the entire observing period is 0.9519, which is calculated using the linear least square method to the relationship between the daily sunspot number, $R_B$, and the daily international relative sunspot number, $R_i$. The yearly correction factor calculated for each year varies slightly from year to year and shows a trend to change along the solar cycle. The correction factor is larger during the solar maxima and smaller during the solar minima in general. This implies that the discrepancy between a relative sunspot number, R, and the daily international relative sunspot number, $R_i$, can be reduced by using a yearly correction factor. From 2002 to 2008 in solar cycle 23, 35.4% and 64.6% of sunspot groups and 35.1% and 64.9% of isolated sunspots in average occurred in the northern hemisphere and in the southern hemisphere, respectively, and from 2008 to 2011 in solar cycle 24, 61.3% and 38.7% of sunspot groups and 65.0% and 35.0% of isolated sunspots were observed, respectively. This result shows that the occurrence frequency for each type of sunspot group changes along the solar cycle development, which can be interpreted as the emerging and decaying process of sunspot groups is different depending on the phase of solar cycle. Therefore, it is considered that a following study would contribute to the efforts to understand the dependence of the dynamo mechanism on the phase of solar cycle.