• 대한전기학회:학술대회논문집
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• 대한전기학회 2001년도 하계학술대회 논문집 B
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• pp.760-761
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• 2001

We have studied quench characteristics for current limiting elements of YBCO films in applied fields of 0 - 130 mT. The films were deposited on sapphire substrates and covered by gold top layer. The current limiting element consists of 2 mm wide YBCO stripes connected in series. The electric field - current density (E-J) measurements showed that the presence of applied magnetic fields induces uniform quench distribution for the stripes, otherwise non-uniform quenches were observed. We suggest that suppressing the critical current by increased fields due to fault current effectively forced the stripes of higher Jc(0) to quench, resulting in equalizing quench times.

• Progress in Superconductivity
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• 제5권2호
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• pp.128-131
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• 2004

The resistive superconducting fault current limiters (SFCLs) are very attractive devices for the electric power network. But they have some serious problems when the YBCO thin films were used for the current limiting materials due to the in homogeneities caused by manufacturing process. When the YBCO films have some inhomogeneities, simultaneous quenches are difficult to achieve when the fault current limiting units are connected in series for increasing operating voltage ratings. Magnetic field application is one of the prospective way of inducing simultaneous quenches far the series-connected resistive FCL components. Magnetic field was typically generated by the fault current thorough a coil, which is connected to components of the fault current limiter in series, leaving the problem, which provides significant inductance to the power line and suppresses critical current density of the superconducting components. In this article we investigated the possible application of the protective current transformer (p-CT), which is available current source to the magnetic coil. This system inductively coupled to the circuit, therefore, remarkably reducing impedance to the circuit. The current by the protective current transformer was directly fed to the coil, generating magnetic field large enough to reduce critical current density of the components. This successfully induced simultaneous quenches of the series-connected resistive FCL components.

• 한국표면공학회지
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• 제29권4호
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• pp.219-228
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• 1996

Neutral Zinc Electroplating(NZE) utilizing the electrolyte of pH 6 to 8 has advantages in waste treatment and the protection of equipment. NZE is beneficially used in chromating treatment, but the limiting current density and the current efficiency are low. Therefore this study is investigated to analyse the characteristics of NZE and to obtain high current density and current efficiency. The deposition potential of zinc in the NZE bath is about 110mV, which is lower than acidic bath. The current density possibily increases up to 60A/d$\m^2$ in lower complexing agent content and pH 6. More than 90% of cathodic current efficiency was obtained in NZE bath. The NZE morphology shows smaller grains than acidic bath. The addition of 4$m\ell$/1 second brightener gives finer morphology. As pH becomes higher, (002) plan decreases and (100), (101) and (110) planes increase in the no additives solution.

• 한국물환경학회지
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• 제27권1호
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• pp.54-60
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• 2011

To evaluate the feasibility of electrodialysis for copper removal from industrial wastewater, the effect of operating parameters on the removal of copper was experimentally estimated. The limiting current density (LCD) linearly increased with the copper concentration and the flow rate. The time when the copper concentration of diluate reaches to 3 mg/L was linearly proportional to initial concentration of diluate, and the concentration of concentrate did not affect the removal rate. Increase in the flow rate gave a positive effect on the removal rate and became insignificant at flow rates greater than 2.4 L/min. The removal rate increased with the applied voltage. From the operation of the electrodialysis module used in this research, the flow rate of 2.4 L/min and the voltage corresponding to the 80~90% of LCD were found be the optimum operating condition for the copper removal from highly concentrated copper solutions.

• 전기학회논문지
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• 제56권12호
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• pp.2078-2083
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• 2007

We have analyzed operating characteristics of transformer-type superconducting fault current limiter (SFCL) according to the serial or parallel connections of secondary coils with $YBa_2Cu_3O_7$ (YBCO) thin films. The turn ratio between the primary and secondary coils was 63:21. Transformer-type SFCL using a transformer with secondary winding of serial or parallel coils could reduce the unbalanced quench caused by differences of the critical current density between YBCO thin films. We found that transformer-type SFCL having serial or parallel connections induced simultaneous quench between the superconducting units. The limiting current in the transformer-type SFCL with a parallel connection was lowered to 30 % compared to the SFCL with a serial connection. In the meantime, when the currents generated in the superconducting units were similar, the voltage value in the parallel connection was 60 % as low as that in the serial connection. However, the voltage generated in the primary winding was some higher. In conclusion, we found that transformer-type SFCL with parallel connection of secondary coils was more effective in fault current limiting characteristics and in the reduction of the consumption power for superconducting units compared to those of the transformer-type SFCL with serial connection of secondary coils.

• 멤브레인
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• 제15권2호
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• pp.175-186
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• 2005

전기투석 공정에서 이온교환막 표면에 형성되는 스케일 영향을 조사하기 위해 장기간 동안 운전되었다. 탈염공정 동안, $Ca^{2+}$과 $SO_4^{2-}$ 이온의 농도는 농축실에서 연속적으로 증가하였으며 양이온교환막(Neosepta CMX)표면에 침전이 발생하였다. 초기 스케일 형성동안, 공정성능과 막 특성의 변화는 농축실 염농도 증가에 기인하여 일어나는 양이온교환막의 하계전류밀도가 감소하는 것을 제외하곤 미미하였다. 공정운전이 진행됨에 따라 양이온교환막의 한계전류밀도는 물의 해리 현상이 진행되어 $300\;A/m^2$까지 감소하였다. 막 오염은 농축실에서 양이온교환막 표면에 형성된 스케일과 물의 해리현상에 의해 유발된다는 결론을 얻었으며, 이러한 스케일 형성은 $CaSO_4$의 용해도에 의해 예측 가능한 것을 알 수 있었다.

• Membrane and Water Treatment
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• 제14권1호
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• pp.47-54
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• 2023

In this study, high concentrations of cadmium-containing wastewater were treated by electrodialysis (ED) with a channel stack. The limiting current density (LCD), cadmium removal efficiency, and current efficiency were investigated under each experimental condition according to the Reynolds number (Re), membrane area, and pH. With the increase in the film area to 111, 333, 555, and 777 cm² at Re (109.1), LCDs decreased to 408.11, 44.45, 35.32, and 13.64 A/m², respectively. The highest cadmium removal efficiency (99.6%) and current efficiency were obtained for the membrane area of 111 and 777 cm², respectively. Under changing Re in the pH range of 1 to 4, Re and LCD were proportional under the same pH condition, and pH and LCD tended to be inversely proportional under the same Re condition. Cadmium removal rate was the best at the pH range 3 - 4. It has been found that ED with channeled stacks can be successfully applied to treat wastewater containing high concentrations of cadmium.

• 전기화학회지
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• 제3권3호
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• pp.162-168
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• 2000

전기주석도금용 PSA(Phenolsulfonic Acid Bath)계 전기주석 도금액은 장기간 사용하면 노화되어 도금 전류밀도 범위 축소 및 표면특성 열화현상이 일어나게 된다. 본 연구에서는 도금액 노화 현상의 원인을 축적된 phenolsulfonate농도 증가의 관점에서 조사하였다. 동전위와 정전위 분극실험 결과에서는, phenolsulfonate축적농도 증가에 따른 도금액의 노화 정도가 증가함에 따라 음극분극 초기에 나타나는 한계전류밀도가 점차 낮아지는 현상이 나타났다. Sodium phenolsulfonate를 첨가하여 phenolsulfonate끼 농도만을 조절한 도금액에서도 노화된 도금액과 거의 비슷한 분극 특성이 나타남으로써 도금액 노화의 원인이 축적된 phenolsulfonate임을 간접적으로 확인할 수 있었다. 또한 도금액의 온도가 증가할수록 한계전류밀도가 뚜렷하게 나타나지 않고 도금액 노화에 따른 영향이 적어져서 도금액의 노화는 물질이동과 같은 thermally-activated process의 제약에 의한 것이며, phenolsulfonate가 축적되면서 주석 이온의 mobility를 감소시키고, 따라서 정상적인 도금 반응이 억제되는 것으로 판단된다.

• Journal of Advanced Marine Engineering and Technology
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• 제29권5호
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• pp.495-501
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• 2005

Al is a active metal that owes its resistance to a thin, protective, barrier oxide surface layer, which is stable in air and neutral aqueous solution. Thus Al alloys are widely used in architectural trim. cold & hot-water storage vessels and piping. However Al and most of its alloy may corrode with some forms such as pitting corrosion, intergranular corrosion and galvanic corrosion in the case of exposure to various industrial and marine atmosphere. Therefore a correct evaluation of corrosion resistance for their Al and Al alloys may be more important in a economical point of view. In this study. a relative evaluation of corrosion resistance for three kinds of Al alloys such as ALDC2, ALDC3, and ALDC8 series was carried out with electrochemical method. There is a tendency that corrosion potential is shifted to positive or negative direction by alloying components regardless of corrosion resistance. Moreover the data of corrosion properties obtained from cathodic Polarization curve, cyclic voltammogram and AC. DC impedance respectively showed a good correspondence each other against the corrosion resistance but variation of corrosion potential. passivity current density of anodic polarization curve and corrosion current density by Tafel extrapolation and Stern-Geary method didn't correspond with not only each other but also considerably the data of corrosion properties discussed above. Therefore it is suggested that an optimum electrochemical evaluation for corrosion resistance of Al alloy is to calculate the diffusion limiting current density of cathodic polarization curve, impedance of AC or DC and polarization resistance of cyclic voltammogram.

• 대한화학회지
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• 제15권6호
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• pp.324-329
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• 1971

In order to evaluate the mechanism of electrolytic oxidation of iodate and to determine the optimum conditions for the electrolysis, studies were made using the cells without diaphragm and the lead peroxide anode. Results are summarized as followings: 1) Current density vs. anode potential curve by lead peroxide electrode had the different limiting current densities from platinum electrode and was more positive than platinum electrode. 2) Additions of potassium bichromate in the electrolyte contribute to maintain high current efficiency. 3) In the acid and alkaline regions, the current efficiencies decreased by reduction of iodate and discharge of hydroxyl ion, so maximum current efficiency was shown at pH 7. 4) Higher current density lowered the current efficiency in the region of 60-80% conversion of iodate. 5) Influence of the conversion on current efficiency in the region of 60-80% conversion of iodate.