• 한국지반환경공학회 논문집
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• 제25권5호
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• pp.21-27
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• 2024

석회암이 주 원료인 시멘트는 세계적으로 건설자재로 잘 활용해 왔으나, 토목건축 개발이 가속화 됨에 따라 석회암이 점차적으로 고갈이 될 것이다. 토목과 건축에 소요되는 주 재료인 시멘트는 현대에 사용량이 급증하고 있어서 미래에는 품질 좋은 석회암 자원의 고갈 또한 예상보다 이를 것이다. 그래서 축적된 기술력을 바탕으로 기존 자원이 시멘트를 대체할 건설자재로 사용이 가능하다면 고갈되어 가는 석회암 자원을 오랜 기간 동안 더 활용할 수 있을 것이다. 본 연구는 한국 지형의 면적에 표층으로 10% 가량을 형성하고 있는 황토를 건설자재로 일부 활용할 수 있는지를 판단하기 위해서 황토급결제를 개발하여 현장에 적용이 가능한지 여부를 실내시험을 통하여 증명하고자 한다.

• 자원환경지질
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• 제41권2호
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• pp.201-210
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• 2008

국내 폐광산 주변 중금속 오염 농경지 토양 복원을 위해 석회(CaO)와 분쇄한 석회암($CaCO_3$)을 안정화제로 이용한 토양 안정화 공법의 효율을 규명하는 배치 및 대형 칼럼실험을 실시하였다. 오염토양은 경북 군위군에 위치한 아연 폐광산 지역의 오염 농경지 토양을 이용하였으며, 안정화제의 함량은 오염토양 대비 0, 0.5, 2, 5%로 다양하게 적용함으로써, 안정화제에 의해 토양으로부터 용출되는 중금속 농도 변화를 시간에 따라 측정하여 안정화제의 중금속 저감 효율을 규명하였다. 배치실험 결과, 가루상의 석회나 석회암 0.5%를 토양과 혼합하여 안정화제로 사용한 경우, 오염토양으로부터 As, Cd, Pb, Zn의 중금속 용출 농도는 안정화제를 사용하지 않은 토양으로부터의 용출 농도를 기준으로 각각 70, 77, 94, 그리고 95% 감소하여 중금속 용출 저감 효과가 매우 높은 것으로 나타났다. 토양 객토법을 모사한 대형 칼럼실험 결과, 2% 입상 석회 첨가에 의해서 As, Cd, Zn의 토양 용출은 안정화제를 사용하지 않은 토양 용출 농도를 기준으로 각각 63, 97, 98% 감소하였다. 입상 석회암을 안정화제로 이용한 칼럼에서는 2% 석회암 첨가에 의해서 As 용출 농도는 135.6${\mu}g/L$에서 30.2 ${\mu}g/L$ 감소하여 약 46% 이상의 감소율을 나타내었으며, Cd와 Zn의 경우에는 97% 이상 감소하였다. 배치 및 칼럼실험 결과 석회암의 중금속 용출 저감 효율이 석회의 저감 효율과 매우 비슷한 것으로 나타나, 토양으로부터 중금속을 안정화시키는데 입상 석회와 석회암 모두 효과가 매우 좋은 것으로 나타났다. 토양 산성화 방지를 위해 토양개량제로 주로 사용하였던 석회의 과도한 토양 내 첨가가 토양의 급격한 pH 증가를 일으켜 농작물 재배에 악 영향을 주게 되는 한계를 극복하기 위하여, 본 배치 및 대형 칼럼실험을 통하여 토양 내 첨가에 의한 pH 증가가 거의 없으며 비용 측면에서도 석회보다 훨씬 저렴하지만 중금속 용출 저감 효과가 비슷한 석회암이 중금속 오염 농경지 토양 복원을 위한 새로운 안정화제로 유용하게 사용될 수 있음을 입증하였다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.239-242
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• 2002

This study is intended to investigate the relationship between rebound value of P type schmidt hammer and the compressive strength with various aggregates, and a series of experiments about early strength quality control by P type schmidt hammer was performed. According to the results, the compressive strength of concrete using basalt and limestone aggregate is higher by 3% and lower by 4% than that of concrete using granite aggregate respectively. Concrete using basalt and lime stone aggregate show high rebound value in vertical strike. Estimation of the compressive strength does not show differences in horizontal strike, but the compressive strength is estimated high in order of granite, basalt and limestone aggregate in vertical strike. A good correlation between the rebound value of schmidt hammer and the compressive strength is confirmed regardless of aggregate types, so it could be possible to control the quality of concrete by P type schmidt hammer test when basalt and limestone aggregates are used at the same time.

• 산업기술연구
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• 제20권A호
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• pp.285-293
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• 2000

In 1970's, the analysis of shallow substructure was the interests of geological engineering and environmental problems. And seismic refraction method was applied to detect those structures. From 1980's, digital electric industry is rapidly developed and high resolution prospecting equipment is supplied. And seismic reflection method is applied to achieve various data gathering and data analysis. In this study, geophysical prospecting method is applied to calculate the basic data of limestone yield production. Seismic shallow reflection method is used to detect the depth of bedrock and electrical resistivity method is used to detect of limestone layer boundary.

• 산업기술연구
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• 제20권A호
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• pp.279-283
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• 2000

Lime is one of the world's most useful chemicals and manufactured in various types of kilns, using various fuels. Quicklimes vary in reactivity with water due to variations in the time and temperature calcining process and type of kiln used. Careful attention and control of time and temperature in the calcining process is necessary to insure a highly reactive lime. Excess time and temperature will cause the lime to be over burned. The highest reactivity of quicklime is obtained by calcination of limestone in the particle size of 0.1cm~2cm, calcination temperature of $1000^{\circ}C$, calcination time 90min. It was found by the scanning electron microscopes that pores of quick lime is reducted if the soft burned quick lime is heated continually.

• 산업기술연구
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• 제20권A호
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• pp.303-309
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• 2000

Seismic reflection method is applied to detect shallow location of limestone in Chechon area. The data using hammer source is compared with that of weight drop. Small size hammer and weight-drop are used as energy source and 100Hz geophones are used for data aquisition. Data processing is conducted utilizing the available processing technique of "Geobit", which is seismic data processing software developed by KIGAM. The result of above data processing, the velocity of topsoil layer is 1,250m/sec. The velocity of this area is higher than other area because loading trucks pass this area and make this layer compact. And in limestone area, hammer is proposed to energy source instead of weight drop because the energy propagates the layer very well.

• Advances in concrete construction
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• 제2권3호
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• pp.209-227
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• 2014

The use of limestone fines (LF) in mortar and concrete can in certain ways improve performance and thus has become more and more commonplace. However, although LF is generally regarded as a filler, it is up to now not clear how much filling effect it could have and how best the filling effect could be utilized. Herein, the packing density and filling effect of LF were studied by measuring the packing densities of LF, (LF + cement) blends and (LF + cement + fine aggregate) blends under dry and wet conditions, and measuring the performance of mortars made with various amounts of LF added. It was found that the addition of LF would not significantly increase the packing density of (LF + cement) blends but would fill into the paste to increase the paste volume and paste film thickness, and improve the flow spread and strength of mortar.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2012년도 제45회 KOSCO SYMPOSIUM 초록집
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• pp.43-45
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• 2012

The effect of limestone characteristics on in-furnace desulfurization was experimentally investigated at hot gas combustion condition in a drop tube furnace (DTF). Flue gas was measured by Gas analyzer in order to figure out $SO_2$ content. The experiments were performed under excess sulfur 3000ppm condition to examine the effect of operating variables such as reaction temperatures, Ca/S ratios on the $SO_2$ removal efficiencies. The results show that the $SO_2$ removal efficiency increased with reaction temperature and Ca/S ratio increase. When considering the economics, $1200^{\circ}C$ and Ca/S ratio 2 condition is optimized to reduce $SO_2$ emission.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 봄 학술발표회 논문집(I)
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• pp.3-8
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• 1998

This research is to examine the relationships between viscosity and fluidity according to binders in the super flowing concrete. And this research is described with respect to rheology concept, confined water ratio($\beta_p$) of binders in paste and mortar, also investigated experimentally the relationships between the relative flowing ratio ($\Gamma_m$) and the funneling velocity ratio($R_m$) on the mortar state according to the water binder ratio(W/B) and the dosage of the superplasticizer. From the confined water ratio tests, it is found that $\beta_p$ of the class C fly ash is higher than that of the class F fly and limestone in paste and mortar, therefore class F fly ash and limestone and super flowing concrete. The result of test, the optimum mix condition to the compactibility if satisfied when the replacement ratio is 30% and $K_p$ is 0.8 for the case of fly ash and limestone.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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• pp.199-200
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• 2010

본 논문은 석회석 미분말을 활용한 고유동 콘크리트의 염소이온 확산계수를 통하여 확산계수를 추정 하였다. 또한 석회석 미분말의 혼합률에 따른 미세공극을 수은압입법에 의해 알아보았다.