• Title/Summary/Keyword: Light activator

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Photoluminescence properties of $Gd_{1-x}Ln_xCa_3(GaO)_3(BO_3)_4$ (Ln=Eu, Tb, Tm) under UV excitation

  • Kyung, Hyun-Ai;Jung, Ha-Kyun;Seong, Tae-Yeon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1565-1568
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    • 2007
  • A borate compound was adopted as new host material for $Eu^{3+}$, $Tb^{3+}$ and $Tm^{3+}$ activators. The phosphor samples, $Gd_{1-x}Eu_xCa_3(GaO)_3(BO_3)_4$, $Gd_{1-x}Tb_xCa_3(GaO)_3(BO3)_4$ and $Gd_{1-x}Tm_xCa_3(GaO)_3(BO_3)_4$ have been synthesized by conventional solid-state reaction. The crystalline phase for the resulting powders was identified using an X-ray diffraction $system^1$. Their photoluminescence properties under the excitation of UV ray were investigated. The Eu, Tb or Tm-doped $GdCa_3(GaO)_3(BO_3)_4$ emits efficient red, green or blue light, respectively. It was observed that the optimum concentration of Eu or Tb activator for the borate host was much higher than other $Eu^{3+}$ or $Tb^{3+}-doped$ phosphors.

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Luminescent Properties of the $Tb^{3+}$-Activated $ABCO_4$ and $ABC_3O_7$ Phosphors (A=Ca, Sr ; B=Y, RE ; C=AI, Ga)

  • Kim, Chang-Hae;Park, Sang-Mi;Park, Joung-Kyu;Park, Hee-Dong;Park, Joon-Taik
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.635-638
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    • 2002
  • In $ABCO_4$ and $ABC_3O_7$ (A=Ca, Sr; B=Y, Rare earth; C=Al, Ga), random distribution of static crystalline fields in activator sites results in inhomogeneous broadening of spectral lines of luminescent materials. In this study, we investigated luminescent properties of above-mentioned materials by excitation and emission spectra. In result, both $ABCO_4$:Tb and $ABC_3O_7$:Tb phosphors emit the green light. $ABC_3O_7$:Tb phosphors absorbed shorter wavelength energy than $ABCO_4$ phosphors so that the emission efficiencies of $ABC_3O_7$:Tb phosphors were higher than those of $ABCO_4$:Tb phosphors under vacuum UV.

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Studies on the Fluorescence of $Eu^{3+}\;and\;Tb^{3+}$ in Lanthanum Oxychloride (염화산화란탄에서 유로퓸(III) 과 테르븀(III)의 형광에 관한 연구)

  • Young Gu Ha;Taesam Kim
    • Journal of the Korean Chemical Society
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    • v.33 no.1
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    • pp.82-89
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    • 1989
  • The fluorescence of $Eu^{3+},\;Tb^{3+}$ substituted for $La^{3+}$ in Lanthanum Oxychloride (LaOCl) has been studied. The fluorescence intensity of the $Eu^{3+},\;Tb^{3+}$ in LaOCl excited by Ultra-violet light were investigated on its activator concentration and discussed as the energy transfer process. The energy transfer from $Tb^{3+}\;to\;Eu^{3+}$ take place in the $Eu^{3+}\;and\;Tb^{3+}$ codoped LaOCl crystal. This process was confirmed to the change of concentration and the measurement of fluorescence decay time.

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Photoluminescence Characteristic of Gallate-Based Red Emitting Phosphors with High Color Purity (색순도가 우수한 갈륨 산화물계 적색 형광체의 광발광 특성)

  • Kim, Kyoung-Un;Choi, Sung-Ho;Jung, Ha-Kyun;Nahm, Sahn
    • Korean Journal of Materials Research
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    • v.18 no.3
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    • pp.159-162
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    • 2008
  • $Eu^{3+}$-activated $R_3GaO_6$ (R = Y, Gd) phosphors were prepared in a conventional solid-state reaction and their optical properties were investigated. These compounds exhibit strong red emission under light excitation at 254 nm. The emission spectra are dominated by peaks appearing around 610-630 nm that are induced by the electric dipole transition of $^5D_0\;{\rightarrow}\;^7F_2$ of $Eu^{3+}$. In addition, the appropriate CIE (Commission Internationale de l'clairage) chromaticity coordinates, (x = 0.656, y = 0.336) for $Y_3GaO_6$ and (x = 0.655, y = 0.334) for $Gd_3GaO_6$, become closer to the NTSC (National Television System Committee) standard values. With the optimized activator concentrations, the maximum emission brightness is approximately 80% of $Y_2O_3$:$Eu^{3+}$ typical red-emitting phosphor with improved color purity under an excitation condition of 254 nm.

Chemoprevention and Chemoprotection Through Heme Oxygenase-1 Induction and Underlying Molecular Mechanisms (Heme oxygenase-1 유도를 통한 화학 암예방 및 세포보호와 그 분자생물학적 기전)

  • Kim, Eun-Hee;Kim, Sung-Hwan;Na, Hye-Kyung;Surh, Young-Joon
    • Environmental Mutagens and Carcinogens
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    • v.26 no.4
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    • pp.97-112
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    • 2006
  • Heme oxygenase(HO)-1 is an important antioxidant enzyme that plays a pivotal role in cellular adaptation and protection in response to a wide array of noxious stimuli. Thus, HO-1 induction has been associated with prevention or mitigation of pathogenesis of various diseases, including acute inflammation, atherosclerosis, degenerative diseases, and carcinogenesis. Recent progress in our understanding of the function of molecules in the cellular signaling network as key modulators of gene transcription sheds light on the molecular mechanisms underlyuing HO-1 gene expression. A panel of redox-sensitive transcription factors such as activator protein-1, nuclear factor-kB, and nuclear factor E2-related factor-2, and some of the upstream kinases have been identified as prime regulators of HO-1 gene induction. This review summarizes molecular mechanisms underlying HO-1 expression and the significance of targeted induction of HO-1 as a potential chemopreventive or chemoprotective strategy.

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Bone Homeostasis and Gut Microbial-Dependent Signaling Pathways

  • Zhong, Xiaohui;Zhang, Feng;Yin, Xinyao;Cao, Hong;Wang, Xuesong;Liu, Dongsong;Chen, Jing;Chen, Xue
    • Journal of Microbiology and Biotechnology
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    • v.31 no.6
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    • pp.765-774
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    • 2021
  • Although research on the osteal signaling pathway has progressed, understanding of gut microbial-dependent signaling pathways for metabolic and immune bone homeostasis remains elusive. In recent years, the study of gut microbiota has shed light on our understanding of bone homeostasis. Here, we review microbiota-mediated gut-bone crosstalk via bone morphogenetic protein/SMADs, Wnt and OPG/receptor activator of nuclear factor-kappa B ligand signaling pathways in direct (translocation) and indirect (metabolite) manners. The mechanisms underlying gut microbiota involvement in these signaling pathways are relevant in immune responses, secretion of hormones, fate of osteoblasts and osteoclasts and absorption of calcium. Collectively, we propose a signaling network for maintaining a dynamic homeostasis between the skeletal system and the gut ecosystem. Additionally, the role of gut microbial improvement by dietary intervention in osteal signaling pathways has also been elucidated. This review provides unique resources from the gut microbial perspective for the discovery of new strategies for further improving treatment of bone diseases by increasing the abundance of targeted gut microbiota.

Advanced Bioremediation Strategies for Organophosphorus Compounds

  • Anish Kumar Sharma;Jyotsana Pandit
    • Microbiology and Biotechnology Letters
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    • v.51 no.4
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    • pp.374-389
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    • 2023
  • Organophosphorus (OP) pesticides, particularly malathion, parathion, diazinon, and chlorpyrifos, are widely used in both agricultural and residential contexts. This refractory quality is shared by certain organ phosphorus insecticides, and it may have unintended consequences for certain non-target soil species. Bioremediation cleans organic and inorganic contaminants using microbes and plants. Organophosphate-hydrolyzing enzymes can transform pesticide residues into non-hazardous byproducts and are increasingly being considered viable solutions to the problem of decontamination. When coupled with system analysis, the multi-omics technique produces important data for functional validation and genetic manipulation, both of which may be used to boost the efficiency of bioremediation systems. RNA-guided nucleases and RNA-guided base editors include zinc-finger nucleases (ZFNs), transcription activator-like effector nucleases (TALENs), and clustered regularly interspaced short palindromic repeats (CRISPR), which are used to alter genes and edit genomes. The review sheds light on key knowledge gaps and suggests approaches to pesticide cleanup using a variety of microbe-assisted methods. Researches, ecologists, and decision-makers can all benefit from having a better understanding of the usefulness and application of systems biology and gene editing in bioremediation evaluations.

Effects of activators contained in adhesives on dentin bond strengths (상아질 접착제에 포함된 활성제의 사용 유무가 자가중합 복합레진의 상아질에 대한 전단결합강도에 미치는 영향)

  • Kang, Hye-Kyung;Shin, Joo-Hee;Suh, Kyu-Won;Ryu, Jae-Jun
    • The Journal of Korean Academy of Prosthodontics
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    • v.46 no.5
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    • pp.511-519
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    • 2008
  • Statement of problem: An incompatibility between the initiator systems of self-curing composite resins and light-curing adhesives was supposed recently. Purpose: The purpose of the study was to evaluate the influence of activators for self/dual bonding on dentin shear bonding strengths. Material and methods: Fifty human molars were divided into 5 groups. A flat dentin surface was created for each tooth. A self-curing composite resin (Luxacore) was bonded with the following adhesives (n = 10); One-Step, Prime&Bond NT, AdheSE, Prime&Bond NT and AdheSE were also used in combination with activators. Shear bond strengths were measured after 24 hours of water storage. The specimens were loaded in shear in the Instron until failure at a 1 mm/min crosshead speed. Data were compared using one-way ANOVA and Tukey HSD test (${\alpha}$= 0.05). Results: The dentin adhesive systems in order of decreasing median bond strength were One-Step > Prime&Bond NT with activator, AdheSE with activator > Prime&Bond NT, AdheSE. Among adhesives, One-Step had the highest bond strength. Prime&Bond NT with activator had higher bond strengths than Prime&Bond NT that was used alone, and so was AdheSE. Conclusion: Shear bond strengths were increased in Prime&Bond NT and AdheSE when these were used with activators comparing used without activators. But using activators was not effective clinically comparing One-Step.

Inhibitory Effect of Rosa multiflora hip Extract on UVB-induced Skin Photoaging in Hs68 Fibroblasts (자외선으로 유도된 Hs68 섬유아세포의 노화 반응에 대한 영실추출물의 억제 효능)

  • Park, Ji-Eun;Kim, Hyoung Ja;Kim, Su-Nam;Kang, Seung Hyun;Kim, Youn Joon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.41 no.4
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    • pp.351-359
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    • 2015
  • Acute and chronic ultraviolet (UV) irradiation triggers severe skin photoaging processes, which directly disrupt the normal three-dimensional integrity of skin. UV light stimulates the expression of matrix metalloproteinases (MMPs) which degrade constituents of extracellular matrix (ECM) proteins. These MMPs reduce collagen synthesis and decrease skin elasticity and integrity, resulting in wrinkle formation. In this study, we identified Rosa multiflora hip extract (RME) as an effective anti-photoaging ingredient. First, cell proliferation activity of RME was verified using Hs68 human dermal fibroblast cell line. RME downregulated MMPs expression through the inhibition of activator protein (AP)-1. In addition, type I and IV collagen expressions were increased with RME treatment and UVB-induced inflammatory responses were also reduced after RME treatment. In conclusion, R. multiflora hip extract may effectively improve UVB-induced skin aging and wrinkle formation which may provide as an anti-aging, anti-wrinkle, and anti-inflammation ingredient in cosmetic industry.

Synthesis and photoluminescence characteristics of SrAl2O4:Mn4+ phosphor for LED applications (LED용 SrAl2O4:Mn4+ 형광체 합성 및 발광특성 연구)

  • Byoung Su Choi;Jun Ho Lee;Sungu Hwang;Jin Kon Kim;Byeong Woo Lee;Hyun Cho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.1
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    • pp.1-16
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    • 2023
  • A non-rare earth-based strontium-aluminate red light emitting phosphor was synthesized by a solid-state reaction method and the effect of synthesis temperature and Mn4+ activator concentration on the photoluminescence characteristics of the phosphor was studied. The synthesized SrAl2O4:Mn4+ phosphor showed broad band absorption characteristics in the near-ultraviolet and blue regions with peaks at wavelengths of near 330 and 460 nm, and a triple band deep red emission consisted of three peaks at near 644, 658, and 673 nm. The SrAl2O4:Mn4+ phosphor synthesized at a temperature 1600℃ and a Mn4+ activator concentration of 0.5 mol% showed the strongest PL emission intensity, and concentration quenching was observed at concentrations higher than 0.7 mol%. FE-SEM and DLS particle size distribution analysis showed that the synthesized SrAl2O4:Mn4+ phosphor had a particle size distribution of 2~6.4 ㎛ and an irregular spherical shape with an average particle size of ~4 ㎛.