background: In an attempt to investigate the role of oxidants in the activation of phospholipase $A_2$(PLA$_2$) and endogenous oxidative stress in the lung. acute inflammatory lung injury was induced by the instillation of hydrogen peroxide into the trachea of Sprague-Dawley rats. Material and Method: To prove the hypothesis thats released oxidants from neutrophils activate the PLA$_2$ retrogradely, activities of PLA$_2$ and lysoplatelet activating factor acetyltransferase(lysoPAF AT) were assayed i hours after instillation of hydrogen peroxide. In addition, to confirm the impairing effects of the activation of PLA$_2$ associated with endogenous oxidative stress, lung weight/body weight ratio(L$\times$10$^{-3}$ B), protein contents(mg/two lungs) in bronchoalveolar lavage(BAL) were measured. As neutrophilic respiratory burst has been known to play a pivotal role in the genesis of endogenous oxidative stress associated with acute inflammatory lung injury, BAL neutrophils counts and level of lung myelperoxidase(MPO) were measured after hydorgen peroxide insult. Morphological and histochemical studies were also performed to identify the effect of the endogenous oxidative stress. Result: Five hours after hydrogen peroxide instillation, lungs showed marked infiltration of neutrophils and increased weight. Protein contents in BAL increased significantly compared to those of normal rats. PLA$_2$ activity was enhanced in the hydrogen peroxide instilled group. Interestingly, the accelerated production of platelet activating factor(PAF) was confirmed by the increased activity of lysoPAF AT in the $H_2O$$_2$ employed lung. Morphologically, light microscopic findings of lungs after instillation of hydrogen peroxide showed atelectasis and infiltration of inflammatory cells, which was thought to be caused by lipid mediators produced by PLA$_2$ activation. In cerium chloride cytochemical electron microscopy, dense deposits of cerrous perhydroxide were identified. In contrast, no deposit of cerrous perhydroxide was found in the normal lung.
Many researchers have studied on rooftop greening that can be installed in abandoned spaces on a building roof. The most important issue in rooftop greening is the soil weight problem. The light greening materials are needed to solve this problem. Therefore, many alternative materials against the soil were investigated for rooftop greening. In this study, the waste wood chips and the waste paper slurry were evaluated as the lightweight vegetation foundation for rooftop greening. It also has a meaning for recycling of waste materials. The mixture ratio of waste wood chips to waste paper slurry for the board (the foundation of greening) was 60 to 40. The wet strength resin and the sizing agent were additionally added with different amount. After the forming of the board, physical and chemical properties were tested with the variation of wet strength resin and sizing agent. As the result of the test, the board with 15% of wet strength resin in the wet condition showed the highest strength. Futhermore, the moisture evaporation loss from the board surface with sizing agent was much lower than that from the board without sizing agent. Therefore, it was clear that the sizing agent was effective for water retention. The change of thickness in the wet condition was less than 1 mm, and it showed that the board is the predominant material on the dimensional stability. The average pH value of the board was ranged from 7.6 to 8.25.
Carbon/carbon (C/C) composites as unique materials possess exceptional thermal resistance with light weight, high stiffness, and strength even at high temperature. However, one serious obstacle for application of the C/C composites is their poor oxidation resistance in high temperature oxidizing environments. SiC coating has been employed to protect the composites from oxidation. This study explored combustion characteristics of 4-directional (4D) carbon/carbon composites using liquid fuel rocket engine to investigate ablative motion of the materials. C/C composites were made of coal tar pitch as a matrix precursor, and heat-treated at $2300^{\circ}C$. Throughout repeated densification process, the density of the material reached $1.903g/cm^3$. After machining 4D C/C composites, the nozzle surface was coated by a SiC layer by pack-cementation method to improve oxidation resistance. Erosion characteristics of SiC-coated C/C composites were measured as function of the ratio of oxygen to fuel. The morphological change of the composites after combustion test was investigated using SEM and erosion mechanism also was discussed.
Choi, Jin Woo;Seo, Su Hong;Joo, Hyung Joong;Yoon, Soon Jong
KSCE Journal of Civil and Environmental Engineering Research
/
v.34
no.5
/
pp.1353-1362
/
2014
In recent years, numerous environmental problems associated with the excessive use of fossil fuel are taking place. For an alternative energy resource, the importance of renewable energy and the demands of facilities to generate renewable energy are continuously rising. To satisfy such demands, a large number of photovoltaic energy generation structures are constructed and planned with large scale. However, because these facility zones are mostly constructed on land, some troubles are occurred such as rising of construction cost due to the cost of land use, environmental devastation, etc. To solve such problems, the floating type photovoltaic energy generation system using FRP members have been developed in Korea. FRP members are recently available in civil engineering applications due to many advantages such as high strength, corrosion resistance, light weight, etc. and they are suitable to fabricate the floating structures because of their material properties. In this study, the analytical and experimental investigations to evaluate the structural performance of floating PV generation structure and SMC FRP vertical member which is used to fabricate the structure were conducted. The static and dynamic performances of floating PV generation structure are evaluated through the FE analysis and the experiment, respectively. Moreover, the structural safety evaluation and buckling analysis of SMC FRP vertical compression member are also conducted by the FE analysis, and the structural behavior of SMC FRP member under compression and pullout is investigated by the experiments. From this study, it was found that the structural system composed of pultruded FRP and SMC FRP members are safe enough to resist externally applied loads.
In this paper, the basic study on the design of the flexible keel of the energy-storage prosthetic foot was performed in order to Improve the walking performance and Increase the activities of the below knee amputees. Based on the analysis of the anthropometric data and the normal gait on two dimensional sagittal plane available In the literature, we presented a model of the basic structure of the flexible keel of the prosthetic foot. The model of the basic structure was composed of the simple beams, and linear rotational spring and damper. Laminated carbon fiber-reinforced composites were selected as the material of the basic structure model of the flexible keel In order to apply the high strength and light weight materials to the basic structure of the flexible keel of the prosthetic foot. The recoverable strain energy In response to the change of beam shape was calculated bur the finite element analysis and it was suggested that the change of beam shape could be the design variable in flexible keel design. The simulation process was systematically designed by using orthogonal array table in order to design the flexible keel structure which could store the more recoverable strain energy. finite element analysis was carried but according to the design of simulations by using the finite element program ABAQUS and the flexible keel structure of the energy-storage prosthetic foot was obtained from the analysis of variance(ANOVA). The dynamic simulation model of the prosthetic walking using the flexible keel structure was made and the dynamic analysis was carried but during one walk cycle. Based on the above results, an effective design process was presented for the development of the prosthetic fool system.
Recently just as in the automobile industry, shipbuilders also try to reduce material consumption and weight in order to keep operating costs as low as possible and improve the speed of production. Naturally industry is ever searching for welding techniques offering higher power, higher productivity and a better quality. Therefore it is important to have a details research based on the various welding process applied to steel and other materials, and to have the ability both to counsel interested companies and to evaluate the feasibility of implementation of this process. Submerged-arc welding (SAW) process is usually used about 20% of shipbuilding. Similar to gas metal arc welding(GMAW), SAW involves formation of an arc between a continuously-fed bare wire electrode and the work-piece. The process uses a flux to generate protective gases and slag, and to add alloying elements to the weld pool and a shielding gas is not required. Prior to welding, a thin layer of flux powder is placed on the work-piece surface. The arc moves along the joint line and as it does so, excess flux is recycled via a hopper. Remaining fused slag layers can be easily removed after welding. As the arc is completely covered by the flux layer, heat loss is extremely low. This produces a thermal efficiency as high as 60% (compared with 25% for manual metal arc). SAW process offers many advantages compared to conventional CO2 welding process. The main advantages of SAW are higher welding speed, facility of workers, less deformation and better than bead shape & strength of welded joint because there is no visible arc light, welding is spatter-free, fully-mechanized or automatic process, high travel speed, and depth of penetration and chemical composition of the deposited weld metal. However it is difficult to application of thin plate according to high heat input. So this paper has been focused on application of the field according to SAW process for thin plate in ship-structures. For this purpose, It has been decided to optimized welding condition by experiments, relationship between welding parameters and bead shapes, mechanical test such as tensile and bending. Also finite element(FE) based numerical comparison of thermal history and welding residual stress in A-grade 3.2 thickness steel of SAW been made in this study. From the result of this study, It makes substantial saving of time and manufacturing cost and raises the quality of product.
Cement-bonded particleboard is being used as outdoor siding material all over the world, because this composite particularly bears a light weight, high resistance against fire, decay, and crack by cyclic freezing and thawing, anti-shock property, and strength enhancement. Construction systems are currently changing into a frame-building style and wooden houses are being constructed with prefabrication type. Therefore, they require a more durability at outdoor-exposed sides. In this study, the cement hydration property for Korean pine particle, Japanese larch particle and face- and middle layer particles (designated as PB particle below) used in Korean particleboard-manufacturing company was investigated, and the rapid manufacturing characteristics of cement-bonded particleboard by supercritical $CO_2$ curing was evaluated. Korean pine flour showed a good hydration property, however, larch flour showed a bad one. PB particle had a better hydration property than larch flour. The addition of $Na_2SiO_3$ indicated a negative effect on hydration, however, $MgCl_2$ had a positive one. Curing by supercritical $CO_2$ fluid gave a conspicuous enhancement in the performances of cement-bonded particleboards compared to conventional curing. $MgCl_2$ 3%-added PB particle had the highest properties, and $MgCl_2$ 1%-added Korean pine particle had the second class with the conditions of cement/wood ratio of 2.7, a small fraction-screened particle and supercritical curing. On the contrary, the composition of non-hammermilled or large fraction-screened particle at cement/wood ratio of 2.2 was poorer. Also, the feasibility for actual use of 3%-added, small PB particle-screened fraction was greatest of all the conventional curing treatments. Relative superiority of supercritical curing vs. conventional curing at dimensional stability was not so apparent as in strength properties. Through the thermogravimetric analysis, it was ascertained that the peak of a component $CaCO_3$ was highest, and the two weak peaks of calcium silicate hydrate and ettringite and $Ca(OH)_2$ were present in supercritical treatment. Accordingly, it was inferred that the increased formation of carbonates in board contributes to strength enhancement.
Kong, Won Suk;Park, Jun Hyo;Yoon, Ho Gyu;Lee, Jae Wook
Journal of Adhesion and Interface
/
v.16
no.1
/
pp.29-34
/
2015
Hydrocarbon resins, which are defined as low molecular weight, amorphous, and thermoplastic polymers, are widely used as tackifier for various types of adhesives, as processing aids in rubber compounds, and as modifiers for plastics polymers such as isotactic polypropylene. Typically, hydrocarbon resins are non-polar, and thus highly compatible with non-polar rubbers and polymer. However, they are poorly compatible with polar system, such as acrylic copolymer, polyurethanes, and polyamides. Moreover, recently the raw materials of hydrocarbon resin from naphtha cracking had been decreased because of light feed cracking such as gas cracking. To overcome this problem, in this study, novel hydrocarbon resins were designed to have a highly polar chemical structure which material is sustainable. And, it was successfully synthesized by Diels-Alder reaction of dicyclopentadiene monomer and sorbic acid from blueberry as renewable resources. Acrylic resins were formulated with various tackifiers solution including sorbic acid grafted hydrogenated dicyclopentadiene hydrocarbon resins in acrylic adhesive and rolling ball tack, loop tack, $180^{\circ}$ peel adhesion strength, and shear adhesion strength were measured. The properties depend on the softening point and polar content of tackifiers.
Journal of the Microelectronics and Packaging Society
/
v.26
no.4
/
pp.33-37
/
2019
In this study, the graded thermal properties of composites are obtained by difference in specific gravity of fillers including Cu, h-BN and GO powders in epoxy. Relatively heavy powders such as Cu and h-BN compared to GO mostly at the bottom layer, while light GO powders were dispersed in the top layer in the composites. The thermal conductivity of composites was gradually increased from 0.55 (0.52) W/mK to 2.82 (1.37) W/mK for GO/h-BN (GO/Cu) epoxy composites from surface to bottom. On the contrary, the coefficient of thermal expansion was decreased from 51 ppm/℃ to 23 ppm/℃ and from 57 ppm/℃ to 32 ppm/℃ for GO/Cu and GO/h-BN, respectively. The variation of thermal properties in composites is attributed due to intrinsic material properties of filler including thermal conductivity, morphology and the distribution by the specific weight of fillers. This simple strategy for realizing graded thermal composites by introducing different filler materials would be effective heat transfer at interface of heterostructure with large thermal properties such as inorganic semiconductor/plastic, metal/plastic, and semiconductor/metal.
To fundamentally solve the problem of deterioration of concrete structures, it has been researched that the high durable concrete structure reinforced with the FRP rebar can be one of major solution to the newly-developed concrete structure. FRP rebar has lots of advantages such as non-corrosive, high performance and light weight against the conventional steel rebar. Among these kinds of FRP rebars, GFRP rebar has usually been considered as the best reinforcement because of its economic point of view. Even though the material capacity of the GFRP rebar was already investigated, there are some problems such as low modulus of elastic that will be cause for degrade of the serviceability of flexural concrete member reinforced with the GFRP rebar. Thus, the deflection characteristics of the GFRP rebar reinforced concrete structure should be considered then investigated. In this study, ACI 440 guideline (2003), ISIS Canada Design Manual (2001) and Toutanji et al. (2000) was considered for predicting the moment of inertia of the concrete beam reinforced with the GFRP rebar. And it was also evaluated that load-deflection relationship had a good accordance with the test and analysis result. In the result of this study, it could be estimated that the load-deflection relationship using the suggested equation of moment of inertia in this study indicated better accordance with the test result than that of the others until failure.
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