• Title/Summary/Keyword: LiV3O8

Search Result 138, Processing Time 0.018 seconds

Thermal Stability of Delithiated LiCoO2-organic Electrolyte for Lithium-Ion Rechargeable Batteries (리튬이온이차전지용 LiCoO2-유기전해액의 충전상태에 따른 열적 안정성)

  • Kim, Dong-Hun;Lee, Young-Ho;Shin, Hye-Min;Chung, Young-Dong;Doh, Chil-Hoon;Jin, Bong-Soo;Kim, Hyun-Soo;Moon, Seong-In;Oh, Dae-Hui;Kim, Ki-Won
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.20 no.5
    • /
    • pp.421-424
    • /
    • 2007
  • Thermal behavior of $Li_{1-x}CoO_2$ has been investigated employing DSC (Differential Scanning calorimetry) and TGA (Thermogravimetry Analyzer), and the crystal parameters were calculated from XRD (X-ray diffraction).for the commercial rectangular pouch cell(1000 mAh).The cathode materials coated over aluminium foil current collector is made up of a blend consisting of active material $LiCoO_2$(size $20\;{\mu}m$, 94 wt%), conducting material super p black (SPB, 3 wt%) and binder polyvinylidene fluoride (PVDF, 3 wt%). The anode is a mix consisting of carbon (92 wt%) and PVDF(8 wt%) coated over copper foil. The cells for the experiments were first preconditioned by cycling three times and stabilized at OCV=3.0, 3.5, 4.2, 4.35 and 4.5 V. The stabilized cathode material was used for thermal and crystal parameter investigations.

Scintillation Characteristics of CsI(Li) Single Crystals (CsI(Li) 단결정의 섬광특성)

  • Lee, W.G.;Doh, S.H.;Ro, T.I.;Kim, W.;Kang, H.D.;Moon, B.S.
    • Journal of Sensor Science and Technology
    • /
    • v.8 no.5
    • /
    • pp.359-367
    • /
    • 1999
  • CsI(Li) single crystals doped with 0.02, 0.1, 0.2 and 0.3 mole% lithium as an activator were grown by Czochralski method. The lattice structure of grown CsI(Li) single crystal was bcc, its lattice constant was $4.568\;{\AA}$. The absorption edge of CsI(Li) single crystal was 245 nm, and the spectral range of luminescence was $300{\sim}600\;nm$, its maximum luminescence intensity appeared at 425 nm. The energy resolutions of CsI(Li) single crystal doped with 0.2 mole% lithium were 14.5% for $^{137}Cs$(662 keV), 11.4% for $^{54}Mn$(835 keV) and 17.7% and 7.9% for $^{22}Na$(511 keV and 1275 keV), respectively. The relation formula of $\gamma$-ray energy versus energy resolution was ln (FWHM%) = -0.893lnE + 8.456 and energy calibration formula was ${\log}E_r=1.455\;{\log}(ch.)-1.277$. The phosphorescence decay time of CsI(Li) crystal doped with 0.2 mole% lithium was 0.51 s at room temperature, and its time resolution measured by CFT(constant-fraction timing method) was 9.0 ns.

  • PDF

Geochemical Characteristics of Stream Sediments Based on Bed Rocks in the Naju Area, Korea (기반암에 따른 나주지역 하상퇴적물의 지구화학적 특성)

  • Park, Young-Seog;Kim, Jong-Kyun;Jung, Young-Hwa
    • Journal of the Korean earth science society
    • /
    • v.27 no.1
    • /
    • pp.49-60
    • /
    • 2006
  • The purpose of this study is to investigate geochemical characteristics for stream sediments in the Naju area. We collected 139 stream sediments samples from primary channels. Samples were dried slowly in the laboratory and chemical analysis was carried out using XRF. ICP-AES and NAA. In order to investigate geochemical characteristics, the geological groups categorized into granitic gneiss area, schist area, granite area, arenaceous rock area, tuff area, andesite area, and rhyolite area. Average contents of major elements for geological groups are $SiO_2\;58.37{\sim}66.06wt.%,\;Al_2O_3\;13.98{\sim}18.41wt.%,\;Fe_2O_3\;4.09{\sim}6.10wt.%,\;CaO\;0.54{\sim}1.33wt.%,\;MgO\;0.86{\sim}1.34wt.%,\;K_2O\;2.38{\sim}4.01wt.%,\;Na_2O\;0.90{\sim}1.32wt.%,\;TiO_2\;0.82{\sim}1.03wt.%,\;MnO\;0.09{\sim}0.15wt.%,\;P_2O_5\;0.11{\sim}0.18wt.%$. According to the comparison of average contents of major elements, $Al_2O_3\;and\;K_2O$ are higher in granitic gneiss area, $Fe_2O_3,\;CaO,\;P_2O_5$ are higher in tuff area, MgO and $TiO_2$ are higher in andesite area, $Na_2O_$ is higher in rhyolite area, $SiO_2$, and MnO are higher in arenaceous rock area. Average contents of minor and rare earth elements for geological groups are $Ba\;1278{\sim}1469ppm,\;Be\;1.1{\sim}1.5ppm,\;Cu\;18{\sim}25ppm,\;Nb\;25{\sim}37ppm,\;Ni\;16{\sim}25ppm,\;Pb\;21{\sim}28ppm,\;Sr\;83{\sim}155ppm,\;V\;64{\sim}98ppm,\;Zr\;83{\sim}146ppm,\;Li\;32{\sim}45ppm,\;Co\;7.2{\sim}12.7ppm,\;Cr\;37{\sim}76ppm,\;Cs\;4.8{\sim}9.1ppm,\;Hf\;7.5{\sim}25ppm,\;Rb\;88{\sim}178ppm,\;Sc\;7.7{\sim}12.6ppm,\;Zn\;83{\sim}143ppm,\;Pa\;11.3{\sim}37ppm,\;Ce\;69{\sim}206ppm,\;Eu\;1.1{\sim}1.5ppm,\;Yb\;1.8{\sim}4.4ppm$. According to the comparison of average contents of minor and rare earth elements for geological groups, Pb, Li, Cs, Hf, Rb, Sb, Pa, Ce, Eu, and Yb are higher in granitic gneiss area; Ba, Co, and Cr in schist area; Nb, Ni, and Zr in arenaceous rock area; Sr in tuff area: and Be, Cu, V, Sc, and Zn are such in andesite area.

A study on characterization of directional coupler using LiNbO$_3$ (LiNbO$_3$ 기판을 이용한 방향성결합형 광 변조기 특성 연구)

  • 강기성;김창원;소대화
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 1995.05a
    • /
    • pp.81-85
    • /
    • 1995
  • A guide-wave electro-optical modulatored direct-ional coupler 1X2 was fabricated on LiNbO$_3$ by proton exchange with self-aligned method After proton exchange process, the waveguide is formed by annealing process, The relationship between refractive index change of waveguide and maximun output was studied a long the annealing time. A self-alinged method was used to simplify the fabrication process of the waveguide and the maximize the efficiency of electric field. The modulatored directional coupler 1${\times}$2 has very good figures of merits; The measured crosstalk was -29.5[dB] and the modulating voltage of 8.0[V].

  • PDF

A Study on Fabrication and Characterization of Directional Coupler 1$\times$2 Optical Modulator Using $LiNbO_3$ ($LiNbO_3$에 의한 1$\times$2 방향성결합형 광 변조기 제작 및 특성 연구)

  • Gang, Gi-Seong;So, Dae-Hwa
    • Korean Journal of Materials Research
    • /
    • v.6 no.5
    • /
    • pp.462-469
    • /
    • 1996
  • 1x2 방향성결합형 광 변조기를 LiNbO3 기판상에 양자교환에 의한 자기정렬 방식으로 제작하였다. 양자교환후 광 도파로의 안정을 위해 열처리를 하였다. 본 연구에서는 광 도파로를 제작한 후 열처리 시간에 의한 도파로의 굴절을 변화의 관계에 대하여 연구하였으며 전계효과가 우수한 자기정렬방식을 선택하였다. 제작된 1x2 방향성결합형 광 변조기는 변조전압 8.0V에서 크로스토오크가 -29.5dB의 매우 우수한 특성을 나타내었다.

  • PDF

GYAGG/6LiF composite scintillation screen for neutron detection

  • Fedorov, A.;Komendo, I.;Amelina, A.;Gordienko, E.;Gurinovich, V.;Guzov, V.;Dosovitskiy, G.;Kozhemyakin, V.;Kozlov, D.;Lopatik, A.;Mechinsky, V.;Retivov, V.;Smyslova, V.;Zharova, A.;Korzhik, M.
    • Nuclear Engineering and Technology
    • /
    • v.54 no.3
    • /
    • pp.1024-1029
    • /
    • 2022
  • Composite scintillation screens on a base of Gd1.2Y1.8Ga2.5Al2.5O12:Ce (GYAGG) scintillator have been evaluated for neutron detection. Besides the powdered scintillator, the composite includes 6LiF particles; both are merged with a binder and deposited onto the light-reflecting aluminum substrate. Results obtained demonstrates that screens are suitable for use with a silicon photomultiplier readout to create a prospective solution for a compact and low-cost thermal neutron sensor. Composite GYAGG/6LiF scintillation screen shows a pretty matched sensitivity and γ-background rejection with a widely used ZnS/6LiF screens however, possesses forty times faster response.

Development of an Electric Field Sensor using Reflective Interference Type Optical Modulator (반사간섭형 광변조기를 이용한 전계 계측센서의 개발)

  • Choi, Young-Kyu
    • Journal of Sensor Science and Technology
    • /
    • v.8 no.4
    • /
    • pp.333-340
    • /
    • 1999
  • A reflective interference type optical modulator to compose the electric field sensor is proposed, and the performance and characteristics are theoretically analyzed. For the high sensitivity of the sensor, a method to improve the modulation index of the modulator is presented. The electric field sensor using $Ti:LiNbO_3$ waveguide was fabricated and qualitatively investigated the characteristics by measuring the low frequency electric field. Even though the sensor showed very low modulation index of 5%, the electric filed strength of 5 V/cm was measured. The experimental results revealed the utilities of this type electric field sensor.

  • PDF

Ion Conduction Properties of PMMA/PVDF based Polymer Electrolyte for Lithium Polymer Battery (리튬 폴리머전지용 PMMA/PVDF계 고분자 전해질의 이온 전도 특성)

  • 이재안;김종욱;구할본;이헌수;손명모
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2000.11a
    • /
    • pp.347-350
    • /
    • 2000
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. The temperature dependence of conductivity, impedance spectroscopy and electrochemical properties of PMMA/PVDF electrolytes as a function of a mixed ratio were reported for PMMA/PVDF based polymer electrolyte films, which were prepared by thermal gellification method of preweighed PMMA/PVDF, plasticizer and Li salt. The ion conductivity of PMMA/PVDF electrolytes was 10$\^$-3/S/cm, which may be applicable to a constituent of lithium secondary battery. 5PMMA20PVDFLiC1O$_4$PC$\sub$8/EC$\sub$8/ electrolyte remains stable up to 5V vs. Li/Li$\^$+/. Steady state current method and AC impedance were used for the determination of transference numbers in PMMA/PVDF electrolyte film. The transference number of 5PMMA20PVDFLiC1O$_4$PC$\sub$8/EC$\sub$8/ electrolyte is 0.55.

  • PDF

Electrochemical Properties of Lithium-Ion Polymer Battery with PMMA IPN-Based Gel Polymer Electrolyte (PMMA IPN계 겔폴리머전해질을 채용한 리튬이온폴리머전지의 전기화학적 특성)

  • 김현수;신정한;나성환;엄승욱;문성인;김상필
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.16 no.11
    • /
    • pp.994-1000
    • /
    • 2003
  • In this study, gel polymer electrolytes (GPE) with semi-interpenerating network of poly (methyl methacrylate) and hexanediol dimethacrylate were synthesized and their electrochemical performances were evaluated. LiCoO$_2$/GPE/graphite cells were prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor containing 5 vol% curable mixture had a low viscosity relatively. GPE showed good electrochemical stability up to potential of 4.8 V vs. Li/Li$\^$+/. Ionic conductivity of the gel polymer electrolyte at room temperature and -20$^{\circ}C$ was ca. 5.9 and 1.4${\times}$10$\^$-3/ Scm$\^$-1/, respectively. LiCoO$_2$/GPE/graphite cells showed good rate capability, low-temperature performance and cycleability.

Effect of Crystal Structural Environment of Pr3+ on Photoluminescence Characteristics of Double Tungstates

  • Lee, Kyoung-Ho;Chae, Ki-Woong;Cheon, Chae-Il;Kim, Jeong-Seog
    • Journal of the Korean Ceramic Society
    • /
    • v.48 no.2
    • /
    • pp.183-188
    • /
    • 2011
  • In this article, the effect of the crystal structural environment of $Pr^{3+}$ ions on the photoluminescence (PL) characteristics of double tungstates, such as $A(M_{1-X}Pr_X)W_2O_8$ (A=Li, Cs, M = In, Y, Sc, La; $0.007{\leq}x{\leq}0.1$) and $La_{1.96}Pr_{0.04}W_3O_{12}$ are characterized. By varying the ion radius in A and M sites, the structural environment of $Pr^{3+}$ ions were modified. The structural criteria, that is, the point charge electrostatic potentials V around the $Pr^{3+}$ activator, were calculated using the crystal structural parameters. The point charge potential V can be a valid criterion for $^3P_o$ quenching in various double tungstates. When the calculated V values are large (> 6.0), the luminescence from the $^3P_0$ level becomes dominant. When the calculated V values are about 3.8, the $^1D_2$ line appears weakly but $^3P_0$-level luminescence is absent. When the calculated V values are small (< 2.0), the luminescence from the $^1D_2$ level becomes dominant and $^3P_0$-level luminescence is absent. At 2.0$^3P_o$ quenching to $^1D_2$ level occurs substantially in accordance with the structural criterion of the point charge potential model.