• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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• pp.550-553
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• 2001

$Li_{2}O-P_{2}O_{5}-Bi_{2}O_{3}-V_{2}O_{5}$ glass containing glass former, $P_{2}O_{5}$ and $Bi_{2}O_{3}$ was prepard by melting the glass batch in pt. erucible followed by guenching on the copper plate. We found that $Li_{2}O-P_{2}O_{5}-Bi_{2}O_{3}-V_{2}O_{5}$ glass-ceramics obtained from the crystallization of glass showed signifieantly higher capacity and longer cycle life tham $LiV_{3}O_{8}$ made from powder synthesis. In this paper, we described crystallization process and $LiV_{3}O_{8}$ crystal growth in glass matrix by increasing temperature. The electrochemical properties were strongly affected by $LiV_{3}O_{8}$ crystal growth in matrix

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집
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• pp.550-553
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• 2001

Li$_2$O-P$_2$O$_{5}$-Bi$_2$O$_3$-V$_2$O$_{5}$ glass containing glass former, P$_2$O$_{5}$ and Bi$_2$O$_3$ was prepard by melting the glass batch in pt. erucible followed by quenching on the copper plate. We found that Li$_2$O-P$_2$O$_{5}$-Bi$_2$O$_3$-V$_2$O$_{5}$ g1ass-ceramics obtained from the crystallization of glass showed significantly higher capacity and longer cycle life tham LiV$_3$O$_{8}$ made from powder synthesis. In this paper, we described crystallization process and LiV$_3$O$_{8}$ crystal growth in glass matrix by increasing temperature. The electrochemical properties were strongly affected by LiV$_3$O$_{8}$ crystal growth in matrix.rowth in matrix.

• 한국전기전자재료학회논문지
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• 제11권9호
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• pp.733-738
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• 1998

본 논문에서는 고체 리듐 전지를 개발하기 위하여 poly(ethylene oxide) [PEO] 에 $LiClO_4$, poly (vinylidene fluoride) [PVDF] 및 가소제로 propylene carbonate [PC] 와 ethylene carbonate[EC] 등을 혼합여 고분자 저해질을 제조하였다. 또한 고체 리듐 전지용 정극으로써 우수한 특성이 기대되는 $Li_xV_3O_8$을 졸-겔법에 의해 합성하여 $Li_xV_3O_8$SPE/Li cell 의 전기화학적 특성을 측정하였다. 고분자 matrix는 PEO와 PVDE를 혼합 사용한 결과 $PEO_4 PVDF_4LiCIO_4PC_5EC_5$ 고분자 전해질이 상온에서 $5.2 {\times} 10{-3}$ S/cm 의 높은 이온 전도도를 나타냈으며 리듐 이온 transference number는 0.3이었다. 졸-겔법에 의해 제조된 $Li_xV_3O_8$을 사용한 $Li_xV_3O_8$SPE/Li cell의 방전시 cell 저항이 방전 초기에는 비소한 증가를 하다가 방전 말기 전압인 2.0V에서 크게 증가하였다. $Li_xV_3O_8$ composite 정극의 첫 번째 방전 용량은 295㎃h/g이었으며 8번째 충방전 싸이클부터 방전 용량이 안정화 되었고 15번째 방전 용량도 212㎃h/g으로 고체 전지용 정극으로써 우수한 특성을 보였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 춘계학술대회 논문집
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• pp.151-154
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• 1998

The layered trivanadate, LiV$_3$O$_{8}$ has been investigated as a cathode material for secondary lithium batteries. Early in its development the preparation method of LiV$_3$O$_{8}$ strongly influenced its electrochemical properties, such as discharge capacity, rate capability and cycling efficiency. In the present experiment, a new synthesis route has been applied to obtain LiV$_3$O$_{8}$ . Instead of the conventional high temperature technique leading to the crystalline form, a solution technique producing the amorphous form has been used. This material, after dehydration, shows an electrochemical performance exeeding that of the crystalline one. The rationale for this behavior mainly lies in microscopic factors, i.e., in the possibility for the unit cell of amorphous LiV$_3$O$_{8}$ to insert up to 9 Li$^{+}$, instead of six for crystalline LiV$_3$O$_{8}$ . The ultrasonically treated products in water were characterized by XRD, TGA, DSC, and SEM. These measurements showed that the ultrasonic treatment process of crystalline LiV$_3$O$_{8}$ causes a decrease in crystallinity and considerable increases in specific surface area and interlayer spacing.g.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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• pp.797-800
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• 2002

Instead of a solution process producing amorphous $LiV_3O_8$ form, we prepared Lithium vanadate glass by melting $Li_2O-P_2O_5-V_2O_5$ and $Li_2O-P_2O_5-Bi_2O_3-V_2O_5$ composition in pt. crucible and by quenching on the copper plate. From the crystallization of $Li_2O-P_2O_5-V_2O_5$ and $Li_2O-P_2O_5-Bi_2O_3-V_2O_5$, we could abtain glass-ceramics having crystal phase, LiV3O8 from glass matrix. The material heat-treated at lower-temperature, $250^{\circ}C$ had less crystalline and lower capacity, But the material heat-treadted at higher-temperature, $330^{\circ}C$ had higher capacity and $Li_2O-P_2O_5-V_2O_5$ glass-ceramics had higher capacity than $Li_2O-P_2O_5-Bi_2O_3-V_2O_5$ glass-ceramics.

• 전기화학회지
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• 제2권2호
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• pp.61-65
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• 1999

리튬이차전지용 양극물질로서 $LiV_3O_8$의 새로운 합성방법이 그 전기화학적 거동을 향상시키는 것으로 제안되고 있다. $LiV_3O_8$을 수용성 lithium trivanadate 겔의 탈수에 의해 잘 분산된 형태로 얻어진다. $LiV_3O_8$의 초음파처리방법은 solutionmethod에 의해 만들어진 초기상태의 $LiV_3O_8$과 비교된다. 수용액상에서 초음파처리 된 물질은 XRD, TGA, SEM등으로 물리적특성을 확인하였다. 이런 방법들은 수용성 $LiV_3O_8$의 초음파처리공정이 결정성을 감소시키고 비표면적과 공간용량을 향상시키는 것으로 나타났다. 특히 2시간 동안 초음파처리한 것은 높은 방전용량을 가지며, 대용량의 손실없이 충방전사이클이 이루어졌다. 따라서, 초음파처리 된 $LiV_3O_8$은 공간용량을 향상시킬 뿐만 아니라 사이클거동 역시 향상되었다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1997년도 하계학술대회 논문집 C
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• pp.1591-1593
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• 1997

The purpose of this study is to research and develop $Li_xV_3O_8$ composite cathode for lithium polymer battery. We investigated electrochemical, interfacial properties and charge/discharge cycling of $Li_xV_3O_8$/SPE/Li cell. The radius of semicircle associated with the interfacial resistance of $Li_xV_3O_8$/SPE/Li cell increased very slowly during discharge process from 100% SOC to 90% SOC. And then the cell resistance was increased at discharge process from 10% SOC to 0% SOC. The discharge capacity based on $Li_xV_3O_8$ was 212mAh/g at 15th cycle. The $Li_xV_3O_8$/SPE/Li cell has a good properties.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1998년도 추계학술대회 논문집
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• pp.29-32
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• 1998

A new treatment of LiV$_3$O$_{8}$ has beer proposed for improving its electrochemical behavior as a cathode material secondary lithium batteries. Early in its development, the preparation method of LiV$_3$O$_{8}$ strongly influenced its electrochemical properties, such as discharge capacity, rate capability and cycling efficiency. In the present experiment, a new synthesis route has been applied to obtain LiV$_3$O$_{8}$ . Instead of the conventional high temperature technique leading to the crystalline form, a solution technique producing the amorphous form has been used. This material, after dehydration, shows an electrochemical performance exceeding that of the crystalline one. These measurements showed that the ultrasonic treatment process of crystalline LiV$_3$O$_{8}$ causes a decrease in crystallinity and considerable increases in specific surface area and interlayer spacing. So the ultrasonic method provides a convenient means for improving the electrochemical behavior of LiV$_3$O$_{8}$ as a cathode material for secondary lithium batteries.batteries.

• 공업화학
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• 제7권2호
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• pp.362-370
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• 1996

$Li/V_6O_{13}$ 전지의 성능과 poly(acrylonitrile)[PAN]계 폴리머 전해질의 전기화학적인 성질을 조사 하였다. 폴리머 전해질의 이온 전도도는 상온에서 $2.3{\times}10^{-3}S/cm$를 보였으며 리튬 전극과의 상용성도 우수하였다. 또한 4.3V(vs. $Li^+/Li$)까지의 전기화학적인 안정성이 있는 것으로 나타났다. $Li/V_6O_{13}$ 전지 반응은 $V_6O_{13}$ 전극과 폴리머 전해질간의 계면 저항이 지배적 이었다. $V_6O_{13}$내의 리튬 이온의 확산 계수값은 $2.7{\times}10^{-9}{\sim}4.2{\times}10^{-8}cm^2/sec$로 나타났다. $V_6O_{13}$ 활물질의 이용률은 C/8($50{\mu}A/cm^2$)에서 95%였으며 C/4($100{\mu}A/cm^2$)에서는 82%로 각각 나타났다.

• 한국전기전자재료학회논문지
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• 제14권8호
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• pp.652-657
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• 2001

Vanadate glasses containing 10~20mol% glass former, P$_2$O$_{5}$ were prepared by melting the batch in platinum crucible and quenching on the copper plate. Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics having LiV$_3$O$_{8}$ were obtained by heat-treatment of this glass in crystallization temperature. The glass-ceramics showed singnificantly good capacity and long cycles life according to heating condition. In this paper, we described electrochemical properties during crystallization process and found the best crystallizaton condition of Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass as cathode material. Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics heat-treated at 233$^{\circ}C$ for 3 hors showed good rechargeable capacity of 220mAh/g in the cycling range between 2.0 and 3.9V.en 2.0 and 3.9V.