• Title/Summary/Keyword: LiBr-water solution

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Thermodynamic Analysis of Double-effect Absorption Heat Pump System with New Working Pairs (작동매체에 따른 2중효용 흡수식 시스템의 성능해석)

  • Won, S.H.;Lee, Y.S.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.3 no.4
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    • pp.250-255
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    • 1991
  • Performance analysis of double-effect absorption heat pump system has been done to find improved working pairs (or mixture) by computer simulation. Based on the thermodynamic analysis, the coefficient of performance and mass flow ratio are investigated to compare three aqueous solutions [LiCl-water, LiSCN-LiBr-water, LiCl-$CaCl_2$-$Zn(NO_3)_2$-water] which was developed for only cooling, with conventional LiBr-water solution. It is found that the performances of the new aqueous solutions are better than that of LiBr-water solution not only in cooling systems, but also in heating systems. Theoretical thermodynamic performance data can be used in heat recovery systems by basic design data.

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Characteristic Analysis of Double Effect Absorption Refrigeration Machine using $H_{2}O/LiBr+HO{(CH_{2})}_{3}OH$ ($H_{2}O/LiBr+HO{(CH_{2})}_{3}OH$를 이용한 2중 효용 흡수식 냉동기 특성해석)

  • 문춘근
    • Journal of Advanced Marine Engineering and Technology
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    • v.22 no.6
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    • pp.792-799
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    • 1998
  • Further improvement of existing $H_{2}O/LiBr$ absorption refrigeration machine is absolutely neces-sary to promote the utilization of gas-cooling system Among various methods to improve the per-formance of the absorption refrigeration machine this research has focused on the use of a new working fluid that has better properties than the existing $H_{2}O/LiBr$ working fluid. In the series of the research, $H_{2}O/LiBr+HO{(CH_{2})}_{3}OH$ system was selected as the most promisable candidate. The absorption refrigeration machine is water-cooled double-effect, $H_{2}O/LiBr+HO{(CH_{2})}_{3}OH$ sys-tem with series flow type. In this study we found out the characteristic of new working solution through the cycle simulation and compared the result with that of LiBr solution to evaluate. Theoptimum designs and operating conditions were determined based on the operating constraints and the coefficient of performance. Results demonstrate that new working fluid subsrantially increases COP by as much as 10% and has a wider working range with 8% higher crystallization limits compared to the conventional $H_{2}O/LiBr$.

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An investigation of absorption phenomena in the horizontal staggered tube absorber for various LiBr solution flow rates (LiBr용액량 변화에 따른 수평다관 흡수기의 특성 연구)

  • Kwon, Yul;Yoon, Sang-Guk
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.3
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    • pp.332-338
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    • 1999
  • An experimental study of absorption phenomena of water vapor into LiBr solution was carried out to find out the optimum solution flow rate. The staggered bundle of horizontal absorption tubes, which are the same configuration as the commercial heat pump, were tested. The results showed that the heat transfer and absorption rate were enhanced with the increase of LiBr solution flow rate. Those values for different absorber pressures showed the same qualitative trends. The optimum flow rate of solution was obtained as three times of the designed flow rate.

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Heat Transfer Enhancement Characteristics for Falling-Film Evaporation on Horizontal Enhanced Tubes with Aqueous LiBr Solution (LiBr 수용액을 이용한 수평관 유하액막 증발의 촉진관 전열향상 특성)

  • Kim, Dong Kwan;Kim, Moo Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.9
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    • pp.1267-1276
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    • 1998
  • Falling-film evaporation experiments with aqueous lithium bromide (LiBr) solution were performed to investigate the heat transfer characteristics of enhanced copper tubes. Enhanced tubes (a knurled tube, a spirally grooved tube, and a tube coated with $20{\mu}m$ aluminum particles) and a bare tube were selected as test specimens. Averaged evaporation fluxes of water were obtained from horizontal tubes with various film Reynolds numbers, system pressures, LiBr concentrations and degrees of wall superheat. The enhanced performance of steam generation was compared between tubes with varying parameters. The knurled tube geometry showed the most excellent performance among the tubes tested. The specified enhanced tubes were more useful for generating steam on a low grade heat source such as waste heat.

Coupled Heat and Mass Transfer in Absorption of Water Vapor into LiBr-$H_2O$ Solution Flowing over a Finned Inclined Surface (좁은 휜이 달린 경사면을 흐르는 리튬브로마이드 수용액 흡수기에서의 열 및 물질전달)

  • 조은준;서태범
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.13 no.9
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    • pp.860-867
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    • 2001
  • Absorption of water vapor into LiBr-$H_2O$ O solution flowing over a finned inclined surface is numerically investigated. The momentum, energy, and diffusion equation are numerically solved using a finite difference method. The four different shapes of the wall surfaces are considered to find the best surface for absorption assuming that the wall temperature and the surface tension are constant. The effects of the fin interval and Reynolds number are investigated. Based on the numerical results, it is known that the parabolic surface shows better absorption performance than the other surfaces, and that water vapor absorption increases gradually with decreasing the fin interval.

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The Effect of LiBr Concentration on Corrosion of Absorption Refrigeration Systems Using $LiBr-H_2O$ Working Fluids ($LiBr-H_2O$계 흡수식냉동기의 부식에 미치는 LiBr 농도의 영향)

  • Lim Uh Joh;Jeong Ki Cheol
    • Journal of the Korean Institute of Gas
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    • v.5 no.4 s.16
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    • pp.33-39
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    • 2001
  • This paper was studied on corrosion behavior of absorption refrigeration systems using $LiBr-H_2O$ working fluids. In the various concentration of lithium bromide solution, polarization test of SS 400, Cu(C1220T-OL) and Al-Ni bronze is carried out. And the corrosion behavior of materials forming absorption refrigeration systems is investigated. The main results are as following: 1) As concentration of lithium bromide solution increases, polarization resistance of materials of each kinds is low. And open circuit potential becomes less noble, the corrosion current density is high drained 2) Open circuit potential of SS 400 is less noble than that of Cu and Al-Ni bronze, corrosion current density of SS5 400 is high drained than that of Cu and Al-Ni bronze. 3) Anodic polarization of Cu and Al-Ni bronze in $62\%$ LiBr solution continues the active state. that of Cu and Al-Ni bronze in the natural sea water maintains the active state and the critical current for passivation appears.

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Cycle Analysis of Air-Cooled Double-Effect Absorption Cooling System Using H2O/LiBr+HO(CH2)3OH (H2O/LiBr+HO(CH2)3OH계 공냉형 이중효용 흡수식 냉방시스템의 사이클 해석)

  • Kwon, Oh-Kyung;Moon, Choon-Geun;Yoon, Jung-In
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.2
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    • pp.272-280
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    • 1999
  • A cycle analysis was achieved to predict the characteristics by comprehensive modeling and simulation of an air-cooled, double-effect absorption system using a new $H_2O/LiBr+HO(CH_2)_3OH$ solution. The simulation results showed that the new working fluid may provide the crystallization limit 8% higher than the conventional $H_2O/LiBr$ solution. With a crystallization margin of 3wt%(weight%), the optimal solution distribution ratio was found in the range of 36 to 40%. Variation of cooling air Inlet temperature has a sensitive effect on the cooling COP and corrosion problem. The simulation of heat exchangers with UA value revealed that the absorber and the evaporator are relatively important for an air-cooled system compared with the condenser and the low temperature generator. The effect of cooling air flow rate, circulation weak solution flow rate and chilled water inlet temperature were also examined. The new working fluid may provide the COP approximately 5% higher than the conventional $H_2O/LiBr$ solution.

Performance Analysis of New Working Solution for Absorption Refrigeration Machine using Treated Sewage (하수처리수이용 신용액 흡수식 냉동기의 성능해석)

  • 권오경;유선일;윤정인
    • Journal of Energy Engineering
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    • v.7 no.2
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    • pp.231-240
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    • 1998
  • The global environmental problems such as CFC, energy losses in heat recovery system as well as summer peak time power demands, the development of high efficiency absorption refrigeration systems is one of the most promising method in this problems. The absorption refrigeration system to utilize treated sewage is available for environmental protection and energy conservation. Simulation analysis on the double-effect absorption refrigeration cucles with parallel or series flow type has been performed. LiBr+LiI+LiCl+LiNO$_3$ solution was selected as the new working fluid. The main purpose of this study is evaluating the possibilities of effective utilization of treated sewage as a cooling water for the absorber and condenser. The other purpose of the present study is to determine the optimum designs and operating conditions based on the operating constraints and the coefficient of performance in the parallel or series flow type. In this study, we found out the characteristic of new working solution through the cycle simulation and compared LiBr solution to evaluate. The absorption refrigeration machine using the new working fluid was obtained better results COP rise and compactness of system by comparison with LiBr solution.

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The Effect of Temperature on Corrosion of Absorption Refrigeration Systems Using LiBr-$H_2O$ Working Fluids (LiBr-$H_2O$계 흡수식냉동기의 부식에 미치는 온도의 영향)

  • 임우조;정기철;윤병두;강성수
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2001.11a
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    • pp.92-97
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    • 2001
  • This paper was studied on the effect of temperature on corrosion of absorption refrigeration systems using LiBr-$H_2O$ working fluids. In the fresh water and 62 %lithium bromide solution at $70^{\circ}C$, polarization test of SS 400, Cu(Cl220T-OL) and Ni-Al bronze was carried out. And Polarization behavior, polarization resistance characteristics, corrosion rate(mmpy) and corrosion sensitivity of materials forming absorption refrigeration systems was considered. The main results are as following: As the experimental temperature increase, the change of corrosion rate of Ni-Al bronze become duller than SS 400 and Cu in 62 % lithium bromide solution. Open circuit potential of SS 400 is less noble than that of Cu and Ni-Al bronze in fresh water, but that becomes noble than Cu and Ni-Al bronze in 62 % lithium bromide solution. The corrosion sensitivity of Ni-Al bronze was controlled than that of Cu and SS 400 in 62% LiBr solution.

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An Experimental Study on Flow and Heat / Mass Transfer Characteristics of $LiBr-H_2O$ Solution Flowing over a Cooled Horizontal Tube (수평 냉각관 외부를 흘러내리는 $LiBr-H_2O$ 수용액의 유동 및 열/물질 전달 특성에 관한 실험적 연구)

  • Seal, Sin-Su;Lee, Sang-Yang
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.8
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    • pp.1085-1096
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    • 2000
  • An experimental study was performed to examine the heat and mass transfer characteristics of $LiBr-H_2O$ solution flowing over a single horizontal tube with the water vapor absorption. Effects of the flow rate and the temperature of the solution at the top of the tube, the absorber pressure and the drainage pattern were considered. The absorption rate depends highly on the absorber pressure at the low flow rate condition while on the solution inlet temperature at the high flow rate condition. Also, when the flow rate is low, the absorption performance with the sheet flow drainage appeared to be higher than that with the dripping/jet drainage. However, at the high flow rate condition, the case became reversed. The liquid film became wavy with the higher absorption rate. The waves were more probable to form with the lower flow rate and temperature of the solution, and with the higher absorber pressure.