• Applied Chemistry for Engineering
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• v.10 no.3
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• pp.400-406
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• 1999

In an effort to obtain high efficiency in gas fired absorption chillers, a new working fluid has been developed with thc addition of the component of $LiNO_3$, LiCl and LiI to the conventional solution of $LiBr-H_2O$. The solubility and vapor pressure of the 4 component working fluid developed in this work were measured and compared to the results of $LiBr-H_2O$ solution. It was observed that there exists an optimal mole ratio of the inorganic salts in terms of solubility. The mole ratio of LiBr, $LiNO_3$ and LiCl was found to be around 5:1:1~2 in the $LiBr-LiNO_3-LiCl-H_2O$ mixture, and in the case of $LiBr-LiO_3-Lil-H_2O$ and $LiBr-Lil-LiCl-H_2O$ mixtures, the mole ratio of LiBr, $LiNO_3$ and Lil/ LiBr, LiI and LiCl were found to be around 5:1:1 and 5:1:0.5~1 respectively. The vapor pressure of the 4 component working fluid of the optimal mole ratio was increascd with adding the component of $LiNO_3$, LiCl and LiI except for $LiBr-LiNO_3-LiCl-H_2O$ mixture. The absorption capacity of $LiBr-LiNO_3-LiCl-H_2O$ mixture was obtained higher than that of $LiBr-H_2O$ mixture.

• Journal of the Korean Solar Energy Society
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• v.25 no.3
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• pp.27-35
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• 2005

In this paper, a thermodynamic analysis was performed to provide design data for a double-effect absorption heating system with water-LiBr-LiSCN mixture which utilizes solar energy as evaporator heat source. In addition, a comparative study of the water-LiBr-LiSCN mixture against the water-LiBr pair was conducted by a computer simulation. The computer simulation is based on mass, material and heat balance equations for each part of the system. Coefficients of performance and flow ratios for effects of different operating temperatures are investigated. It is found that the heating COP is higher for the water-LiBr-LiSCN mixture than for the water-LiBr pair, and FR is lower for the former.

• Journal of the Korean Institute of Gas
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• v.2 no.4
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• pp.47-52
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• 1998

Water vapor absorption performance of four components solution ($LiBr+LiNO_3+LiC1+H_2O$) which could be substituted for commonly used $LiBr/H_2O$ solution in water cooled abosorption chiller is tested using a vertical tube absorber. Inlet solution concentration, inlet solution temperature, solution flow rate and inlet temperature of cooling water is varied as experimental parameters. The results of the experiment of water vapor absorption performance show that four components solution should have $2\%$ higher concentration for equal absorption capacity of $LiBr/H_2O$. But considering that four components solution have higher solubility than LiBr solution about $3\%$ high oncentration, four components solution ($LiBr+LiNO_3+LiC1+H_2O$) have more absorption capacity than LiBr solution in actual absorption chiller and can be applied to a small or air cooled absorption chiller.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.5
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• pp.27-34
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• 2018

Recently, liquid desiccant systems have received attention for the dehumidification of air. LiCl and LiBr are widely used in liquid desiccant systems due to their excellent thermo-physical properties. In this study, dehumidification tests were conducted with Celdek elements using LiCl and LiBr. During the tests, the dry and wet-bulb air temperatures were maintained at $35^{\circ}C$ and $28^{\circ}C$, respectively. The solution temperature was $20^{\circ}C$, the solution concentration was 50%, the solution circulation rate was 50 kg/h, and the frontal air velocity was varied from 2.0 to 4.0 m/s. The results show that the amount of dehumidification increased as the frontal velocity increased. On average, LiCl showed 27% higher dehumidification performance than LiBr, which was probably due to the lower saturation of the absolute humidity of LiCl compared with that of LiBr. On the other hand, LiBr yielded 12% larger pressure drop than LiCl. In general, the Sherwood numbers of LiCl and LiBr were approximately the same, showing that the effect of the desiccant on the Sherwood number was insignificant. Existing correlations highly overpredicted the present Sherwood numbers.

• Applied Chemistry for Engineering
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• v.9 no.1
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• pp.82-88
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• 1998

In an effort to obtain high efficiency in air cooled absorption heat pump, a new working fluid has developed with the addition of $LiNO_3$ and LiCl to the conventional solution of $LiBr-H_2O$. The solubility and vapor pressure of the multicomponent salts solution developed in this work were measured and compared with the results of $LiBr-H_2O$ solution. It was observed that there exists an optimal molar ratio of the inorganic salts in terms of solubility. The molar ratio of LiBr, $LiNO_3$ and LiCl was found to be about 5:1 in the $LiBr-LiNO_3$ mixture, and in the case of $LiBr-LiNO_3-LiCl$ mixture, the molar ratio of LiBr, $LiNO_3$ and LiCl was found to be around 5:1:2. The vapor pressure of the multicomponent salts solution of the optimal molar ratio was increased with adding $LiNO_3$, while decreased with adding LiCl.

• Journal of the Korean Solar Energy Society
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• v.26 no.4
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• pp.73-81
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• 2006

In this paper, with water-LiBr-LiSCN mixture which utilizes solar energy as mid temperature range evaporator heat source, a thermodynamic analysis was performed to provide design data for a double-effect absorption heating system. A comparative study of the water-LiBr-LiSCN mixture against the water-LiBr pair was conducted by a computer simulation. The computer simulation is based on mass, material and heat balance equations for each part of the system. Coefficients of performance and flow ratios for effects of different operating temperatures are investigated. It is found that the heating COP is higher for the water-LiBr-LiSCN mixture than for the water-LiBr pair, and FR is lower for the former.

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.228-233
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• 2000

An experimental study has been performed regarding heat and mass transfer in a falling film absorber of domestic small-sized absorption chiller/heater. Components were concentrically arranged in cylindrical form : from the center, with a series of low temperature generator, absorber and evaporator. The arrangement of such helical-typed heat exchangers allows to make the system more compact as compared to conventional one. Experimental measurements were conducted with a helical absorber using $LiBr+LiI+LiNO_3+LiCl$ and LiBr solutions. As a result, the heat and mass flux performance of $LiBr+LiI+LiNO_3+LiCl$ solution shows the tendency of $2{\sim}5%$ increase. Therefore, $LiBr+LiI+LiNO_3+LiCl$ solution can be taken consideration into applying to small-sized absorption chiller/heater because of using without crystal through high concentration as 4wt% comparing with LiBr solution.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.9 no.2
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• pp.163-170
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• 1997

Solubility on $(LiBr+CaCl_2)$ in water has been measured systematically and compared with those of pure LiBr. It has been observed that there exists optimum value of $CaCl_2(LiBr+CaCl_2)$ in solubility when total$(LiBr+CaCl_2)$ concentration is higher than 57wt%. As total concentration increases up to 65wt%, it is found that the optimum value also increases monotonically. From the experimental results, a master plot has been constructed, with which optimum ratio of LiBr to $CaCl_2$ can be found in terms of total concentration. Vapor pressure of $H_2O/(LiBr+CaCl_2)$ solution with optimum contents of $CaCl_2$ has been observed to be changed negligibly at relatiely low temperature. However, as temperature increases, it is found that increasement in vapor pressure is significant.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.7 no.2
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• pp.196-206
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• 1995

Experimental investigations on heat and mass transfer characteristics in a vertical tube absorber have been carried out. Three different copper tubes with a length of 1.5m have been tested using LiBr solution and LiBr-$CaCl_2$ solution. The effects of solution flow rate, cooling water temperature, solution inlet temperature and evaporation temperature have been investigated in detail. It is found that heat transfer coefficient increases gradually with the increase of solution flow rate, but decreases rapidly for the flow rates less than 0.02kg/ms. The grooved tube generally shows better heat transfer performances than the smooth tube. LiBr solution shows almost no absorption capability for the cooling water temperatures over $40^{\circ}C$. LiBr-$CaCl_2$ gives less decreasing rate in absorption capability at these temperatures and the heat transfer coefficient becomes less dependent on the types of tubes in use. Considering heat and mass transfer rates, LiBr-$CaCl_2$ solution is found to be more suitable than LiBr solution for air cooled absorber, which operates at higher temperature than water cooled absorber.

• Journal of Advanced Marine Engineering and Technology
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• v.22 no.6
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• pp.792-799
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• 1998

Further improvement of existing $H_{2}O/LiBr$ absorption refrigeration machine is absolutely neces-sary to promote the utilization of gas-cooling system Among various methods to improve the per-formance of the absorption refrigeration machine this research has focused on the use of a new working fluid that has better properties than the existing $H_{2}O/LiBr$ working fluid. In the series of the research, $H_{2}O/LiBr+HO{(CH_{2})}_{3}OH$ system was selected as the most promisable candidate. The absorption refrigeration machine is water-cooled double-effect, $H_{2}O/LiBr+HO{(CH_{2})}_{3}OH$ sys-tem with series flow type. In this study we found out the characteristic of new working solution through the cycle simulation and compared the result with that of LiBr solution to evaluate. Theoptimum designs and operating conditions were determined based on the operating constraints and the coefficient of performance. Results demonstrate that new working fluid subsrantially increases COP by as much as 10% and has a wider working range with 8% higher crystallization limits compared to the conventional $H_{2}O/LiBr$.