• Title/Summary/Keyword: Li2CO3

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Remediation of Diesel Contaminated Soil Using Flowing Subcritical Water (흐름식 아임계수에 의한 경유오염토양의 정화)

  • Li, Guang-Chun;Jung, Sun-Kook;Chung, Seon-Yong;Jo, Young-Tae;Park, Jeong-Hun
    • Journal of Soil and Groundwater Environment
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    • v.16 no.3
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    • pp.10-16
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    • 2011
  • The experimental studies for remediation of diesel contaminated soils were performed using subcritical water in laboratory scale. Contaminated soils from industrial area and artificially contaminated soils were utilized for soil remediation. Experimental system was composed for subcritical water to flow upward through the soil packed column for extracting contaminants. 10 g of contaminated soil was packed into the column and water flow rate was 2 mL/min. To evaluate the effects of temperature, pressure and treatment time on the removal efficiency, temperature was changed from 100$^{\circ}C$ to 350$^{\circ}C$, pressure from 50 bar to 220 bar and treatment time at the predetermined temperature from 0 min to 120 min. The purification efficiency increased as temperature increased. However, the effect of pressure and treatment time was low. Temperature 250$^{\circ}C$, pressure 50 bar and treatment time 30 min were selected for optimal operating condition for this study.

Treatment of Oily Wastewater with WPO and CWO

  • Han, Mei;Chen, Yihui;He, Fang;Yu, Li
    • Journal of the Korean Chemical Society
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    • v.58 no.1
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    • pp.68-71
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    • 2014
  • Petroleum refining unavoidably generates large volumes of oily wastewater. The environmentally acceptable disposal of oily wastewater is a current challenge to the petroleum industry. Nowadays, more attentions have been focused on the treatment techniques of oily wastewater. Oily wastewater contained highly concentrated and toxic organic compounds. Wet peroxide oxidation (WPO) and catalytic wet oxidation (CWO) were applied to eliminate pollutants to examine the feasibility of the WPO/CWO of oily wastewater. The results indicated that more than 80% chemical oxygen demand (COD) removal from oily wastewater was achieved with CWO. Homogenous catalyst, $NaHCO_3$ and $Na_2CO_3$ and NaOH showed effective removal for pollutants in oily wastewater. Greater than 90% COD removal was achieved with WPO. It was concluded that WPO was a far more effective process for oily wastewater.

An Economic Assessment of Large-scale Battery Energy Storage Systems in the Energy-Shift Application to Korea Power System (장주기 대용량 전력저장장치의 부하이전에 대한 실계통 적용 경제성 평가 연구)

  • Park, Jong-Bae;Park, Yong-Gi;Roh, Jae-Hyung;Chang, Byung-Hoon;Toon, Yong-Beum
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.64 no.3
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    • pp.384-392
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    • 2015
  • This paper presents an economic assessment of large-scale Li-ion battery energy storage systems applied to Korean power system. There are many applications of the battery energy storage systems (BESSs) and they can provide various benefits to power systems. We consider BESSs to the energy time-shift application to Korean power system and evaluate the benefits from the application of BESS in the social perspective. The mixed integer programming (MIP) algorithm is used to resolve the optimal operation schedule of the BESS. The social benefits can include the savings of the fuel cost from generating units, deferral effects of the generation capacity, delay of transmission and distribution infra construction, and incremental CO2 emission cost impacts, etc. The economic evaluation of the BESS is separately applied into Korean power systems of the Main-land and Jeju island to reflect the differences of the load and generation patterns.

PEO/PPC based Composite Solid Electrolyte for Room Temperature Operable All Solid-State Batteries (상온에서 작동되는 전고체전지 용 PEO/PPC 기반의 복합 고체 전해질)

  • Shin, Sohyeon;Kim, Sunghoon;Cho, Younghyun;Ahn, Wook
    • Journal of the Korean Electrochemical Society
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    • v.25 no.3
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    • pp.105-112
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    • 2022
  • For the commercialization of all-solid-state batteries, it is essential to develop a solid electrolyte that can be operable at room temperature, and it is necessary to manufacture all-solid-state batteries by adopting materials with high ionic conductivity. Therefore, in order to increase the ionic conductivity of the existing oxide-based solid, Li7La3Zr2O12 (LLZO) doped with heterogeneous elements was used as a filler material (Al and Nb-LLZO). An electrolyte with garnet-type inorganic filler doped was prepared. The binary metal element and the polymer mixture of poly(ethylene oxide)/poly(propylene carbonate) (PEO/PPC) (1:1) are uniformly manufactured at a ratio of 1:2.4, The electrochemical performance was tested at room temperature and 60 ℃ to verify room temperature operability of the all-solid-state battery. The prepared composite electrolyte shows improved ionic conductivity derived from co-doping of the binary elements, and the PPC helps to improve the ionic conductivity, thereby increasing the capacity of all-solid-state batteries at room temperature as well as 60 ℃. It was confirmed that the capacity retention rate was improved.

The Study on Costume in Palhae and Shilla (발해와 신라의 복식 비교 연구)

  • 전현실;유송옥
    • Journal of the Korean Society of Costume
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    • v.50 no.6
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    • pp.109-125
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    • 2000
  • As the result of the study of this thesis, the costume of Palhae and Shilla shows the many similarity. 1. The two centuries introduced the system of four-colored official uniform. This official uniforms are BokDoo(복두), DanLyung(團領) and Dae(帶). BanLyung of Palhae are GyulGoPo(결과포), leather belt and that of Shilla are GyulGoPo, YuLanPo(유란포), KwaDae(과대) Similarly BokDoo shows the long Gak(脚) in back. 2. Yu(유) and Ko(袴), the native costumes have worn even after the period of the three countries. 3. The two countries wore DanLyung. A man In Palhae wore GyulGoPo(결과포), leather belt and a man in Shilla wore GyulGoPo, YuLanPo(유란포), KwaDae(과대). 4. A woman in Palhae wore SangEui(上衣), Sang(裳), JikLyung(直領) one by one. And over Sang wrapped PoBaekDae(布帛帶) and covered the shoulder by UnGyun(雲肩). A woman in Shilla wore SangEui, Sang, PoBaekDea one by one and covered the shoulder by Pyo(표). 5. The two countries put on Rib(笠) and similary shoes. Rib insists of Moche(帽體), ChaYang(次養) and can classify the estate by decoration. A man wore Wha(靴), Li(履) and a woman wore KoDooLi(高頭履). This similarity is the result by the cultural interchange between Palhae and Shilla. There are the five reasons. Interchange by the envoy's visit. Interchange through Shillado(新羅道), Interchange in T'ang Dynasty, Interchange in Japan, Interchange of Buddhist culture. By the cultural interchange between Palhae(渤海) and Shilla(新羅), the shape of costume is similary. The meaning of this similarity of costume equals to the similarity of culture. We will approval Palhae is the co-subject of Korean history with Shilla and will name as "The period of NamBukKuk(南北國時代)" from the late 7th century to the early 10th century in the academy of the history of Korean Costume.

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Gold Abundance in Aicd-Sulfate Alteration Zone of the Ogmaesan-Seongsan Ore Deposits in Haenam Area, Korea (해남 옥매산-성산광산 Acid-Sulfate 변질대에서 금 함량에 관한 연구)

  • Yoon, Chung-Han
    • Economic and Environmental Geology
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    • v.26 no.2
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    • pp.155-166
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    • 1993
  • Gold contents with major and trace elements have been determined in 67 fresh igneous and altered wall rocks in the acid-sulfate alteration zone of the Ogmaesan-Seongsan pyrophyllite deposits in the Haenam area of the south-western part of Korean peninsula. The results are as follows; (1) Li contents have a tendency to show high value in dickite and altered rocks with dickite, while As, Mo and Sb contents have tendencies to show high values in alunite vein and silicified zone. F contents are higher in the altered rocks compared to fresh rocks. (2) Gold contents are enriched in alunite vein and silicified zone of the Seongsan deposit, but depleted in dickite and altered rock with dickite. Gold contents are especially concentrated in fault or conjunction area of two faults. (3) Gold contents are higher values in the mineral assemblages of alunite-quartz-pyrite and alteration zone of the Seongsan deposit among the studied deposits. (4) Gold contents in samples of silicified zones tend to show positive correlations with Ag, As, Co, Hg, Sb and V content, but negative correlations with Y and Zr contents, while on the other gold contents of silicified tuffs tend to show positive correlations with Hg and Sb contents. Therefore it is important to survey alunite vein and silicified zone at the conjunction of faults, and to analyze pathfinder elements such as Ag, As, Hg and Sb for geological and geochemical exploration of gold in the studied deposits.

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Numerical study of wake and aerodynamic forces on a twin-box bridge deck with different gap ratios

  • Shang, Jingmiao;Zhou, Qiang;Liao, Haili;Larsen, Allan;Wang, Jin;Li, Mingshui
    • Wind and Structures
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    • v.30 no.4
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    • pp.367-378
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    • 2020
  • Two-dimensional Delayed Detached Eddy Simulation (DDES) was carried out to investigate the uniform flow over a twin-box bridge deck (TBBD) with various gap ratios of L/C=5.1%, 12.8%, 25.6%, 38.5%, 73.3% and 108.2% (L: the gap-width between two girders, C: the chord length of a single girder) at Reynolds number, Re=4×104. The aerodynamic coefficients of the prototype deck with gap ratio of 73.3% obtained from the present simulation were compared with the previous experimental and numerical data for different attack angles to validate the present numerical method. Particular attention is devoted to the fluctuating pressure distribution and forces, shear layer reattachment position, wake velocity and flow pattern in order to understand the effects of gap ratio on dynamic flow interaction with the twin-box bridge deck. The flow structure is sensitive to the gap, thus a change in L/C thus leads to single-side shedding regime at L/C≤25.6%, and co-shedding regime at L/C≥35.8% distinguished by drastic changes in flow structure and vortex shedding. The gap-ratio-dependent Strouhal number gradually increases from 0.12 to 0.27, though the domain frequencies of vortices shedding from two girders are identical. The mean and fluctuating pressure distributions is significantly influenced by the flow pattern, and thus the fluctuating lift force on two girders increases or decreases with increasing of L/C in the single-side shedding and co-shedding regime, respectively. In addition, the flow mechanisms for the variation in aerodynamic performance with respect to gap ratios are discussed in detail.

Alterations of mRNA and lncRNA profiles associated with the extracellular matrix and spermatogenesis in goats

  • Chen, Haolin;Miao Xiaomeng;Xu, Jinge;Pu, Ling;Li, Liang;Han, Yong;Mao, Fengxian;Ma, Youji
    • Animal Bioscience
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    • v.35 no.4
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    • pp.544-555
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    • 2022
  • Objective: Spermatozoa are produced within the seminiferous tubules after sexual maturity. The expression levels of mRNAs and lncRNAs in testicular tissues are different at each stage of testicular development and are closely related to formation of the extracellular matrix (ECM) and spermatogenesis. Therefore, we set out to study the expression of lncRNAs and mRNAs during the different developmental stages of the goat testis. Methods: We constructed 12 RNA libraries using testicular tissues from goats aged 3, 6, and 12 months, and studied the functions of mRNAs and lncRNAs using the gene ontogeny (GO) and Kyoto encyclopedia of genes and genomes (KEGG) databases. Relationships between differentially expressed genes (DEGs) were analyzed by lncRNA-mRNA co-expression network and protein-protein interaction network (PPI). Finally, the protein expression levels of matrix metalloproteinase 2 (MMP2), insulin-like growth factor 2 (IGF2), and insulin-like growth factor-binding protein 6 (IGFBP6) were detected by western blotting. Results: We found 23, 8, and 135 differentially expressed lncRNAs and 161, 12, and 665 differentially expressed mRNAs that were identified between 3 vs 6, 6 vs 12, and 3 vs 12 months, respectively. GO, KEGG, and PPI analyses showed that the differential genes were mainly related to the ECM. Moreover, MMP2 was a hub gene and co-expressed with the lncRNA TCONS-0002139 and TCONS-00093342. The results of quantitative reverse-transcription polymerase chain reaction verification were consistent with those of RNA-seq sequencing. The expression trends of MMP2, IGF2, and IGFBP6 protein were the same as that of mRNA, which all decreased with age. IGF2 and MMP2 were significantly different in the 3 vs 6-month-old group (p<0.05). Conclusion: These results improve our understanding of the molecular mechanisms involved in sexual maturation of the goat testis.

Characterization of a Recombinant Thermostable Xylanase from Hot Spring Thermophilic Geobacillus sp. TC-W7

  • Liu, Bin;Zhang, Ningning;Zhao, Chao;Lin, Baixue;Xie, Lianhui;Huang, Yifan
    • Journal of Microbiology and Biotechnology
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    • v.22 no.10
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    • pp.1388-1394
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    • 2012
  • A xylanase-producing thermophilic strain, Geobacillus sp. TC-W7, was isolated from a hot spring in Yongtai (Fuzhou, China). Subsequently, the xylanase gene that encoded 407 amino acids was cloned and expressed. The recombinant xylanase was purified by GST affinity chromatography and exhibited maximum activity at $75^{\circ}C$ and a pH of 8.2. The enzyme was active up to $95^{\circ}C$ and showed activity over a wide pH range of 5.2 to 10.2. Additionally, the recombinant xylanase showed high thermostability and pH stability. More than 85% of the enzyme's activity was retained after incubation at $70^{\circ}C$ for 90 min at a pH of 8.2. The activity of the recombinant xylanase was enhanced by treatment with 10 mM enzyme inhibitors (DDT, Tween-20, 2-Me, or TritonX-100) and was inhibited by EDTA or PMSF. Its functionality was stable in the presence of $Li^+$, $Na^+$, and $K^+$, but inhibited by $Hg^{2+}$, $Ni^{2+}$, $Co^{2+}$, $Cu^{2+}$, $Zn^{2+}$, $Pb^{2+}$, $Fe^{3+}$, and $Al^{3+}$. The functionality of the crude xylanase had similar properties to the recombinant xylanase except for when it was treated with $Al^{2+}$ or $Fe^{2+}$. The enzyme might be a promising candidate for various industrial applications such as the biofuel, food, and paper and pulp industries.

Effects of essential oil coated with glycerol monolaurate on growth performance, intestinal morphology, and serum profiles in weaned piglets

  • Yanan Wang;Juntao Li;Huakai Wang;Yihai Mi;Yongqiang Xue;Jiaan Li;Yongxi Ma
    • Animal Bioscience
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    • v.36 no.5
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    • pp.753-760
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    • 2023
  • Objective: This study aimed to investigate the effects of essential oil coated with glycerol monolaurate (GML) on the growth performance, intestinal morphology, and serum profiles of weaned piglets. Methods: A total of 144 weaned piglets (Duroc×[Landrace×Yorkshire], average weight 8.07±3.33 kg) were randomly assigned to three groups with six replicate pens and eight piglets per pen: i) CON: a corn-soybean basal diet; ii) LEG: with 1,000 mg/kg essential oil coated with GML; and iii) HEG: with 2,000 mg/kg essential oil coated with GML. Results: Results showed that average daily gain was increased (p<0.05) linearly by essential oil coated with GML supplementation on day 14 to 28 and day 0 to 28 compared with the CON group. Dietary supplementation with HEG increased (p<0.05) total antioxidant capacity and catalase activity on day 14, and immunoglobulin A (IgA) and IgM concentration on day 28 and tended to increase IgG on day 28. In addition, the crypt depth in the jejunum was reduced (p<0.05), and villus height and villus height/crypt depth in the ileum were increased (p<0.05) in the HEG group compared with the CON group. Moreover, lower (p<0.05) concentrations of tumor necrosis factor-α, interferon-γ, interleukin-1β (IL-1β), IL-8, and IL-10 were observed in the jejunum of piglets supplemented with HEG compared with the CON group. In addition, dietary HEG tended to decrease IL-6 level in the jejunum of piglets compared with the CON group. Conclusion: Dietary essential oil coated with GML can improve growth performance of weaned piglets. Moreover, supplementing 2,000 mg/kg essential oil coated with GML was demonstrated to improve antioxidant ability, and intestinal morphology, and reduce jejunal inflammatory factor levels.