• Journal of the Semiconductor & Display Technology
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• v.13 no.1
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• pp.101-108
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• 2014

The battery pack in this research consists of dozens of a small battery for energy storage. And this battery pack charges and discharges repeatedly at high capacity (25 ~ 50 V, 25 ~ 100 A). The high temperature which can be generated in this process has a bad effect to the lifetime and efficiency of batteries. Moreover these factors are related with maintenance cost. Therefore, we need to assess the thermal performance of the battery pack in advance using the experimental or numerical analysis. In this research, we analyzed voltage and surface temperature of one cell battery to calculate heat transfer using the numerical analysis. And the temperature of the battery surfaces and inside of the pack was also analyzed. As a result, we found out the appropriate pack structure which stacked five modules.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.21 no.12
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• pp.1130-1134
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• 2008

Thermal and electrochemical properties were discussed with tris(2,4,6-trimethoxyphenyl)Phosphine (TTMPP) as a flame retradant additive for Li-ion battery. TTMPP showed excellent thermal stability with charged cathodes. Addition of 1 wt.% of the additive to the electrolyte improved the thermal stability without damaging the performance of the battery. The oxygne evolution reaction delayed nearly by $60^{\circ}C$. The capacity retention ratio in cycle life tests of the battery with 1 wt.% TTMPP was slightly improved comparing to the no additive cells.

• Proceedings of the KIEE Conference
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• 2001.07d
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• pp.2531-2533
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• 2001

This paper describes a low noise and high efficiency analog-digital switching mixed mode battery charger for production facilities of Li-Ion batteries. The requirements for battery chargers for production facilities are very strict. The accuracy of output voltage and output current should be below 0.1% with very low ripple current. Therefore analog type linear regulators are widely used for battery charger in spite of their inefficiency and bulkiness. We combined linear regulator as a voltage source with digital switching converter as a dependent current source. Low current ripple and high accuracy are obtained by linear regulator while high efficiency is achieved by digital switching converter. Experimental results show that proposed method has 0.1% ripple and 90% efficiency at an output current of 1A for a battery voltage of 4V.

• Applied Microscopy
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• v.48 no.2
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• pp.49-53
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• 2018

A successful transmission electron microscope (TEM) analysis is closely related to the preparation of the TEM specimen and should be followed by the suitable TEM specimen preparation depending on the purpose of analysis and the subject materials. In the case of the Si-based anode material, lithium atoms of formed Li silicide were removed due to ion beam and electron beam during TEM specimen preparation and TEM observation. To overcome the problem, we proposed a new technique to make a TEM specimen without the ion beam damage. In this study, two types of test specimens from the Si-based anode material of Li-ion battery were prepared by respectively adopting the only focused ion beam (FIB) method and the new FIB-ultramicrotome method. TEM analyses of two samples were conducted to compare the Ga ion damage of the test specimen.

• Carbon letters
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• v.2 no.1
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• pp.72-75
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• 2001

The performance of Li-ion system based on $LiCoO_2$ and Graphite is well optimized for the 3C applications. The charge-discharge mode, the manufacturing process, the cell performance and the thermal reactions affecting safety has been explained in the engineering point of view. The energy density of the current LIB system is in the range of 300~400 Wh/l. In order to achieve the energy density higher than 500 Wh/l, the active materials should be modified or changed. Adopting new high capacity anode materials would be effective to improve energy density.

• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.1
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• pp.130-136
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• 2009

A lumped parameter model of Li-ion battery in hybrid electric vehicle(HEV) is constructed and system parameters are identified by using recursive least square estimation for different C-rates, SOCs and temperatures. The system characteristics of pole and zero in frequency domain are analyzed with the parameters obtained from different conditions. The parameterized model of Li-ion battery indicates highly dependant of temperatures. The system pole and internal resistance changes 6.6 and 18 times at $-20^{\circ}C$, comparing with those at $25^{\circ}C$, respectively. These results will be utilized on constructing model-based state observer or an on-line identification and an adaptation of the model parameters in battery management systems for hybrid electric vehicle applications.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.2
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• pp.212-218
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• 2018

Li-ion battery system is regarded as one of the most potent power sources for electrified power-trains. For the Li-ion battery system to be widely adopted in automotive applications, the performance, safety, and cycle life issues need to be properly addressed. These issues are closely related to the thermal management of battery system. Especially, the effective cooling module design is the core part for the novel battery thermal management system development. In this paper, an experimental approach was carried out as a basic part of comprehensive battery thermal management research. The main goal of this paper is to present a comparison of two cooling systems (air cooling and phase change material (PCM) based cooling) of the unit 18650 battery module. The temperature rise with different battery discharge rate (c-rate) was mainly investigated and analyzed for two types of battery cooling systems. It is expected that this study can properly contribute to providing basic insights into the design of robust battery thermal management system for vehicular applications.

• Proceedings of the KIEE Conference
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• 1996.07c
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• pp.1412-1413
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• 1996

Li ion battery have many advantages such as high energy density, high voltage and low self discharge, so it will replace conventional Ni/Cd battery. But, charge-discharge characterization of Li battery is controlled by weight ratio of electrodes (Cathode/Anode). So, we performed a study on relation between charge/discharge characterization and weight ratio (cathode/anode).

• Journal of Electrochemical Science and Technology
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• v.5 no.2
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• pp.37-44
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• 2014

The $Li-O_2$ battery has been attracting much attention recently, due to its very high theoretical capacity compared with Li-ion chemistries. Nevertheless, several studies within the last few years revealed that Li-ion derived electrolytes based on alkyl carbonate solvents, which have been commonly used in the last 27 years, are irreversibly consumed at the $O_2$ electrode. Accordingly, more stable electrolytes are required capable to operate with both the Li metal anode and the $O_2$ cathode. Thus, due to their favorable properties such as non volatility, chemical inertia, and favorable behavior toward the Li metal electrode, ionic liquid-based electrolytes have gathered increasing attention from the scientific community for its application in $Li-O_2$ batteries. However, the scale-up of Li-$O_2$ technology to real application requires solving the mass transport limitation, especially for supplying oxygen to the cathode. Hence, the 'LABOHR' project proposes the introduction of a flooded cathode configuration and the circulation of the electrolyte, which is then used as an oxygen carrier from an external $O_2$ harvesting device to the cathode for freeing the system from diffusion limitation.

• Journal of Powder Materials
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• v.31 no.2
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• pp.163-168
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• 2024

As the demand for lithium-ion batteries for electric vehicles is increasing, it is important to recover valuable metals from waste lithium-ion batteries. In this study, the effects of gas flow rate and hydrogen partial pressure on hydrogen reduction of NCM-based lithium-ion battery cathode materials were investigated. As the gas flow rate and hydrogen partial pressure increased, the weight loss rate increased significantly from the beginning of the reaction due to the reduction of NiO and CoO by hydrogen. At 700 ℃ and hydrogen partial pressure above 0.5 atm, Ni and Li₂O were produced by hydrogen reduction. From the reduction product and Li recovery rate, the hydrogen reduction of NCM-based cathode materials was significantly affected by hydrogen partial pressure. The Li compounds recovered from the solution after water leaching of the reduction products were LiOH, LiOH·H₂O, and Li₂CO₃, with about 0.02 wt% Al as an impurity.