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http://dx.doi.org/10.5229/JECST.2014.5.2.37

Ionic Liquid-based Electrolytes for Li Metal/Air Batteries: A Review of Materials and the New 'LABOHR' Flow Cell Concept  

Bresser, Dominic (Institute of Physical Chemistry & MEET Battery Research Center, University of Muenster)
Paillard, Elie (Institute of Physical Chemistry & MEET Battery Research Center, University of Muenster)
Passerini, Stefano (Institute of Physical Chemistry & MEET Battery Research Center, University of Muenster)
Publication Information
Journal of Electrochemical Science and Technology / v.5, no.2, 2014 , pp. 37-44 More about this Journal
Abstract
The $Li-O_2$ battery has been attracting much attention recently, due to its very high theoretical capacity compared with Li-ion chemistries. Nevertheless, several studies within the last few years revealed that Li-ion derived electrolytes based on alkyl carbonate solvents, which have been commonly used in the last 27 years, are irreversibly consumed at the $O_2$ electrode. Accordingly, more stable electrolytes are required capable to operate with both the Li metal anode and the $O_2$ cathode. Thus, due to their favorable properties such as non volatility, chemical inertia, and favorable behavior toward the Li metal electrode, ionic liquid-based electrolytes have gathered increasing attention from the scientific community for its application in $Li-O_2$ batteries. However, the scale-up of Li-$O_2$ technology to real application requires solving the mass transport limitation, especially for supplying oxygen to the cathode. Hence, the 'LABOHR' project proposes the introduction of a flooded cathode configuration and the circulation of the electrolyte, which is then used as an oxygen carrier from an external $O_2$ harvesting device to the cathode for freeing the system from diffusion limitation.
Keywords
Li-air / $Li-O_2$ battery; electrolyte; ionic liquid; Li metal anode; flow cell;
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