• Transactions on Electrical and Electronic Materials
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• 제17권6호
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• pp.311-316
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• 2016

Batteries are critical components of electric vehicles and energy storage systems. The connection of a battery to the power grid for charge and discharge greatly affects energy storage. Therefore, an accurate and easy-to-observe battery model should be established to achieve systematic design, simulation, and SOC (state of charge) estimations. In this review, several equivalent circuit models of representative significance are explained, and their respective advantages and disadvantages are compared to determine and outline their reasonable applications to Li-ion batteries. Numerous commonly used model parameter identification principles are summarized as well, and basic model verification methods are briefly introduced for the convenient use of such models.

• 반도체디스플레이기술학회지
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• 제14권1호
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• pp.39-43
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• 2015

This paper is to derive information about the optimal shape of the pack has a minimum temperature range of a Li-ion battery equipped with a module. We selected the shape of the pack in order to reduce the temperature deviation between the batteries as a variable. And we derived the experimental points with a minimum of DOE by D-optimal. We analyzed the temperature and the flow within the battery pack by using a numerical analysis verified in previous studies. We derive the equation for the temperature variation in the objective function using the RSM and performed optimization. As a result, it was confirmed that with the variation in the $1.706e-4^{\circ}C$ when to apply an optimized shape.

• 한국세라믹학회지
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• 제46권6호
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• pp.587-591
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• 2009

Lithium salt have been used mainly as electrolyte of thermal battery for electricity storage. Recently, The 3phase lithium salt(LiCl-LiF-LiBr) is tried to use as electrolyte of thermal battery for high electric power. It is reported that LiCl-LiF-LiBr salt have high ion mobility due to its high lithium ion concentration. Solid lithium salt is melt to liquid state at above $500{^{\circ}C}$. The lithium ion is easily reacted with support materials. Because the melted lithium ion has small ion size and high ion mobility. For the increasing mechanical strength of electrolyte pellet, the research was started to apply ceramic filter to support of electrolyte. In this study, authors used SiOC web and glass fiber filter as ceramic mat for support of electrolyte and impregnated LiCl-LiF-LiBr salt into ceramic mat at above $500{^{\circ}C}$. The fabricated electrolyte using ceramic mat was washed with distilled water for removing lithium salt on ceramic mat. The washed ceramic mat was observed for lithium ion reaction behavior with XRD, SEM-EDS and so on.

• Journal of Electrical Engineering and Technology
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• 제13권3호
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• pp.1147-1155
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• 2018

This paper presents an improved method to determine the internal parameters for improving accuracy of a lithium ion battery equivalent circuit model. Conventional methods for the parameter estimation directly using the curve fitting results generate the phenomenon to be incorrect due to the influence of the internal capacitive impedance. To solve this phenomenon, simple correction procedure with transient state analysis is proposed and added to the parameter estimation method. Furthermore, conventional dynamic equation for correction is enhanced with advanced RC impedance dynamic equation so that the proposed modeling results describe the battery dynamic characteristics more exactly. The improved accuracy of the battery model by the proposed modeling method is verified by single cell experiments compared to the other type of models.

• 전력전자학회논문지
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• 제13권5호
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• pp.360-368
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• 2008

하이브리드 전기자동차용 리튬이온 배터리 시스템의 모델링 및 모델기반 상태 관측기 설계에 관한 연구를 수행하였다. 배터리의 동적 특성을 모사하기 위한 모델은 전기적 등가회로로 단순화하여 제안하였다. 모델 파라미터는 최소 자승 이론에 의거 다양한 운전조건에 따라 추정하였고, 실험 검증하였다. 검증된 모델을 기반으로 하는 비례-적분(PI) 제어의 상태 관측기를 구성하였고, 제어 이득 선정방법을 제안하였다. 제안된 상태 관측기의 강인성은 시뮬레이션 및 실험에 의거 다양한 운전조건 변동에 따른 민감도를 분석하여 검증하였다.

• 항공우주시스템공학회지
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• 제8권4호
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• pp.1-6
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• 2014

This paper presents the trade-off study of conducting a survey of the weights for various kind of propulsion systems installed in the Smart Unmanned Aerial Vehicle TR-100, a tilt-rotor vehicle, which is developed by Korea Aerospace Research Institute, in order to predict the appropriate propulsion system for present and future Personal Air Vehicle, which has single mode and vertical take-off & landing. In order to perform the trade-off study, we set the requirements that the vehicle hovers for 1 hour with 1,000 kg maximum take off weights. In this study, the power systems are classified engine, which uses the fossil fuel - turboshaft engine, piston engine, diesel engine and rotary engine, and electric motor with fuelcell or Li-Ion battery. The results of trade-off study shows the power systems using fossil fuel are superior to using fuelcell or Li-Ion battery for weight of propulsion system. Also turboshaft engine is the best power system for the aspects of system weight, and the nexts are rotary engine, piston engine, diesel engine, electric motor with Li-Ion battery, and electric motor with fuelcell.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집
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• pp.252-254
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• 2002

In this study, polyurethane acrylate macromer was synthesized and it was used in a gel polymer electrolyte, and then its electrochemical performances were evaluated. LiCoO$_2$/GPE/MCF cells were also prepared and their performances depending on discharge currents and temperatures were evaluated. ionic conductivity of the gel polymer electrolyte with PUA at room temperature and -20$^{\circ}C$ was ca. 4.5 x 10$\^$-3/ S/cm and 1.7${\times}$10$\^$-3/ S/cm, respectively. GPE was stable electrochemically up to 4.5 V vs. Li/Li$\^$+/. LiCoO$_2$/GPE/MCF cell showed a good high-rate and a low-temperature performance.

• Transactions on Electrical and Electronic Materials
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• 제18권3호
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• pp.136-140
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• 2017

The state of charge (SOC) is an important parameter in a battery-management system (BMS), and is very significant for accurately estimating the SOC of a battery. Li-ion batteries boast of excellent performance, and can only remain at their best working state by means of accurate SOC estimation that gives full play to their performances and raises their economic benefits. This paper summarizes some measures taken in SOC estimation, including the discharge experiment method, the ampere-hour integral method, the open circuit voltage method, the Kalman filter method, the neural network method, and electrochemical impedance spectroscopy (EIS. The principles of the various SOC estimation methods are introduced, and their advantages and disadvantages, as well as the working conditions adopted during these methods, are discussed and analyzed.

• 전기화학회지
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• 제2권2호
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• pp.88-92
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• 1999

리튬이온전지용 $LiCoO_2$ 전극의 도전재료인 흑연과 블랙에 대하여 도전재료 함량에 따른 복합체 전극의 겉보기 밀도, 전해액 중에서 집전체로부터 전극복합체의 자기박리 및 전자전도 저항 특성을 조사하였다. $LiCoO_2$복합전극의 겉보기 밀도는 도전재료의 함량 증가에 따라 감소하였으며, 복합체 중 $LiCoO_2$ 단독의 겉보기 밀도는 보다 큰 감소를 나타내었다. $4.7\%w/w$ 이상의 super s black 도전재료를 사용한 전극은 propylene carbonate와 diethyl carbonate의 1: 1 체적비 혼합용매 중의 1 mol/I $LiPF_6$ 전해액 함침으로 자기박리하였으며, 흑연 도전재료에서는 자기박리가 없었다 복합전극의 전자전도에 대한 비저항은 도전재료의 함량 증가에 따라 감소하였으며, super s black도전재료 $2\~3\%w/w$ 함량의 비저항은 Lonza KS6흑연 도전재료 $12\%w/w$ 함량의 비저항과 유사하였다. 본 연구에서 나타낸 범위 내에서 super s black도전재료를 사용할 때 전극 복합체 중의 $LiCoO_2$밀도가 높아 고용량을 나타내었다.

• 한국가시화정보학회지
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• 제21권2호
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• pp.34-45
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• 2023

When lithium-ion batteries operate out of the proper temperature range, their performance can be significantly degraded and safety issues such as thermal runaway can occur. Therefore, battery thermal management systems are widely researched to maintain the temperature of Li-ion battery cells within the proper temperature range during the charging and discharging process. This study investigates the cooling performance and isothermal maintenance of cooling materials by measuring the surface temperature of a battery cell with or without cooling materials, such as silicone oil, thermal adhesive, and phase change materials during discharge process of battery by the experimental and numerical analysis. As a result of the experiment, the battery pack filled with phase change material showed a temperature reduction of 47.4 ℃ compared to the case of natural convection. It proves the advanced utility of the cooling unit using phase change material that is suitable for use in battery thermal management systems.