• Title/Summary/Keyword: Li reduction

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Simplified Algorithm of the Novel Steel-concrete Mixed Structure under Lateral Load

  • Li, Liang;Li, Guo-qiang;Liu, Yu-shu
    • International Journal of High-Rise Buildings
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    • v.1 no.4
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    • pp.247-254
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    • 2012
  • In order to improve the seismic behaviors of traditional steel-concrete mixed structure, a novel steel concrete mixed structure consisting of steel frames braced with buckling restrained braces (BRBs) and a concrete tube is proposed. Based on several assumptions, the simplified mechanical model of the novel mixed structure is established, and the shear and bending stiffness formulas of the steel frames, BRBs and concrete tube are respectively introduced. The equilibrium differential equation of the novel mixed structure under horizontal load is developed based on the structural elastic theory. The simplified algorithms to determine the lateral displacement and internal forces of the novel mixed structure under the inverted-triangle distributed load, uniformly load and top-concentrated load are then obtained considering several boundary conditions and compatible deformation conditions. The effectiveness of the simplified algorithms is verified by FEM comparison.

Electrochemical Properties of Carbonized Phenol Resin (탄화된 페놀레진의 전기화학적 성질)

  • 김한주;박종은;홍지숙;류부형;박수길
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.629-632
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    • 1999
  • For replacing Li metal ai Lithium ton Bakery(LIB) system. we used carbon powder material which prepared by pyrolysis of phenol resin as starting material. It became amorphous carbon by pyrolysis through it\`s self condensation by thermal treatment. Amorphous carbon can be doped with Li intercalation and deintercalation because it has wide interlayer. however it has a problem with structural destroy causing weak carbon-carbon bond. So. we used ZnCl$_2$ as the pore-forming agent. This inorganic salt used together with the resin serves not only as the pore-forming agent to form open pores, which grow Into a three-dimensional network structure in the cured material, foul also as the microstructure-controlling agent to form a loose structure dope with bulky dopants. We analyzed SEM in order to find to different of structure. and can calculate distance of interlayer. CV test showed oxidation and reduction

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Dehydropolymerization of Bis(silyl)alkylbenzenes to Highly Cross-Linked Polysilanes, Catalyzed by Group 4 Metallocene Complex

  • 우희권;김숙연;김환기;연승호;조은정;정일남
    • Bulletin of the Korean Chemical Society
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    • v.16 no.11
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    • pp.1109-1112
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    • 1995
  • Bis(silyl)alkylbenzenes such as bis(1-sila-sec-butyl)benzene (1) and 2-phenyl-1,3-disilapropane (2) were prepared in high yields by reduction of the corresponding chlorosilanes with LiAlH4. The dehydropolymerization of 1 and 2 was carried out with group 4 metallocene complexes generated in situ from Cp2MCl2/Red-Al and Cp2MCl2/n-BuLi (M=Ti, Hf), producing two phases of polymers. The TGA residue yields of the insoluble polymers were in the range of 64-74%. The molecular weights of the soluble polymers produced ranged from 700 to 5000 (Mw vs polystyrene) and from 500 to 900 (Mn vs polystyrene). The dehydropolymerization of 1 and 2 seemed to initially produce a low-molecular-weight polymer, which then underwent an extensive cross-linking reaction of backbone Si-H bonds, leading to an insoluble polymer.

Low-Overhead Feedback Topology Design for the K-User MIMO Interference Alignment

  • Jin, Jin;Gao, Xiang-Chuan;Li, Xingwang;Cavalcante, Charles Casimiro;Li, Lihua
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.12 no.11
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    • pp.5304-5322
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    • 2018
  • Since designing a feedback topology is a practical way to implement interference alignment at reduced cost of channel state information (CSI) feedback, six feedback topologies have been presented in prior works for a K-user multiple-input multiple-output interference channel. To fully reveal the potential benefits of the feedback topology in terms of the saving of CSI overhead, we propose a new feedback topology in this paper. By efficiently performing dimensionality-decreasing at the transmitter side and aligning interference signals at a subset of receivers, we show that the proposed feedback topology obtains substantial reduction of feedback cost over the existing six feedback designs under the same antenna configuration.

Studies of the Passivation Film as a Function of the Concentration of Electrolyte in Lithium-ion Battery

  • Jeong, Gwang Il;Jeong, Myeong U;Kim, U Seong;Kim, Sin Guk;Seong, Yong Eun;Choe, Yong Guk
    • Bulletin of the Korean Chemical Society
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    • v.22 no.2
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    • pp.189-193
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    • 2001
  • The irreversible capacities caused by the reduction of solvent on the surface of a negative electrode (KMFC:Kawasaki Mesophase Fine Carbon) were examined during the initial cycle in ethylene carbonate (EC)-diethyl carbonate (DEC) electrolyte solut ions at various concentrations of LiPF6. Chronopotentiograms, linear sweep voltammograms, and impedance spectra clearly showed differences in irreversible capacity and that those differences are related to the concentration of electrolyte during the initial charge. These differences were caused by the amount of solvent decomposition as a function of the concentration of LiPF6 electrolytic salt. The data are discussed with reference to the concentration of electrolytic salt and the properties of passivation film formed by solvent decomposition.

Methyl Viologen Mediated Oxygen Reduction in Ethanol Solvent: the Electrocatalytic Reactivity of the Radical Cation

  • Lin, Qianqi;Li, Qian;Batchelor-McAuley, Christopher;Compton, Richard G.
    • Journal of Electrochemical Science and Technology
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    • v.4 no.2
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    • pp.71-80
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    • 2013
  • The study of methyl viologen ($MV^{2+}$) mediated oxygen reduction in electrolytic ethanol media possesses potential application in the electrochemical synthesis of hydrogen peroxide mainly due to the advantages of the much increased solubility of molecular oxygen ($O_2$) and high degree of reversibility of $MV^{2+/{\bullet}+}$ redox couple. The diffusion coefficients of both $MV^{2+}$ and $O_2$ were investigated via electrochemical techniques. For the first time, $MV^{2+}$ mediated $O_2$ reduction in electrolytic ethanol solution has been proved to be feasible on both boron-doped diamond and micro-carbon disc electrodes. The electrocatalytic response is demonstrated to be due to the radical cation, $MV^{{\bullet}+}$. The homogeneous electron transfer step is suggested to be the rate determining step with a rate constant of $(1{\pm}0.1){\times}10^5M^{-1}s^{-1}$. With the aid of a simulation program describing the EC' mechanism, by increasing the concentration ratio of $MV^{2+}$ to $O_2$ electrochemical catalysis can be switched from a partial to a 'total catalysis' regime.

Dynamic numerical analysis of single-support modular bridge expansion joints

  • Yuan, Xinzhe;Li, Ruiqi;Wang, Jian'guo;Yuan, Wancheng
    • Steel and Composite Structures
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    • v.22 no.1
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    • pp.1-12
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    • 2016
  • Severe fatigue and noise problems of modular bridge expansion joints (MBEJs) are often induced by vehicle loads. However, the dynamic characteristics of single-support MBEJs have yet to be further investigated. To better understand the vibration mechanism of single-support MBEJs under vehicle loads, a 3D finite element model of single-support MBEJ with five center beams is built. Successive vehicle loads are given out and the vertical dynamic responses of each center beams are analyzed under the successive loads. Dynamic amplification factors (DAFs) are also calculated along with increasing vehicle velocities from 20 km/h to 120 km/h with an interval 20 km/h. The research reveals the vibration mechanism of the single-support MBEJs considering coupled center beam resonance, which shows that dynamic responses of a given center beam will be influenced by the neighboring center beams due to their rebound after the vehicle wheels depart. Maximal DAF 1.5 appears at 120 km/h on the second center beam. The research results can be utilized for reference in the design, operation and maintenance of single-support MBEJs.

Cyclic load experiment study on the laminated composite RC walls with different concrete ages

  • Zhang, Hongmei;Lua, Xilin;Li, Jianbao;Liang, Lin
    • Structural Engineering and Mechanics
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    • v.36 no.6
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    • pp.745-758
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    • 2010
  • 12 typical laminated composite reinforced concrete (RC) walls with different concrete ages and 3 cast-in-place RC walls subjected to low frequency cyclic load were carried out in this study. The failure mode, force-deformation response and energy dissipation capacity of these specimens were investigated. Differences of structural behaviours between composite RC walls and common cast-in-place RC walls were emphasized in the analysis. The compatibility of the composite specimens with different concrete ages was discussed based on the experiment. Test results indicated that the differences between the lateral bearing capacity and the displacement ductility of the composite walls and the common walls were not so obvious. Some of the composite specimen even has higher bearing capacity under the experiment loading situation. Besides, the two parts of the laminated composite specimens demonstrates incompatibility at the later loading sequence on failure mode and strain response when it is in tension. Finally, this laminated composite shear walls are suggested to be applied in rapid reconstruction structures which is not very high.

ASSESSMENT OF ACTIVITY-BASED PYROPROCESS COSTS FOR AN ENGINEERING-SCALE FACILITY IN KOREA

  • KIM, SUNGKI;KO, WONIL;BANG, SUNGSIG
    • Nuclear Engineering and Technology
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    • v.47 no.7
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    • pp.849-858
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    • 2015
  • This study set the pyroprocess facility at an engineering scale as a cost object, and presented the cost consumed during the unit processes of the pyroprocess. For the cost calculation, the activity based costing (ABC) method was used instead of the engineering cost estimation method, which calculates the cost based on the conceptual design of the pyroprocess facility. The calculation results demonstrate that the pyroprocess facility's unit process cost is $194/kgHM for pretreatment, $298/kgHM for electrochemical reduction, $226/kgHM for electrorefining, and $299/kgHM for electrowinning. An analysis demonstrated that the share of each unit process cost among the total pyroprocess cost is as follows: 19% for pretreatment, 29% for electrochemical reduction, 22% for electrorefining, and 30% for electrowinning. The total unit cost of the pyroprocess was calculated at $1,017/kgHM. In the end, electrochemical reduction and the electrowinning process took up most of the cost, and the individual costs for these two processes was found to be similar. This is because significant raw material cost is required for the electrochemical reduction process, which uses platinum as an anode electrode. In addition, significant raw material costs are required, such as for $Li_3PO_4$, which is used a lot during the salt purification process.

An Analysis on Student Burden Double Reduction Policy in China - Based on Kingdon's Policy Stream Model (중국 의무교육단계 학생 부담경감 정책의 흐름 분석 - Kingdon의 정책흐름모형을 중심으로)

  • Xiaohui Li
    • Journal of the International Relations & Interdisciplinary Education
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    • v.4 no.1
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    • pp.35-56
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    • 2024
  • Based on Kingdon's policy stream model, the logical mechanism of student burden double reduction policy agenda setting process in China was analyzed from three aspects: problem stream, policy stream, political stream. It was found that the direct reflection of data, the feedback and improvement of current policies constitute the problem stream.The high attention of government departments, the suggestions of CPPCC members and experts and scholars, the strong voice of schools, and the continuous voice of stakeholders constitute the policy stream. The ruling party's governing idea and educational policy, national mood and interest game during the transition period constitute the political policy stream. The three streams, coupling interaction, open the policy window, promoting the introduction of the 'double reduction' policy.