• Title/Summary/Keyword: Li reduction

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Relationship between Ionic Conductivity and Composition of Li2O-ZrO2-SiO2 Glasses Determined from Mixture Design (혼합물계획법에 의한 Li2O-ZrO2-SiO2 유리의 이온전도도와 조성의 관계)

  • Kang, Eun-Tae;Kim, Myoung-Joong;Kim, Jae-Dong
    • Journal of the Korean Ceramic Society
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    • v.44 no.4 s.299
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    • pp.219-223
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    • 2007
  • The ionic conductivity of $Li_2O-ZrO_2-SiO_2$ glasses has been designed and analyzed on the basis of a mixture design experiment with constraints. Fitted models for the activation energy and the ionic conductivity are as follows: $Q(kJ/moi)=54.8565x_1+144.825x_2+133.846x_3-170.908x_1x_3-334.338x_2x_3$ $log{\sigma}(300K)=-5.00245x_1-1.17876x_2-15.5173x_3+17.4522x_1x_3$. The electrical properties are very sensitive to the ratio of $Li_2O/SiO_2$. The effect of $ZrO_2$ is less than that of this ratio but $ZrO_2$ component attributes to the reduction of the activation energy. The optimal composition for best ionic conduction based on these fitted models is $55Li_2O{\cdot}10ZrO_2{\cdot}35SiO_2$. Its activation energy and ionic conductivity at 300 K are 46.98 kJ/mol and $1.08{\times}10^{-5}{\Omega}^{-1}{\cdot}cm^{-1}$, respectively.

Charge/discharge Characteristics of Polypyrrole/SPE/Li Cell with Polypyrrole film Prepared by Electropolymerization Method as a Function of Temperature (전해중합법에 의한 Polypyrrole/SPE/Li Cell의 온도에 따른 충방전 특성)

  • Kim, J.U.;Yu, Y.H.;Cho, J.C.;Jeong, W.J.;Park, G.C.;Park, B.K.;Gu, H.B.;Moon, S.I.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1703-1706
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    • 1996
  • The purpose of this study is to research and develop polypyrrole(PPy) positive for thin film rechargeable lithium battery. We investigated cyclic voltammetry, AC impedance response and charge/discharge cycling of PPy/SPE/Li cells as a function of temperature. The redox capacity of $PPy/CF_{3}SO_{3}$ film was the most large. The discharge capacity of PPy/SPE/Li cell with $PPy/CF_{3}SO_{3}$ film was higher than those of $PPy/ClO_{4}$ and $PPy/AsF_6$ films at all cycles. The energy density of PPy/SPE/Li cells during 1st cycle was 73, 90 and 101Wh/kg at $25^{\circ}C$, $45^{\circ}C$ and $60^{\circ}C$, respectively. The improvement of energy density is due to reduction of charge-transfer resistance associated doping-undoping process in PPy film with Increasing temperature. $PPy/CF_{3}SO_{3}$ film shows a good property on charge/discharge cycling in PEO-$LiClO_4$-PC-EC electrolyte.

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Charge/discharge Properties of $V_{6}O_{13}$ Composite/Li Cell with Solid Polymer Electrolyte (고체 고분자 전해질을 사용한 $V_{6}O_{13}$ Composite/Li Cell의 충방전 특성)

  • Kim, J.U.;Yu, Y.H.;Jeong, I.S.;Park, B.K.;Gu, H.B.;Moon, S.I.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1414-1417
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    • 1996
  • The purpose of this study Is to research and develop $V_{6}O_{13}$ composite cathode for lithium thin film battery. $V_{6}O_{13}$ represents a class of cathode active material used in Li rechargeable batteries. In this study, we investigated cyclic voltammetry and charge/discharge characteristics of $V_6O_{13}$/SPE/Li cells. Cyclic voltammogram of $V_{6}O_{13}$/SPE/Li cell at scan rate 1mV/sec showed reduction peaks of 2.25V and 2.4V and oxidation peaks of 2.4V and 2.2V. The discharge curve of $V_{6}O_{13}$/SPE/Li cell showed 4 potential plateaus. The discharge capacity was decreased in the beginning of charge/discharge cycling. After 8th cycling, the discharge capacity was stable. The discharge capacity of 1st cycle and 15th cycle was 290mAh/g and 147mAh/g at $25^{\circ}C$, respectively.

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Effect of Ca Addtion on Microstructure and Mechanical Properties of Mg-11Li-3Zn-1Sn-0.4Mn Based Alloys (Mg-11Li-3Zn-1Sn-0.4Mn 마그네슘 합금의 Ca 첨가에 따른 미세조직 및 기계적 특성평가)

  • Kim, Jung-Han;Kim, Yong-Ho;Yoo, Hyo-Sang;Son, Hyeon-Taek;Lee, Seong-Hee
    • Korean Journal of Materials Research
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    • v.25 no.6
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    • pp.269-273
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    • 2015
  • The effect of adding Ca on the microstructural and mechanical properties of as-cast Mg-11Li-3Zn-1Sn(wt%) alloys were investigated. Mg-11Li-3Zn-1Sn-0.4Mn with different Ca additions (0.4, 0.8, 1.2 wt%) were cast under an $SF_6$ and $Co_2$ atmosphere at $720^{\circ}C$. The cast billets were homogenized at $400^{\circ}C$ for 12h and extruded at $200^{\circ}C$. The microstructural and mechanical properties were analyzed by OM, XRD, SEM, and tensile tests. The addition of Ca to the Mg-11Li-3Zn-1Sn-0.4Mn alloy resulted in the formation of $Ca_2Mg_6Zn_3$, MgSnCa intermetallic compound. By increasing Ca addition, the volume fraction and size of $Ca_2Mg_6Zn_3$ with needle shape were increased. This $Ca_2Mg_6Zn_3$ intermetallic compound was elongated to the extrusion direction and refined to fine particles due to severe deformation during hot extrusion. The elongation of the 0.8 wt% Ca containing alloy improved remarkably without reduction strength due to the formation of fine grain and $Ca_2Mg_6Zn_3$ intermetallic compounds by Ca addition. It is probable that fine and homogeneous $Ca_2Mg_6Zn_3$ intermetallic compounds played a significant role in the increase of mechanical properties.

Characterization and the Catalytic Properties of Alkali- Exchanged Y-Zeolites on NOx Conversion (알칼리 이온 교환 Y-제올라이트의 NOx 전환에 대한 촉매 특성 및 반응성)

  • Lee Chang-Seop;Lee Kyung Hee
    • Journal of the Korean Institute of Gas
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    • v.9 no.2 s.27
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    • pp.50-55
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    • 2005
  • The compositional and structural properties of alkali metal ion exchanged Y-zeolites have been investigated by la number of analytical techniques and their catalytic activities were tested for NOx reduction in combination with a non-thermal plasma. The NOx conversion data for LiY, NaY, KY and CsY were measured by chemiluminiscent NOx meter in the temperature range of 100 to $350^{\circ}C$. The initial activities of the catalyst at $150^{\circ}C$ increased in the order LiY < KY < NaY < CsY in alkali series. The activity of CsY and NaY were increased and showed maximum at $200^{\circ}C$ and then decreased in the plasma reactor, as the temperature increased. The activity of KY maintained same by $200^{\circ}C$ and then decreased, whereas the activity of LiY decreased with the increasing temperature. The CsY catalyst, which showed the highest activity in alkali metal series, exhibits a NOx conversion efficiency of $80\%$ between $170{\~}220^{\circ}C$.

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Salmonella vector induces protective immunity against Lawsonia and Salmonella in murine model using prokaryotic expression system

  • Sungwoo Park;Eunseok Cho;Amal Senevirathne;Hak-Jae Chung;Seungmin Ha;Chae-Hyun Kim;Seogjin Kang;John Hwa Lee
    • Journal of Veterinary Science
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    • v.25 no.1
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    • pp.4.1-4.14
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    • 2024
  • Background: Lawsonia intracellularis is the causative agent of proliferative enteropathy and is associated with several outbreaks, causing substantial economic loss to the porcine industry. Objectives: In this study, we focused on demonstrating the protective effect in the mouse model through the immunological bases of two vaccine strains against porcine proliferative enteritis. Methods: We used live-attenuated Salmonella Typhimurium (ST) secreting two selected immunogenic LI antigens (Lawsonia autotransporter A epitopes and flagellin [FliC]-peptidoglycan-associated lipoprotein-FliC) as the vaccine carrier. The constructs were cloned into a Salmonella expression vector (pJHL65) and transformed into the ST strain (JOL912). The expression of immunogenic proteins within Salmonella was evaluated via immunoblotting. Results: Immunizing BALB/c mice orally and subcutaneously induced high levels of LI-specific systemic immunoglobulin G and mucosal secretory immunoglobulin A. In immunized mice, there was significant upregulation of interferon-γ and interleukin-4 cytokine mRNA and an increase in the subpopulations of cluster of differentiation (CD) 4+ and CD 8+ T lymphocytes upon splenocytes re-stimulation with LI antigens. We observed significant protection in C57BL/6 mice against challenge with 106.9 times the median tissue culture infectious dose of LI or 2 × 109 colony-forming units of the virulent ST strain. Immunizing mice with either individual vaccine strains or co-mixture inhibited bacterial proliferation, with a marked reduction in the percentage of mice shedding Lawsonia in their feces. Conclusions: Salmonella-mediated LI gene delivery induces robust humoral and cellular immune reactions, leading to significant protection against LI and salmonellosis.

Correlation between Operation Result and Patient Satisfaction of Nasal Bone Fracture

  • Kang, Chang Min;Han, Dong Gil
    • Archives of Craniofacial Surgery
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    • v.18 no.1
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    • pp.25-29
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    • 2017
  • Background: Many authors have evaluated the post-reduction result of nasal bone fracture through patient satisfaction or postoperative complications. However, these results are limited because they are subjective. The aim of this study was to correlate an objective operation result with patient satisfaction and postoperative complications according to the type of nasal bone fractures. Methods: Our study included 313 patients who had isolated nasal bone fractures and had undergone a closed reduction. Postoperative outcomes were evaluated objectively using computed tomographic (CT) images, while patient satisfaction was evaluated one month after the operation. The correlation of the operation result with patient satisfaction was then evaluated. Results: The correlation between the operation result and patient satisfaction was highest for the lateral impact group type I (LI) type of fracture and lowest for the comminuted fracture group (C) type of fracture. However, there were no statistically significant differences in correlation between the overall result and patient satisfaction by fracture type. The complication rate of lateral impact group type II (LII), C, and frontal impact group type I (FI) fractures were statistically significantly higher than that of frontal impact group type II (FII) and LI fractures. There were no statistically significant relationships between the prevalence of complications and septal fracture or deviation according to the fracture type. In the total group, however, there was a statistically significant difference in complication rate by septal fracture. Conclusion: We found that the CT outcomes correlated with patient satisfaction. The complication rate of LII, C, and FI fractures were statistically significantly higher than that of FII and LI fractures. Septal fracture/deviation increased the postoperative complication in the total group.

Improvement of Structure and Electrochemical Properties of LiNi0.5Mn1.5O4 for High Voltage Class Cathode Material by Cr Substitution (Cr 치환을 이용한 고전압용 양극 활물질 LiNi0.5Mn1.5O4의 구조와 전기화학적 성능의 개선)

  • Eom, Won-Sob;Kim, Yool-Koo;Cho, Won-Il;Jang, Ho
    • Journal of the Korean Electrochemical Society
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    • v.8 no.2
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    • pp.82-87
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    • 2005
  • The cathode material, $LiNi_{0.5}Mn_{1.5}O_4$, for high voltage applications of Li-ion batteries exhibits impurity phases due to oxygen deficiency during the high temperature heat treatment. The impurity phase reduces the electrochemical properties of the electrode since the deficiency spinel structure disturbs the lithium ion intercalation and deintercalation. In this study, Cr-substituted $LiNi_{0.5-x}Mn_{1.5}Cr_xO_4(0{\leq}x{\leq}0.05)$ powders are synthesized by a sol-gel method in order to reduce the amount of the impurity phases in the $LiNi_{0.5-x}Mn_{1.5}Cr_xO_4$. Thermal analysis of the cathode material shows that the $LiNi_{0.5}Mn_{1.5}O_4$ without Cr substitution looses $2\%$ of its weight due to oxygen deficiency but the amount of weight loss is diminished when Cr is substituted. XRD analysis also supports the reduction of the impurity phases in the cathode after chromium substitution, suggesting that the improvement of the electrochemical properties such as the capacity retention and electrochemical stability are attributed to the low content of impurity phases in the Cr-substituted $LiNi_{0.5-x}Mn_{1.5}Cr_xO_4.$

On robustness in dimension determination in fused sliced inverse regression

  • Yoo, Jae Keun;Cho, Yoo Na
    • Communications for Statistical Applications and Methods
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    • v.25 no.5
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    • pp.513-521
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    • 2018
  • The goal of sufficient dimension reduction (SDR) is to replace original p-dimensional predictors with a lower-dimensional linearly transformed predictor. The sliced inverse regression (SIR) (Li, Journal of the American Statistical Association, 86, 316-342, 1991) is one of the most popular SDR methods because of its applicability and simple implementation in practice. However, SIR may yield different dimension reduction results for different numbers of slices and despite its popularity, is a clear deficit for SIR. To overcome this, a fused sliced inverse regression was recently proposed. The study shows that the dimension-reduced predictors is robust to the numbers of the slices, but it does not investigate how robust its dimension determination is. This paper suggests a permutation dimension determination for the fused sliced inverse regression that is compared with SIR to investigate the robustness to the numbers of slices in the dimension determination. Numerical studies confirm this and a real data example is presented.

Biaxial creep property of ethylene tetrafluoroethylene (ETFE) foil

  • Li, Yintang;Wu, Minger
    • Structural Engineering and Mechanics
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    • v.54 no.5
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    • pp.973-986
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    • 2015
  • Ethylene tetrafluoroethylene (ETFE) foil is a novel structural material which has being used in shell and spatial structures. This paper studies biaxial creep property of ETFE foil by creep tests and numerical simulation. Biaxial creep tests of cruciform specimens were performed using three stress ratios, 1:1, 2:1 and 1:2, which showed that creep coefficients in biaxial tension were much smaller than those in uniaxial one. Then, a reduction factor was introduced to take account of this biaxial effect, and relation between the reduction factor and stress ratio was established. Circular bubble creep test and triangle cushion creep test of ETFE foil were performed to verify the relation. Interpolation was adopted to consider creep stress and reduction factor was involved to take account of biaxial effect in numerical simulation. Simulation results of the bubble creep test embraced a good agreement with those measuring ones. In triangle cushion creep test, creep displacements from numerical simulation showed a good agreement with those from creep test at the center and lower foil measuring points.