• Title/Summary/Keyword: Li battery

Search Result 1,090, Processing Time 0.025 seconds

Electrical Power Subsystem Performance Evaluation of the GEO Satellite (정지궤도위성 전력계 성능 평가)

  • Koo, Ja Chun;Ra, Sung Woong
    • Journal of Korea Society of Industrial Information Systems
    • /
    • v.19 no.1
    • /
    • pp.31-41
    • /
    • 2014
  • The satellite on geostationary orbit accommodates multiple payloads into a single spacecraft platform and launched in June 26, 2010. The Electrical Power Subsystem provides a fully regulated power bus at $50V_{DC}$ in sunlight and eclipse conditions. The electrical power required to the satellite is generated by a solar array wing and the energy is stored by a Li-Ion battery with a capacity of 192.5Ah. This paper selects the main design parameters, compares and analyzes with the results at ground test and in orbit operation to apply this performance evaluation of the Electrical Power Subsystem to next satellite design on geostationary orbit. The Electrical Power Subsystem is demonstrated nominal behavior without significant degradation through the performance evaluation from design to in orbit operation.

Synthesis and Characterization of Quaternary Ammonium-based Ionic Liquids Containing an Alkyl Carbonate Group

  • Nguyen, Dinh Quan;Oh, Ji-Hee;Kim, Chang-Soo;Kim, Seung-Wook;Kim, Hong-Gon;Lee, Hyun-Joo;Kim, Hoon-Sik
    • Bulletin of the Korean Chemical Society
    • /
    • v.28 no.12
    • /
    • pp.2299-2302
    • /
    • 2007
  • A series of quaternary ammonium-based ionic liquids (ILs) containing an alkyl carbonate group on the cation was first prepared and their physical and electrochemical properties including density, viscosity, thermal stability, electrochemical stability, and ionic conductivity were reported. These ILs exhibited wide electrochemical windows of at least 5.0 V and relatively high conductivities. In contrast to dialkyl-substituted ionic liquids, the ILs with an alkyl carbonate group on the cation showed much smaller drop in conductivities when mixed with a lithium salt, due to the interaction of lithium ions with carbonate groups. Upon interaction with a Li salt, the carbonyl stretching frequency of the carbonate group shifted to a lower frequency whereas the peak associated with C-O single bond moved to a higher frequency.

A Study on WSN based Low Power Fire Prevention System (무선 센서 네트워크 기반 저전력 화재방재 시스템을 위한 전송 프로토콜 연구)

  • Kim, Young-Hyuk;Lim, Il-Kwon;Li, Qi Gui;Kim, Myung-Jin;Lee, Jae-Kwang
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
    • /
    • 2010.10a
    • /
    • pp.535-538
    • /
    • 2010
  • In this paper, this study goal is development for WSN-based fire prevention systems of using temperature/humidity Sensor. So, distributed sensor nodes structural and packet transfer characteristics study for fire monitoring. Battery-operated wireless sensor networks is data transfer manner of multi-hop. WSN fire prevention system need to sensor nodes management and energy consumption of efficient adjust for sustained action. Thus, study with efficient energy consumption the normal WSN environment is not, characteristics for WSN fire prevention environment.

  • PDF

Transmission Power Minimization with Network Coding for Mobile Terminals in Cellular Relay Networks

  • Du, Guanyao;Xiong, Ke;Li, Dandan;Qiu, Zhengding
    • KSII Transactions on Internet and Information Systems (TIIS)
    • /
    • v.6 no.9
    • /
    • pp.2098-2117
    • /
    • 2012
  • This paper jointly investigates the bandwidth allocation, transmission strategy and relay positions for two-way transmission aware cellular networks with network coding (NC). Our goal is to minimize the transmission power of mobile terminals (MTs). Consider a cellular system, where multiple MTs exchange information with their common base station, firstly, we propose an efficient bandwidth allocation method and then give a transmission strategy for each MT to determine whether to use relay stations (RSs) for its two-way transmission with the BS or not. To further improve the system performance, the optimal positions of RSs are also jointly discussed. A GA-based algorithm is presented to obtain the optimum positions for RSs. Besides, the impacts of frequency reuse on MT's transmission power and system spectral efficiency (SE) under different number of relays are also discussed in our work. Numerical results show that the proposed NC aware scheme can extend MTs' battery life at least 6% more than traditional method.

Lithium intercalation into a plasma-enhanced-chemical-vapour-deposited carbon film electrode

  • Pyun Su-II
    • Journal of the Korean Electrochemical Society
    • /
    • v.2 no.1
    • /
    • pp.38-45
    • /
    • 1999
  • Electrochemical lithium intercalation into a PECVD (plasma enhanced chemical vapour deposited) carbon film electrode was investigated in 1 M $LiPF_6-EC$ (ethylene carbonate) and DEC (diethyl carbonate) solution during lithium intercalation and deintercalation, by using cyclic voltammetry supplemented with ac-impedance spectroscopy. The size of the graphitic crystallite in the a- and c-axis directions obtained from the carbon film electrode was much smaller than those of the graphite one, indicating less-developed crystalline structure with hydrogen bonded to carbon, from the results of AES (Auger electron spectroscopy), powder XRD (X-ray diffraction) method, and FTIR(Fourier transform infra-red) spectroscopy. It was shown from the cyclic voltammograms and ac-impedance spectra of carbon film electrode that a threshold overpotential was needed to overcome an activation barrier to entrance of lithium into the carbon film electrode, such as the poor crystalline structure of the carbon film electrode showing disordered carbon and the presence of residual hydrogen in its structure. The experimental results were discussed in terms of the effect of host carbon structure on the lithium intercalation capability.

Electrochemical Properties of Lithium Sulfur Battery with Silicon Anodes Lithiated by Direct Contact Method

  • Kim, Hyung Sun;Jeong, Tae-Gyung;Kim, Yong-Tae
    • Journal of Electrochemical Science and Technology
    • /
    • v.7 no.3
    • /
    • pp.228-233
    • /
    • 2016
  • It is hard to employ the carbon materials or the lithium metal foil for the anode of lithium sulfur batteries because of the poor passivation in ether-based electrolytes and the formation of lithium dendrites, respectively. Herein, we investigated the electrochemical characteristics of lithium sulfur batteries with lithiated silicon anode in the liquid electrolytes based on ether solvents. The silicon anodes were lithiated by direct contact with lithium foil in a 1M lithium bis(trifluoromethane sulfonyl) imide (LiTFSI) solution in 1,2-dimethoxyethane (DME) and 1,3-dioxolane (DOL) at a volume ratio of 1:1. They were readily lithiated up to ~40% of their theoretical capacity with a 30 min contact time. In particular, the carbon mesh reported in our previous work was employed in order to maximize the performance by capturing the dissolved polysulfide in sulfur cathode. The reversible specific capacity of the lithiated silicon-sulfur batteries with carbon mesh was 1,129 mAh/g during the first cycle, and was maintained at 297 mAh/g even after 50 cycles at 0.2 C, without any problems of poor passivation or lithium dendrite formation.

The Effect of Synthetic Heat-treatment Temperatures on the Substitution Behavior of Lithium Ions in Potassium Tetratitanate (합성 열처리온도 변화가 Potassium Tetratitanate의 리튬 이온 치환거동에 미치는 영향)

  • 이재만;윤순길;이상훈;이재도
    • Journal of the Korean Ceramic Society
    • /
    • v.37 no.10
    • /
    • pp.955-961
    • /
    • 2000
  • 사티탄산칼륨을 리튬이온 전지의 양극재료로써 사용하고자 할 때 사티탄산칼륨의 합성 열처리 온도가 리튬이온 치환량에 미치는 영향에 대해 조사하였다. 사티탄산칼륨은 $K_2$O와 TiO$_2$의 몰 비를 1 : 3.91로 칭량하여 95$0^{\circ}C$, 100$0^{\circ}C$, 105$0^{\circ}C$에서 각각 합성하였다. 그 후, 사티탄산칼륨의 (Ti$_4$O$_{9}$ )$^{2-}$ 층간에 존재하는 $K^{+}$ 이온을 H$^{+}$ 이온으로 치환하고 이것을 다시 Li$^{+}$ 이온으로 치환하였다. 사티탄산칼륨의 합성 열처리 온도가 증가할수록 사티탄산칼륨의 (Ti$_4$O$_{9}$ )$^{2-}$ 층간의 거리가 감소했고 사티탄산칼륨의 길이가 증가했다. 95$0^{\circ}C$에서 열처리된 사티탄산칼륨의 리튬이온 치환량이 가장 많았다. 이는 상대적으로 낮은 합성 열처리 온도에서 사티탄산칼륨의 (Ti$_4$O$_{9}$ )$^{2-}$ 층간의 거리가 넓어져 리튬이온의 층간 이동이 쉬어졌고, 고온에서 열처리되어 길이가 긴 사티탄산칼륨에 비해 저온에서 열처리된 사티탄산칼륨은 길이가 짧아져 리튬이온이 (Ti$_4$O$_{9}$ )$^{2-}$ 층간으로 이동해 가는 거리가 짧아졌으며 아울러 짧은 사티탄산칼륨의 개수가 동일한 무게 당긴 사티탄산칼륨의 개수보다 많으므로 리튬이온의 치환량이 많아진다고 사료된다.

  • PDF

Properties and Application of Metal Sulfide Powder

  • Park, Dong-Kyu;Bae, Sung-Yeal;Ahn, In-Shup;Jung, Kwang-Chul
    • Proceedings of the Korean Powder Metallurgy Institute Conference
    • /
    • 2006.09b
    • /
    • pp.918-920
    • /
    • 2006
  • Metal sulfide powders such as MnS, $MoS_2$ and FeS are simply used to the machinery processing improvement agent and solid lubricant in powder metallurgy industrial. And then, metal sulfide powders have received relatively little attention from powder metallurgy. Recently, the portable machine is one of the important interfaces between human or human and electronic machine. With the increase of the intelligent activity, the social and industrial demands for information display device and power source are increasing. The transition metal sulfide materials (FeS, ZnS) have received considerable attention due to the large variety of its electric, optical and magnetic properties. Among the metal sulfide, $FeS_2$ is appealing superior material for applications in $Li-2^{nd}$ battery because of high capacity. ZnS is also a famous phosphor material with various luminescence properties, such as photoluminescence (PL) and electroluminescence (EL). So generally used in the fields of display, sensors and laser. Metal sulfide materials, therefore, are provided for most widely application in all industries. In recent years, material researchers have become increasingly interested in studying with synthesis of metal sulfide.

  • PDF

Cycling Performance and Surface Chemistry of Si-Cu Anode in Ionic Liquid Battery Electrolyte Diluted with Dimethyl Carbonate

  • Nguyen, Cao Cuong;Kim, Dong-Won;Song, Seung-Wan
    • Journal of Electrochemical Science and Technology
    • /
    • v.2 no.1
    • /
    • pp.8-13
    • /
    • 2011
  • Interfacial compatibility between the Si-Cu electrode and diluted ionic liquid electrolyte containing 50 vol.% of 1M lithium bis(trifluoromethanesulfonyl)imide (LiTFSI)/1-methyl-1-propylpyrrolidinium bis(trifluoromethylsulfonyl)imide (MPP-TFSI) and 50 vol.% dimethyl carbonate (DMC) in a lithium cell and dilution effect on surface chemistry are examined. ex-situ ATR FTIR analysis results reveal that the surface of the Si-Cu electrode cycled in the diluted ionic liquid electrolyte is effectively passivated with the SEI layer mainly composed of carboxylate salts-containing polymeric compounds produced by the decomposition of DMC. Surface species by the decomposition of TFSI anion and MPP cation are found to be relatively in a very low concentration level. Passivation of electrode surface with the SEI species contributes to protect from further interfacial reactions and to preserve the electrode structure over 200 cycles, delivering discharge capacity of > 1670 $mAhg^{-1}$ and capacity retention of 88% of maximum discharge capacity.

Effect of Carbon Matrix on Electrochemical Performance of Si/C Composites for Use in Anodes of Lithium Secondary Batteries

  • Lee, Eun Hee;Jeong, Bo Ock;Jeong, Seong Hun;Kim, Tae Jeong;Kim, Yong Shin;Jung, Yongju
    • Bulletin of the Korean Chemical Society
    • /
    • v.34 no.5
    • /
    • pp.1435-1440
    • /
    • 2013
  • To investigate the influence of the carbon matrix on the electrochemical performance of Si/C composites, four types of Si/C composites were prepared using graphite, petroleum coke, pitch and sucrose as carbon precursors. A ball mill was used to prepare Si/C blends from graphite and petroleum coke, whereas a dispersion technique was used to fabricate Si/C composites where Si was embedded in disordered carbon matrix derived from pitch or sucrose. The Si/pitch-based carbon composite showed superior Si utilization (96% in the first cycle) and excellent cycle retention (70% after 40 cycles), which was attributed to the effective encapsulation of Si and the buffering effect of the surrounding carbon matrix on the silicon particles.