• Title/Summary/Keyword: Li Diffusion

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Numerical investigation on gypsum and ettringite formation in cement pastes subjected to sulfate attack

  • Zuo, Xiao-Bao;Wang, Jia-Lin;Sun, Wei;Li, Hua;Yin, Guang-Ji
    • Computers and Concrete
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    • v.19 no.1
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    • pp.19-31
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    • 2017
  • This paper uses modelling and experiment to perform a quantitative analysis for the gypsum and ettringite formations in cement pastes subjected to sulfate attack. Firstly, based on Fick's law and chemical reaction kinetics, a diffusion model of sulfate ions in cement pastes is proposed, and then the model of the gypsum and ettringite formations is established to analyze its contents in cement pastes with corrosion time. Secondly, the corrosion experiment of the specimens with cement pastes immersed into 2.5%, 5.0% and 10.0% $Na_2SO_4$ solutions are carried out, and by using XRD-Rietveld method, the phases of powder samples from the specimens are quantitatively analyzed to obtain the contents of gypsum and ettringite in different surface depth, solution concentration and corrosion time. Finally, the contents of gypsum and ettringite calculated by the models are compared with the results from the XRD experiments, and then the effects of surface depth, corrosion time and solution concentration on the gypsum and ettringite formations in cement pastes are discussed.

Determination of Microbial Growth by Protein Assay in an Air-Cathode Single Chamber Microbial Fuel Cell

  • Li, Na;Kakarla, Ramesh;Moon, Jung Mi;Min, Booki
    • Journal of Microbiology and Biotechnology
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    • v.25 no.7
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    • pp.1114-1118
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    • 2015
  • Microbial fuel cells (MFCs) have gathered attention as a novel bioenergy technology to simultaneously treat wastewater with less sludge production than the conventional activated sludge system. In two different operations of the MFC and aerobic process, microbial growth was determined by the protein assay method and their biomass yields using real wastewater were compared. The biomass yield on the anode electrode of the MFC was 0.02 g-COD-cell/gCOD-substrate and the anolyte planktonic biomass was 0.14 g-COD-cell/g-COD-substrate. An MFC without anode electrode resulted in the biomass yield of 0.07 ± 0.03 g-COD-cell/g-CODsubstrate, suggesting that oxygen diffusion from the cathode possibly supported the microbial growth. In a comparative test, the biomass yield under aerobic environment was 0.46 ± 0.07 g-COD-cell/g-COD-substrate, which was about 3 times higher than the total biomass value in the MFC operation.

\Transport Phenomena of Alkali Metal Chlorides theough Poly(2-Hydroxyethyl Methacrylate) Hydrogel Membrane (Poly(2-Hydroxyethyl Methacrylate) 수화겔 막에 대한 알카리 금속 염화물의 수송현상)

  • Seong, Yong-Gil;Lee, Chun-Gi;Jeon, Mu-Sik
    • Journal of Biomedical Engineering Research
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    • v.8 no.2
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    • pp.123-134
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    • 1987
  • The transport phenomena of alkali metal chlorides through poly(2 hydroxyethyl methacrylate) hydrogel membrane have been studied using electrodialysis. The hydrogel membranes were prepared by the polymerization of 2-hydroxvethyl methacrylate in the presence of 45%(V/V) H2O and ethyleneglycodimethacrylate. The initiator used in the polymerization was azobismethylisobutyrate (AMIB) prepared from azobisiobtyronitrile (AIBN) using Mortimer method. The permeability of alkali metal chlorides such LiCl, NaCl and KCI at 50 voltage was obtained. The permeability of NaCl was also observed at 30, 40, 50, and 60 voltages respectively. The concentration of solutes permeated through the membrane was measurer by flame photometry. The experimental results have been discussed with the comparison of apparent solute molecular size, the self-diffusion coefficient of solutes, the transport number of cations in aqueous solution. These indic aloes that poly(2 hydroxyethyl methacrylate) hydrogel membrane shows a specific selectivity for sodium ion.

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Thermal Stability Improvement of Ni-Germanide Using Ni-N(1%) for Nano Scale Ge-MOSFET Technology (나노급 Ge-MOSFET를 위한 Ni-N(1%)을 이용한 Ni-germanide의 열 안정성 개선)

  • Yim, Kyeong-Yeon;Park, Kee-Young;Zhang, Ying-Ying;Li, Shi-Guang;Zhong, Zhun;Jung, Soon-Yen;Lee, Ga-Won;Wang, Jin-Suk;Lee, Hi-Deok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.17-18
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    • 2008
  • In this paper, 1%-nitrogen doped Nickel was used for improvement of thermal stability of Ni-Germanide. Proposed Ni-N(1%)/TiN structure has shown better thermal stability, sheet resistance and less agglomeration characteristic than pure Ni/TiN structure. During the germanidation process, it is believed that the nitrogen atoms in the deposited nickel layer can suppress the agglomeration of Ni germanide by retarding the diffusion of Ni atoms toward silicon layer, hence improve the thermal stability of Ni-germanide.

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Effects of Non-Absorbable Gases on the Absorption Process of Aqueous LiBr Solution Film in a Vertical Tube (II) (수직관내 리튬브로마이드 수용액막의 흡수과정에 대한 비흡수가스의 영향)

  • Kim, Byeong-Ju;Lee, Chan-U
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.4
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    • pp.499-509
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    • 1998
  • In the absorption process of water vapor in a liquid film, the composition of the gas phase, in which a non-absorbable gas is combined with the absorbate influences the transport characteristics remarkably. In the present study, the absorption processes of water vapor into aqueous solution of lithium bromide in the presence of non-absorbable gases were investigated analytically. The continuity, momentum, energy and diffusion equations for the solution film and gas phase were formulated in integral forms and solved numerically. It was found that the mass transfer resistance in gas phase increased with the concentration of non-absorbable gas. However the primary resistance to mass transfer was in the liquid phase. As the concentration of non-absorbable gas in the absorbate increased, the liquid-vapor interfacial temperature and concentration of absorbate in solution decreased, which resulted in the reduction of absorption rate. The reduction of mass transfer rate was found to be significant for the addition of a small amount of non-absorbable gas to the pure vapor, especially at the outlet of an absorber where non-absorbable gases accumulated. At higher non-absorbable gas concentration, the decrease of absorption flux was almost linear to the volumetric concentration of non-absorbable gas.

A study on effects of water-cement ratio and crack width on chloride ion transmission rate in concrete

  • Li, Yue;Chen, Xiaohan;Zhang, Guosheng
    • Computers and Concrete
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    • v.19 no.4
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    • pp.387-394
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    • 2017
  • To study the effects of water-cement ratio changes and cracks on chloride ion transmission rate in cracked concrete, RCM method was adopted to accelerate the diffusion of chloride ion in cracked concrete, and the changes in chloride ion concentration and around the cracks are inferred by finite-element method. The test results show that as far as prefabricated cracks on concrete components are concerned, the width thresholds of two cracks on the concrete specimens with a water-cement ratio of 0.5 and 0.6 are 0.05 mm and 0.1 mm respectively, the width threshold of two cracks on the concrete specimens with a water-cement ratio of 0.4 is 0.05 mm and 0.2 mm respectively; and the results of numerical simulation show that the smaller the water-cement ratio is, the more significant effects of cracks on chloride ion transmission rate are. As a result, more attention shall be paid to the crack prevention, repairing and strengthening for high-strength concrete.

Postbuckling and nonlinear vibration of composite laminated trapezoidal plates

  • Jiang, Guoqing;Li, Fengming;Zhang, Chuanzeng
    • Steel and Composite Structures
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    • v.26 no.1
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    • pp.17-29
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    • 2018
  • The thermal effects on the buckling, postbuckling and nonlinear vibration behaviors of composite laminated trapezoidal plates are studied. Aiming at the complex plate structure and to simulate the temperature distribution of the plate, a finite element method (FEM) is applied in this paper. In the temperature model, based on the thermal diffusion equation, the Galerkin's method is employed to establish the temperature equation of the composite laminated trapezoidal plate. The geometrical nonlinearity of the plate is considered by using the von Karman large deformation theory, and combining the thermal model and aeroelastic model, Hamilton's principle is employed to establish the thermoelastic equation of motion of the composite laminated trapezoidal plate. The thermal buckling and postbuckling of the composite laminated rectangular plate are analyzed to verify the validity and correctness of the present methodology by comparing with the results reported in the literature. Moreover, the effects of the temperature with the ply-angle on the thermal buckling and postbuckling of the composite laminated trapezoidal plates are studied, the thermal effects on the nonlinear vibration behaviors of the composite laminated trapezoidal plates are discussed, and the frequency-response curves are also presented for the different temperatures and ply angles.

How Facebook Functions in a Social Movement: An Examination Using the Web Mining Approach

  • Cao, Wenny;Cheong, Angus;Li, Zizi
    • Asian Journal for Public Opinion Research
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    • v.1 no.4
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    • pp.268-291
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    • 2014
  • Social media is becoming more and more important in social movements. This study, adopting the web mining approach, attempts to investigate how social media, Facebook in particular, functioned in the "May 25 Protest" and the "May 27 Protest", two movements which broke out in Macao on 25 and 27 May 2014, respectively, against the Retirement Package Bill. In the two protests, Macao residents deployed Facebook to share information and motivated people's participation. Twelve events (181,106 people invited) and 36 groups/pages (41,266 members) related on Facebook were examined. Results showed that the information flow on Facebook fluctuated in accordance with the event development in reality. Multiple patterns of manifestation, such as video of adopted news or songs, designed profile (protest icon), original ironic pictures, self-organized clubs by undergraduates and white T-shirts as a symbol, among others, appeared online and interacted with offline actions. It was also found that social media assisted the information diffusion and provided persuasive reasons for netizens to join the movement. Social media helped to expand movement influence in providing a platform for diversified performances for actions taken in a protest, which could express and develop core and consistent movement repertoire.

A New Way to Prepare MoO3/C as Anode of Lithium ion Battery for Enhancing the Electrochemical Performance at Room Temperature

  • Yu, Zhian;Jiang, Hongying;Gu, Dawei;Li, Jishu;Wang, Lei;Shen, Linjiang
    • Journal of Electrochemical Science and Technology
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    • v.7 no.2
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    • pp.170-178
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    • 2016
  • Composited molybdenum oxide and amorphous carbon (MoO3/C) as anode material for lithium ion batteries has been successfully synthesized by calcining polyaniline (PANI) doped with ammonium heptamolybdate tetrahydrate (AMo). The as prepared electrode material was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and field emission scanning electron microscopy (FE-SEM). The electrochemical performance of the anode was investigated by galvanostatic charge/discharge, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The MoO3/C shows higher specific capacity, better cyclic performance and rate performance than pristine MoO3 at room temperature. The electrochemical of MoO3/C properties at various temperatures were also investigated. At elevated temperature, MoO3/C exhibited higher specific capacity but suffered rapidly declines. While at low temperature, the electrochemical performance was mainly limited by the low kinetics of lithium ion diffusion and the high charge transfer resistance.

High Performance Wearable/Flexible Energy Storage Devices Based on Ultrathin $Ni(OH)_2$ Coated ZnO Nanowires

  • Shakir, Imran;Park, Jong-Jin;Kang, Dae-Joon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.597-597
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    • 2012
  • A simple solution-based method is developed to deposit crystalline ultrathin (2 nm) nickel hydroxide on vertically grown ZnO nanowires to achieve high specific capacitance and long-term life for flexible and wearable energy storage devices. Ultrathin crystalline $Ni(OH)_2$ enables fast and reversible redox reaction to improve the specific capacitance by utilizing maximum number of active sites for the redox reaction while vertically grown ZnO nanowires on wearable textile fiber effectively transport electrolytes and shorten the ion diffusion path. Under the highly flexible state $Ni(OH)_2$ coated ZnO nanowires electrode shows a high specific capacitance of 2150 F/g (based on pristine $Ni(OH)_2$ in 1 M LiOH aqueous solution with negligible decrease in specific capacitance after 1000 cycles. The synthesized energy-storage electrodes are easy-to-assemble which can provide unprecedented design ingenuity for a variety of wearable and flexible electronic devices.

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