• Proceedings of the KIEE Conference
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• 1993.11a
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• pp.264-267
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• 1993

A high plasma density of $10^{12}cm^{-3}$ can be produced at the pressure of few mTorr with R. F input power of 300-400W. A radially uniform plasma to a radius of 7cm at the substrate was produced at the pressure of 1 mTorr. The electron density and temperature were confirmed with double Langmuir probe, $\mu$-wave interferometer. It has bee found that the dispersion relation N/B=constant not be applied at the low R.F input power(<600W) but can be applied at high R.F input power(>600W).

• Journal of Advanced Marine Engineering and Technology
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• v.32 no.1
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• pp.175-183
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• 2008

In this paper, a new in-pipe inspection robot was developed for inspecting a large number of circular pipe insides of the sea plant, ships, and buildings. A new pressure generation system was devised to inspect circular pipes with different diameters and to move up and down slant or perpendicular slopes inside of the pipe. Also, a design method was analyzed to decide the capacity of driving motor for the robot if the mass and maximum velocity of the robot are identified. According to the design specification, a robot was developed and was tested to verify the performance of the pressure generation system. For tests, a control system was developed.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2006.10a
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• pp.407-408
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• 2006

• The Korean Journal of Nuclear Medicine
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• v.1 no.2
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• pp.35-39
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• 1967

Ferrokinetcs by Pollycove's method on 2 cases of Chronic myelogenous leukemia were presented in order to study the erythropoietic function and pathogenesis of anemia. The results are as follows. (1) The daily hemoglobin syntheses were slightly elevated. Both the mean effective hemoglobinization time and mean erythron life span were shortened. The maximum net ROC incorporations of $^{59}Fe$ weere decreased. The in vivo surface measurements of radioactivity over liver, spleen, and sacral bone marrow revealed findings consistant with hemolysis and extramedullary hematopoies. (2) Based upon those findings it is assumed that anemia in chronic myelogenous leukemia may result from hemolysis and inadequate compensation to the developing anemia.

• 한국해양학회지
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• v.16 no.1
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• pp.1-11
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• 1981

The seasonal variations of surface current patterns in the Japan Sea were drawn out from the results of drift bottle experiments, current measurements and hydrographic observations during 1979∼1980. The North Korean Cold Current(NKCC) and the East Korean Warm Current(EKWC) were common features of circulation in the eastern sea of Korea. The intrusion of NKCC along the Korean coast became strong in summer(average velocity of 47.4cm/sec off Jumunjin and 23.4cm/sec near Jugbyeon) when the Tsushima Current was strong. But there was no indication of the NKCC in November 1979. Dynamic topography(August & November 1979) and satellite picture(November 1979) seemed to show the topographic steering of EKWC beginning off Janggigab. Drift bottles arrived at the Japaness coast were affected significantly by the strong Tsushima Current in summer and by the predominant northwesterlies in winter instead of weak current.

• Journal of the Korean Chemical Society
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• v.16 no.4
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• pp.219-228
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• 1972

Geochemical investigation of river waters and reservoirs in Seoul city on fluorine contents were conducted between June in 1969 and February in 1970. Fluorine contents of most river waters and reservoirs in Seoul city were between 0.09 and 0.32 mg/l. It was found that fluorine contents of Han River and rivers running through the outskirt of the city were relatively less than those of the river waters running through the residential areas and the industrial areas. Fluorine contents were less seasonally variable than chlorine ones. Some implications of those results were discussed in detail.

• Bulletin of the Korean Chemical Society
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• v.32 no.12
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• pp.4403-4407
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• 2011

The nucleophilic substitution reactions of dipropyl chlorothiophosphate (3) with substituted anilines ($XC_6H_4NH_2$) and deuterated anilines ($XC_6H_4ND_2$) are investigated kinetically in acetonitrile at $55.0^{\circ}C$. The obtained deuterium kinetic isotope effects (DKIEs; $k_H/k_D$) are primary normal ($k_H/k_D$ = 1.11-1.35). A concerted mechanism involving predominant frontside nucleophilic attack is proposed on the basis of the primary normal DKIEs and selectivity parameters. Hydrogen bonded, four-center-type transition state is proposed. The steric effects of the two ligands on the anilinolysis rates of various substrates are discussed.

• Bulletin of the Korean Chemical Society
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• v.32 no.12
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• pp.4179-4184
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• 2011

The nucleophilic substitution reactions of bis(2,6-dimethylphenyl) chlorophosphate (5), containing the four ortho-methyl substituents, with X-pyridines are investigated kinetically in MeCN at $65.0^{\circ}C$. The free energy correlations for substituent X variations in the nucleophiles exhibit biphasic concave upwards with a breakpoint at a X = 3-Cl. Unusual positive ${\rho}_X$ (= +5.40) and negative ${\beta}_X$ (= -0.83) values are obtained with the weakly basic pyridines. The pyridinolysis rate of 5 is hundreds times slower compared to that of bis(phenyl) chlorophosphate because of the steric hindrance of the four ortho-methyl substituents in the two phenyl rings. Ion-pair mechanism is proposed and positive ${\rho}_X$ and negative ${\beta}_X$ values are substantiated by an imbalance of the transition state.

• Bulletin of the Korean Chemical Society
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• v.32 no.12
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• pp.4387-4391
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• 2011

The kinetic studies on the pyridinolysis of diisopropyl thiophosphinic chloride have been carried out in acetonitrile at $55.0^{\circ}C$. The free energy correlations for substituent X variations in the X-pyridines are biphasic concave upwards with a break point at X = 3-Ph. A concerted SN2 mechanism is proposed with a change of the attacking direction of the X-pyridine from a frontside attack for the strongly basic pyridines to a backside attack for the weakly basic pyridines. The factors to determine the rates and thio effects on the rates for the pyridinolyses of thiophophinic chloride, chlorothiophosphate, phosphinic chloride, phosphonochloridothioate, and chlorophosphate systems are briefly reviewed on the basis of the magnitude of the positive charge of the reaction center P atom and steric effects of the two ligands.

• Bulletin of the Korean Chemical Society
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• v.32 no.7
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• pp.2306-2310
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• 2011

The nucleophilic substitution reactions of diethyl thiophosphinic chloride with substituted anilines ($XC_6H_4NH_2$) and deuterated anilines ($XC_6H_4ND_2$) are investigated kinetically in acetonitrile at 55.0 $^{\circ}C$. The values of deuterium kinetic isotope effects (DKIEs; $k_H/k_D$) invariably increase from secondary inverse ($k_H/k_D$ < 1) to primary normal (kH/kD > 1) as the nucleophiles change from the strongly basic to weakly basic anilines. The secondary inverse with the strongly basic anilines and primary normal DKIEs with the weakly basic anilines are rationalized by the gradual transition state (TS) variation from a predominant backside attack, via invariably increasing the fraction of a frontside attack, to a predominant frontside attack, in which the reaction mechanism is a concerted $S_N2$ pathway. A frontside attack involving a hydrogen bonded, four-center-type TS is substantiated by the primary normal DKIEs.