• Title/Summary/Keyword: Leather

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Eco-friendly Leather Dyeing Using Biomass Wastes(III): Imparting Functionality by Combination Dyeing with Marigold (Tagetes erecta L.) and Hinoki Cypress(Chamaecyparis obtusa) Leave Extracts (생물자원 폐기물을 활용한 친환경 가죽염색(III): 매리골드와 편백나무 잎 추출물의 복합염색에 의한 기능성 부여)

  • Lee, Geonhee;Shin, Younsook
    • Textile Coloration and Finishing
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    • v.31 no.1
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    • pp.1-13
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    • 2019
  • In this study, eco-friendly functional leather was developed by recycling wastes such as eel skin, marigold(Tagetas erecta l.), hinoki cypress(Chamaecyparis obtusa). The hot water extracts of marigold and hinoki cypress leaves were freeze-dried at $-80^{\circ}C$ to prepare colorant powder. The dyeing of eel leather with marigold was carried out to investigate the effects of dyeing conditions, mordanting on dye uptake, color, morphological change, and color fastness. Considering shrinkage of eel leather caused by dyeing, the optimum dyeing conditions were $60^{\circ}C$ of dyeing temperature and 60 min of dyeing time at 1:100 of bath ratio, and color of the dyed eel leather was Y to YR Munsell series. In order to prevent the degradation of leather from microbe, we conducted combination dyeing with marigold and hinoki cypress leave colorants. In this case, the combination dyed eel leathers showed excellent antimicrobial activity with above 99% bacterial reduction rate against S. aurieus and K. pneumoniae. It was confirmed that all of the dyed eel leathers were sufficient to meet the Korean Standard for color fastness of leather products. It can be applied practically for the development of eco-friendly functional leather by utilizing some useful active components extracted from plant resources and by recycling food wastes.

Conservation Treatment and Structural Characteristics of a Leather Briefcase Used during the Korean War (6·25전쟁 당시 사용된 가죽가방의 보존처리와 구조적 특징)

  • Kang, Hyunsam;Jang, Hanul;Yi, Hyeonju;Gu, Jihye
    • Conservation Science in Museum
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    • v.27
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    • pp.57-66
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    • 2022
  • This study conducted conservation treatment of a briefcase used by a soldier who fought in the Korean War as a member of the United Nations Forces. The zooid characteristics of its main material, leather, were analyzed in collaboration with the researchers at the National Palace Museum of Korea who have conducted relevant research. A plan for conservation treatment was established based on the results of this analysis. The briefcase was made of leather with a wooden frame. The many densely arranged tiny pores in different patterns on the leather's surface suggests calf leather. The wooden frame and leather had suffered deformation over long years of deterioration and thus required conservation treatment to enhance their structural stability. The conservation treatment began with the removal of contaminants from the exterior and interior of the briefcase. The stiffened leather was softened through humidification, and torn or separated areas were restored using cowhide glue. It is expected that the results of this conservation treatment and analysis of the leather material will serve as useful sources for basic research on leather items as well as wartime and military items.

Effect of Organic Photosensitizers on the Antimicrobial Property of Polyurethane coated Leather

  • Oh, Kyung Wha;Lim, Ki Sub
    • Fashion & Textile Research Journal
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    • v.15 no.4
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    • pp.630-634
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    • 2013
  • Cow leather coated with polyurethane film that contains various organic photosensitizers was investigated to demonstrate the antimicrobial properties in the application of the material to protective clothing and home appliances. To prepare the antimicrobial coating on leather surfaces with high potency against microbes, photoactive agents, such as benzophenone (BP), 4,4'-bis(dimethylamino) benzophenone (MK), 4,4'-dihydroxybenzophenone (DHBP) and methylene blue (MB), were incorporated into polyurethane-based coating solutions. The photoactive antimicrobial agent treated leather samples were characterized by SEM, color appearance, color fastness against abrasion, and antimicrobial tests. The optical properties of organic photosensitizers indicated that active UV absorbance ranges were different: BP (around 250 nm), MK (around 360 nm), DHBP (around 305 nm) and MB (around 295 nm &570 nm-685 nm). The intensity of the UV absorbance curve at the UVA light wavelength for the antimicrobial test showed the highest value with MK; subsequently, this was followed by MB, DHBP and BP in decreasing order. The treated-leather samples demonstrated excellent antibacterial activity under UVA light. The antimicrobial effects for the Staphylococcus aureus were superior to Escherichia coli. Moreover, the polyurethane finishing showed an effective durability to abrasion. The overall results indicated that DHBP is the most suitable PU coating additive to provide antimicrobial properties to leather as well as color and surface appearance than MK, MB, and BP.

Natural dyeing of cow leather with cochineal (코치닐을 활용한 우피의 천연염색)

  • Kim, Sangyool
    • The Research Journal of the Costume Culture
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    • v.24 no.6
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    • pp.817-824
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    • 2016
  • The introduction of natural dyes into modern dye houses is very promising green chemistry concept that should be popularized more to reduce the dependency of leather dyeing on some toxic and non-biodegradable synthetic dyes. In this study, the properties of dyeing of cochineal on cow leather were evaluated. The proper dyeing conditions were identified with dye uptake (K/S values) depending on the colorant concentration, dyeing duration, dyeing temperature, and dye bath pH. For the proper mordanting conditions, color changes for different mordants were observed as $La^{*}b^{*}$ and H V/C values. Color fastness (light, rubbing, and dry cleaning) was also examined. Additionally, antibacterial properties and UV protection were examined. The results were as follows: The optimized dyeing conditions were 300% o.w.f., $40^{\circ}C$, 40 min., and pH 5. The cow leather color was red in the absence of mordanting, while it was red purple after being mordanted with Al and Cu, and purple mordanted with Fe. The K/S value of cow leathers increased in the order of the dyeing using $AlK(SO_4)_2$ > $CuSO_4$ > $FeSO_4$. The colorfastness to light and rubbing were reduced compared to original (untreated) cow leather. However dry cleaning fastness was very satisfactory, with a 4~5 rating. The dyed and pre-mordanting dyed cow leather showed excellent antibacterial properties.

A Study on the Property Changes by Trihydric Alcohol Addition Reaction and Polyurethane Dispersion Synthesis for Buffalo Leather Coatings (Buffalo Leather 코팅에 대한 수분산 폴리우레탄의 합성 및 3가 알콜 첨가에 의한 물성변화 연구)

  • Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.4
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    • pp.623-630
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    • 2015
  • Prepared polyurethane resin for buffalo leather coating on surface was synthesized with addition reaction glycerol which had different mole ratio. Mechanical properties of the synthesized polyurethane resin were measured by the SEM, FT-IR, UTM. Growing concerns in the evnironment-friendly polymer resin, we have synthesized low late obtained solvent water dispersion resin to be coating on buffalo leather. The increase of aliphatic trihydric alcohol glycerol mole %, abrasion resistance and tensile strength had demonstrated reduce properties. On the contrary, elongation and flexibility properties had highly increased. In the result of toluene solvent resistance, there was no effect of increased or decreased by the ratio of glycerol mole %.

Mechanical Properties and Synthesis of Polyurethane Dispersion by Glycerol for Vegetable Leather Surface Coatings (Vegetable Leather 표면코팅에 대한 Glycerol을 이용한 수분산 폴리우레탄의 합성 및 기계적 특성)

  • Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.100-107
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    • 2015
  • Prepared polyurethane resin for vegetable leather coating on surface was synthesized with glycerol which had different mole ratio. Mechanical properties of the synthesized polyurethane resin were measured by the SEM, FT-IR, UTM. Growing concerns in the evnironment-friendly polymer resin, we have synthesized low late obtained solvent water dispersion resin to be coating on vegetable leather. The increase of aliphatic trihydric alcohol glycerol mole %, abrasion resistance and tensile strength had highly stronger in intensity and longer durability. On the contrary, demonstrated reduce properties of elongation and flexibility. In the result of toluene solvent resistance, there was no effect of increased or decreased by the ratio of glycerol mole %.

A Study on the Preferences to the Functionality and the Level of the Discomfort to the Various Materials of the Footwear when Wearing (신발의 소재별 특성이 기능성 선호도와 착용시 불편 정도에 미치는 영향)

  • Choi, In-Ryu
    • Journal of the Korea Fashion and Costume Design Association
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    • v.17 no.2
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    • pp.239-249
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    • 2015
  • This study was focused on how the various materials of footwear affect the preferences of functionality and the level of discomfort when wearing. Datas were collected using questionnaire, age of 20's to 50's of female and male. Results were analysed using SPSS WIN 2.0 through t-test and ANOVA test. Results are as follows: In the preferences of materials of footwear, datas showed the shoes are of genuine leather, the sneakers are of textiles, the sandals are of man-made leather and the boots are of genuine leather. The important factor to the preferences of the materials were the leathers in the durability, the man-made leathers in easy-care and maintenance, the rubber and the complex materials in comforts. The level of the discomforts of the footwear were highly ranked in genuine leather, the man-made leather and the complex material with man-made leather and textiles followed. Man-made leather and the textiles represented the discomfort in the ankle. Mostly discomforts of the footwear showed in the sole and the top side of the foot in all kinds of footwear. The preferences in functionality were collected by the female, also female preferred the comfort the first, male preferred the durability. And the texture and the durability were highly preferred in aged female and male.

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Design Research of the Natural Leather using a Marbling Technique (I) (Marbling 기법을 응용한 천연가죽의 디자인 연구 (I))

  • Lee, Sang-Chul;Shin, Eun-Chul;Kim, Won-Ju;Park, Soo-Min
    • Textile Coloration and Finishing
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    • v.20 no.1
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    • pp.1-7
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    • 2008
  • The study has attempted to introduce a new coating than the conventional standardized method of spray, padding and roll coating. The study has focused on finding condition for separating water and organic layer in marble bath and surface effects according to kind of raw hide. It was found that dyestuff-free was to be used in water layer and the input amount of initial insoluble pigment to be added in marble bath should be adjusted following the change of surface area of the marble bath in order to get efficient marble effect while preventing coagulation of water and organic layers. Eventually, amorphous high value-added leather could be obtained treated in process other than the conventional standardized method. Even raw hides of low grades($C{\sim}E$ grades) could be processed into amorphous marble effect that could conceal or shield surface scratches by the colorant, which eventually eliminated necessity of using excessive amount of chemicals in the coating process leading to achieving high quality marble leather of natural look.

Research on Reproduction for Baekje Armor Display -Focus on the Lamellar Armors of the Baekje Hanseong Era- (백제 갑옷 전시를 위한 재현 제작에 관한 연구 -한성 시기 찰갑을 중심으로-)

  • Chae, Keum Seok;Kim, So-Hee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.41 no.2
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    • pp.281-295
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    • 2017
  • This research is about the reproduction of Baekje's armor-lamellar made for the Hanseong Baekje Museum exhibition. The purpose of the research are as follows. First, to categorize Baekje armor by type based on ancient documents and the excavated relics. Second, to reproduce categorized armor that provide a visual work for use in diverse areas. Baekje armor can be examined through the ancient records and several excavated relics. The results of the research are as follows. First, Baekje armor can be categorized into four types by material: 1) brass 2) iron 3) leather 4) bone. The can also be categorized into three types by finishing a) Hyeongnyubongnyun type (the leather skin interweaves with the lamellar armor method) b) Hyeokpobongnyun type (the method which wraps around the edges of leather skin) c) leather cloth added to clothe type. Second, we reproduced metal armor, iron armor and leather armor using brass, iron and leather (but not bone). Each type of armor were made life-size for exhibition purposes. We used Hyeongnyubongnyun method, Hyeokpobongnyung method and leather cloth; in addition, reproductions were made based on the Yangdang method that connected the front and the back from both sides of the shoulders so it can be open and close at the side part.

Types and Characteristics of the Clothes of Fur and Leather Worn by Chinese Minority Races in the Northeastern Regions of China and Inner Mongolia (동북.내몽골지역 중국소수민족이 착용한 모피와 피혁류 복식의 유형과 특성)

  • Ko, Soon-Hee;Jang, Hyun-Joo
    • Journal of the Korean Society of Costume
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    • v.60 no.4
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    • pp.58-75
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    • 2010
  • The purpose of this study is to investigate the characteristics of fur and leather clothes of minority races of China in Northeas and Inner Mongolia. To examine their characteristics, the clothes and ornaments were classified into four types: headwear, clothes, footwear, and accessories. First, headwear was divided into animal head-shaped, petal-shaped, round-shaped, and cone-shaped head wear. Among them, the animal head-shaped headwear was made by making the best use of the shape of animal's head and it was used as the best disguising method when hunting. Second, clothes were composed of upper garments and lower garments. For the upper garments, Po and Jeogori were worn and pants were worn for the lower garments. The clothes were decorated with lining, applique, or top-stitching on the outer collar, neck circumference, and the edge of sleeves and pants. Third, for the footwear, high boots of leather were developed to meet the needs for a convenient life in the plains. In some areas, fur shoes and leather shoes were also used. Finally, accessories included bags and gloves. Bags were usually decorated with fur on the outside or with a fringe or applique of tanned leather. Gloves were lavishly decorated with embroideries and partly with fur or leather.