• Korean Chemical Engineering Research
• /
• v.62 no.4
• /
• pp.364-370
• /
• 2024

In response to the threats of global warming and climate change, the development of highly energy-efficient lean methane oxidation processes has become crucial. One promising technology is ozone-induced lean methane oxidation (O₃-LMO), which utilizes ozone as an oxidant and a transition metal-loaded zeolite as a catalyst. Our previous study demonstrated that the O₃-LMO system, employing a cobalt-exchanged BEA (Co-BEA) catalyst, effectively abates lean methane (500 ppm) at low temperatures below 200℃ under dry conditions. In this study, we investigated the effect of water vapors on the performance of Co-BEA-based O₃-LMO system. The results indicated that CH₄ conversion, CO₂ selectivity, and O₃ utilization efficiency of the system were not significantly affected by water vapors. Additionally, any temporary suppression of activity could be easily reversed through simple vacuum drying of the catalyst. The system maintained robust activity for over 18 hours during prolonged testing under wet conditions.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.8 no.1
• /
• pp.92-100
• /
• 2000

The model gas reaction tests were carried out to investigate the purification characteristics of methane on the exclusive catalyst for NGV. The experiment was conducted with the factors which affect the conversion efficiency of methane, such as Redox ratio, coexistence components of CO, MO, $H_2$O, precious metals and additives. The catalyst loaded with larger amount of pd and with additive La showed lower light-off temperature. In the presence of CO and NO, the conversion efficiency of methane was varied according to the kind of additive loaded. The conversion efficiency of methane was dropped for the catalyst loaded with La under lean air-fuel ratio, while it increased for the one loaded with Ti+Zr for the same condition. It was shown that the water vapor inhibited methane from oxidation by its poisoning on the surface of catalyst.

• Journal of Advanced Marine Engineering and Technology
• /
• v.30 no.4
• /
• pp.455-462
• /
• 2006

Natural gas is a promising alternative fuel to meet strict engine emission regulations in many countries. Natural gas engines can operate at lean burn and stoichiometric burn conditions with different combustion and emission characteristics. In this paper, the fuel economy, emissions, misfire, knock and cycle-to-cycle variations in indicated mean effective pressure of lean burn natural gas engines are highlighted. Stoichiometric burn natural gas engines are briefly reviewed. To keep the output power and torque of natural gas engines comparable to that of gasoline engines, high boosting pressure should be used. High activity catalyst for methane oxidation and lean deNOx system or three way catalyst with precisely control strategies should be developed to meet stringent emission standards.

• 한국연소학회:학술대회논문집
• /
• 2006.04a
• /
• pp.149-156
• /
• 2006

Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

• Journal of the Korean Society of Combustion
• /
• v.11 no.1
• /
• pp.19-26
• /
• 2006

Structure of edge flame established in a mixing layer, formed between two uniformly flowing pure $CH_4$ and pure $O_2$ streams, is numerically investigated by employing a detailed methane-oxidation mechanism. The numerical results exhibited the most outstanding distinction of using pure oxygen in the fuel-rich premixed-flame front, through which the carbon-containing compound is found to leak mainly in the form of CO instead of HC compounds, contrary to the rich $CH_4-air$ premixed flames in which $CH_4$ as well as $C_2H_m$ leakage can occur. Moreover, while passing through the rich premixed flame, a major route for CO production, in addition to the direct $CH_4$ decomposition, is found to be $C_2H_m$ compound formation followed by their decomposition into CO. Beyond the rich premixed flame front, CO is further oxidized into $CO_2$ in a broad diffusion-flame-like reaction zone located around moderately fuel-rich side of the stoichiometric mixture by the OH radical from the fuel-lean premixed-flame front. Since the secondary CO production through $C_2H_m$ decomposition has a relatively strong reaction intensity, an additional heat-release branch appears and the resulting heat-release profile can no longer be seen as a tribrachial structure.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.19 no.12
• /
• pp.41-46
• /
• 2018

In this research, numerical analysis was performed to determine the effects of hydrogen on biogas combustion for homogeneous charged compression ignition (HCCI) engines. The target engine specifications were a 2300cc displacement volume, 13:1 compression ratio, 15kW of electricity, and 1.2 bar boost pressure. The engine speed was fixed to 1800rpm. By varying the excess air ratio and hydrogen contents, the cylinder pressure, nitric oxide, and carbon dioxide were measured as a function of the hydrogen contents. According to preliminary studies related to the reaction mechanism for methane combustion and oxidation, a GRI 3.0 mechanism as the base mechanism was selected for HCCI combustion calculations describing the detailed reaction mechanism. By adding hydrogen, NO was increased while $CO_2$ was decreased. The cylinder pressure was also increased, having advanced timing for the maximum cylinder pressure and pressure rise region. Furthermore, lean operation limits were extended by adding hydrogen to the HCCI engine.