• Title/Summary/Keyword: Lead ion

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Outside plant Facility Management using Geographic Information System (지리정보시스팀을 이용한 통신선로시설 관리)

  • 최지선
    • Spatial Information Research
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    • v.2 no.1
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    • pp.53-63
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    • 1994
  • Korea Telecom provides a wide range of communicat ion services and plays an important role in bring advanced technologies to the society. Increasing needs for utility management lead up to develop a Telephone Outside plant Management System(TOMS) which combines facility management with Geog¬raphic Information System (GIS). TOMS is a powerful, flexible and effective outside plant facility management system. TOMS provides value added applic¬at ion softwares and easy-to-use user interfaces which make TOMS eas i ly adapted and extended to the individual sites. TOMS is now in use in 30 percent of central offices and will be used nation-wide by 1996.

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Comparision of Test Methods for Estimating Chloride Ion Diffusion Coefficient in Concrete (콘크리트중의 염소이온 확산계수 추정 실험법의 비교)

  • 문한영;김홍삼;문재흠;한아름
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.787-790
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    • 1999
  • To estimate durability of reinforced concrete structures located in or nearby seawater, many different kinds of accelerated tests for evaluation of chloride ion permeation in concrete were proposed. At present the only standardized test is the ASTM C 1202(RCP test). This test method is used to estimate the concrete's resistivity of the chloride penetration in concrete by using the total charges passed and sometimes used to calculate the chloride diffusion coefficients. However, this test may lead to an erroneous chloride diffusion coefficient. So this test method was compared with the modified Dhir's test and the traditional concentration diffusion test. Experimental results showed that the diffusion coefficients determined the RCP test and the PD Index gave wrongous values, but the diffusion coefficient acquired by considering a migration term was nearly the same to the CD Test.

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Effects of Electron Beam Heating(EBH) on the Properties of ion Plated Ti(C, N) Films (이온도금된 Ti(C, N)피막의 물성에 대한 전자빔가열 효과)

  • 김치명;고경현;안재환;배종수;정형식
    • Journal of the Korean institute of surface engineering
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    • v.28 no.5
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    • pp.267-275
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    • 1995
  • Electron beam can provide convenient way to heat the substrate during Hollow Cathode Discharge (HCD) ion plating of Ti(C, N)films. Densification of columnar structrue is enhanced by longer duration of electron beam heating(EBH). While strong(111) texture is identified always to be formed, the amount of (200) oriented grains which coherently interfaced with carbide particles of the substrate increased with heating(EBH). In turns, these crystallogaphical change lead to the increase of micro hardness and adhesion of coating. Adhesion of Ti(C, N) films increased more dramatically in case of ASP30 substrate of which carbide particles dispersed more finely than M42. Therefore, it could be concluded that both the density of film and interfacial structure can affect the adhesion property. Overheating of substrate could be resulted in low adhesion resistance due to high residual stress developed in the film.

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Selective Response of Dye Rotaxane to Metal Ions (금속 이온에 대한 염료 로택산의 선택적 반응성)

  • Park, Jong-S.
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.35-35
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    • 2011
  • The design and preparation of novel dye rotaxanes have gained much interest recently, since such structure usually exhibits peculiar spectral and optical changes. In spite of the promising results to date, increasing pressure remains to develop novel supramolecular structures based on stimuli-responsive systems. This presentation covers the study of inclusion complexes of cyclodextrins and various chromophores, with an emphasis on our most recent outcome of anisotropic hydrogel. In this system, physical gelation prepared from simple mixture of CD and a azo dye is completed through specific host-guest interaction. The obtained hydrogel exhibits respective morphological transitions based on supramolecular assembly and dissociation, leading to either precipitation or a sol-to-gel transition. It can identify different classes of metal ions, and, among them, naked-eye differentiation of lead ion is possible due to the coordination-induced unthreading of dye molecules. Accompanying structural changes were verified by numerous characterization techniques, including 2D-ROESY, HR-MAS, UV-Visible absorption, small-angle X-ray scattering, and induced circular dichroism measurements. Such properties discussed here will find useful in analytical applications, such as metal ion sensing and removal applications.

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Factors that Influence Biofilm Formation in Vibrio parahaemolyticus (장염비브리오의 biofilm 형성에 영향을 미치는 인자)

  • No, A-Reum;Park, Kwon-Sam
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.42 no.5
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    • pp.456-460
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    • 2009
  • Biofilm is a structured community of microorganism encapsulated within a self-developed polymeric matrix and adherent to a living or a solid surface. In this study, we investigated the effects of various substrates on the formation of biofilm in Vibrio parahaemolyticus. We found that biofilm formation profoundly increased in a substrate, that consisted of calcium chloride, calcium nitrate, and calcium sulfate in 1% peptone water. On the other hand, a dramatic reduction in biofilm formation was observed in a substrate, that consisted of glucose and ferric chloride in LB broth. These results suggest that V. parahaemolyticus prefer to form a biofilm on the surface of a crustacean or a clam, where calcium ion is rich, and also where seawater temperature is relatively lower. In contrast, high levels of glucose in a crustacean or a clam body resulting from increased seawater temperature, can make V. parahaemolyticus detach from it and lead to free floating.

Recent Developments in High-performance Liquid Chromatography of Lipids

  • Christie, William W.
    • Journal of the Korean Applied Science and Technology
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    • v.10 no.1
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    • pp.1-8
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    • 1993
  • The possibilities for HPLC analysis of lipids have been revolutionised by the availability of evaporative light-scattering detectors, with which the response is independent of the nature of the mobile phase and does not depend On the presence of specific chromophores in the lipids. It was thus possible to develop an HPLC procedure, involving ternary gradient elution, for separating all the lipid classes in animal tissues in a single step. Although reversed-phase HPLC has been widely used for the analysis of molecular species of lipids, sliver ion chromatography can be a valuable alternative. For example, a stable silver ion column for HPLC was developed which permitted resolution of molecular species of triacylglycerols, even from such complex samples as fish oils, again With light-scattering detection and gradient elution. The capacity for HPLC resolution of diastereomeric diacyl-sn-glycerol derivatives, prepared from triacylglycerols. has lead to a new simple method for stereospecific analysis of the latter.

Stomatal Response by Ozone (오존에 대한 식물 기공 반응고찰)

  • 이준상;김병우
    • The Korean Journal of Ecology
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    • v.20 no.2
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    • pp.83-94
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    • 1997
  • Stomatal closing by ozone and water stress could reduce further ozone injury by inhibition of ozone influx to the tissue. Direct effect of ozone on stomata can be explained from two aspects which are a stimulation of stomatal closing and an inhibition of stomatal opening. An increase of $Ca^{2+}$ influx into cytoplasm by ozone could stimulate potassium efflux ion channel and inhibits inward potassium ion channels. By this mechanism ozone could induce stomatal closing. On the other hand, ozone could inhibit stomatal opening by affecting the activity of $H^{+}$ dependent ATPase of the membrane in guard cells. This would inhibit proton efflux which precede stomatal opening. It is also possible that ozone could reduce the activity of photosynthesis in guard cells which lead to affect the production of osmotically active sugars and energy. Indirect effect of ozone to stomata is through the effect of $CO_2$ elevation as a result of damage of the photozynthetic machinery. This indirect effect is slower than the direct effect.

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A Study on the Synthesis and Properties of (Ba,Pb)$TiO_3$Powder by Modified Oxalate Process (Modified Oxalate Process에 의한 (Ba,Pb)$TiO_3$ 분말합성 및 특성에 관한 연구)

  • ;;;Y, Torii
    • Journal of the Korean Ceramic Society
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    • v.33 no.7
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    • pp.743-754
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    • 1996
  • In this study (Ba1-xPbx)TiO3 was synthesized by modified oxalate process in order to prevent vaporization of PbO through low temperature synthesis climinate Cl ion reproducibly substitute Pb for by and uniformly distribute ion (Ba1-xPbx)TiO3 was synthesized by coprecipitation of lead acetate barium acetate and ammonium titanyl oxalate have been used as starting materials. The substitution of Pb for Ba was reproducibly possible synthetic temperature of perovskite structure becomes lowed as the Pb concentration increases and fine partic-les (specific surface are :7.2 cm2/g) were obtained, BaTiO3 powders calcined at 90$0^{\circ}C$ for 3 hours were cubic from in XRD analysis and as Pb content was increases evident split of tetragonal peaks could be observed The optimum conditions to synthesize (Ba,Pb)TiO3 powder are the followings ; synthesis temperature (5$^{\circ}C$)

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The Influence of Simple Electrolyte on the Behaviour of Some Acid Dyes in Aqueous Media

  • M. M. El-Fass;N. A. Badawy;A. A. El-Bayaa;N. S. Moursy
    • Bulletin of the Korean Chemical Society
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    • v.16 no.5
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    • pp.458-461
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    • 1995
  • The influence of adding counter-ion such as Na+ on the dimerization of the two sulphonated azo dyes, C.I. Acid Red 14 and C.I. Acid Red 17 in aqueous media has been studied spectrophotometrically. The observed hypochromic effect on increasing the amount of salt has been described. The dye concentration range where the dimerization equilibrium is applicable was chosen. No metachromatic behaviour was observed on changing the dye concentration and the amount of salt. This behaviour was attributed to the ability of the counter-ion to disrupt the structure of water as well as reducing the electrostatic repulsion forces between dye anions which will lead to the increase of aggregation tendency of the dye species.

Effects of free metal ions and organo-metal complexes on the absorption of lead and cadmium by plants (식물에 의한 납, 카드뮴 흡수 기작에 미치는 자유이온 및 유기산-중금속 복합체의 영향)

  • Lee, Mina;Seo, Byounghwan;Kim, Kwon-Rae
    • Journal of Applied Biological Chemistry
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    • v.64 no.2
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    • pp.159-164
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    • 2021
  • Heavy metals exist in soils in various chemical forms including free metal ions and organo-metal complexes. The ratio of free metal ions has been known to be highly associated with the plant absorption of heavy metals. This study aims to understand the effect of free ions and organo-metal complexes on the absorption of lead (Pb) and cadmium (Cd) by plants. For this, lettuce grown in a hydroponic system for 28 days was consequently grown another 48 hours using Pb and Cd solutions. The ratios of free ion to organo-metal complexes in the solutions were adjusted at 100:0, 90:10, 70:30, 60:40 by four different organic acids (citric, oxalic, acetic, and humic acid). After that, the concentration of Pb and Cd in lettuce were analyzed. The Pb and Cd absorption by lettuce was more relied on the types of organic acids treated and the type of metals rather than the ratio of free metal ions. For example, citric acid increased the Pb absorption while it decreased the Cd absorption by lettuce. There was no significant relationship between free metal ion ratios and both Pb and Cd uptake by lettuce. It could be explained that citric acid, a relatively higher molecular weight organic acid, has higher ion binding capacity, so it forms organo-Pb complex easily due to the higher affinity of Pb on the binding site in comparison with Cd. Consequently, this complexation would assist Pb uptake by lettuce.