• Resources Recycling
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• v.30 no.3
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• pp.63-69
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• 2021

Supply deficit of lead commodities and environmental pollution can be simultaneously resolved through the recovery and recycling of waste lead. The recent recovery of lead through recycling of the lead battery waste is a positive development. To maximize the effect of lead recovery and recycling in the future, the updated status of the lead material flow should be recognized. However, such an analysis at the preliminary stages may be cumbersome owing to the complexity and diversity of emission sources and material streams. At this stage, a preliminary screening by domestic lead flow using public information should be feasible. Therefore, in this study, using the data from the UN Comtrade and domestic PRTR (Pollutant Release and Transfer Register) databases, the amounts of lead import, emission, and transfer were identified and cross-checked with the domestic lead flow described in the National Material Flow Analysis database. The lead flow for major categories such as waste lead-acid batteries showed a rough consistency between the databases.

• Resources Recycling
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• v.28 no.4
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• pp.3-14
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• 2019

Lead is one of the common non-ferrous metals used in modern industry. The usage of lead continues to increase and has risen from 5 million tonnes per year worldwide in the 1970s to 11 million tonnes in the 2010s. In principle lead is virtually 100 % recyclable as an element without loss of quality. The recycling of lead scrap reduces the energy consumption and environmental burden, comparing to the primary metal production. Therefore production of secondary lead from scrap has been steadily growing and at present it meets approximately 60 % of usage worldwide. Lead scrap (mainly lead-acid battery) is smelted in primary and secondary smelter. Most secondary lead smelting were performed in a shaft-type furnace (blast furnace), rotary furnace and reverberatory furnace. The lead bullion is either cast into ingots and re-melted in refining kettles or refining is performed on the hot lead bullion immediately after production. This work provides an overview of the primary lead production and recycling process.

• Journal of the Korean Electrochemical Society
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• v.3 no.2
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• pp.90-95
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• 2000

Cycle life test was carried out to evaluate the failure modes of the gel type nth batteries at $C_5$ currents and $100\%$ DOD. When the batteries were charged at constant voltage of 2.40 V and 2.50 Vi respectively, cycle lift was over 1,000 cycles. The batteries lost 426.4 g and 391.2 g of electrolyte far each case after the weight measurement. The battery charged at 2.50 V was shown to have a better cyclic performance than charged at 2.40 V, and the amounts of electrolyte loss was proportional to charge factor. After cycle test, the micro-structure of positive active material was completely changed and the corrosion layer of positive grid was about $50{\mu}m$. Failure mode of the positive plate of the gel type battery was a shedding of the positive active material, and the cause of discharge capacity decrease was found to be a electrolyte loss.

• Journal of the Korean Electrochemical Society
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• v.11 no.1
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• pp.33-36
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• 2008

In the present study, impedance spectrometry has been used for predicting State-of-Charge (SoC) of gel type, Valve Regulated Lead Acid (VRLA), battery. The impedance measurements of VRLA battery (2V/1.2 Ah) at various SoC were made over the frequency range from 100kHz to 10mHz with an amplitude 10 mV. The impedance parameters have been evaluated by the analysis of the data using an equivalent circuit and a complex non-linear least squares (CNLS) fitting method. The charge transfer resistance values and double layer capacitance values of the positive electrode were higher than those of the negative electrode. The gel resistance values increased with decreasing in SoC. This indicates that the gel resistance is an important parameter for predicting SoC of VRLA battery.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.2255-2260
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• 2007

This Paper focuses on modeling and simulation to analyze the characteristic of hybrid vehicle. The system includes proton exchange membrane fuel cell(PEMFC), photovoltaic generator(PV), lead-acid battery, motor, vehicle and controller. Main electricity is produced by the PEMFC and battery to meet the requirements of a user load. When vehicle is parked in a sunny place, extra power is generated by the photovotaics and is charged in a battery for next drive. Further we evaluate usefulness of this hybrid vehicle by using ADVISOR - the advanced vehicle simulator written in the Matlab/Simulink environment. According to simulation results, the extra power obtained by photovoltaics which have been explored in nature conditions can help to reduce the electrical load of PEMFC and increase the efficiency (over 30%).

• Proceedings of the KIEE Conference
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• 1990.11a
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• pp.206-209
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• 1990

The battery energy storage system has been studied and adopted actively by foreign advanced utilities to use off-peak energy. Korea electro-technology research institute & KEPCO developed a small scale battery energy storage system. This system is composed of a voltage type self commutating inverter and 180 cells of 500 AH lead acid battery. Using the result of operation of the system, we make a conceptual design of MW class system.

• Journal of Electrical Engineering and Technology
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• v.13 no.6
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• pp.2254-2261
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• 2018

This paper analyzes stability of current control in respect of four cases of battery energy storage system (BESS) in a stand-alone microgrid. The stand-alone microgrid is composed of BESS, diesel generator and controllable loads, where all of them have a rated power of 50kW. The four cases are considered as following: 1) BESS with a stiff grid 2) BESS with the diesel generator 3) BESS with passive damping + diesel generator 4) BESS with active damping + diesel generator, and their stabilities are analyzed in the frequency domain and discrete time domain. The comparative analysis for four cases are verified through simulation and experiments through demonstration site of the stand-alone microgrid, where the DC link is connected to a 115kW battery bank composed of 48 lead-acid batteries (400AH/12V). Experimental results show a good agreement with the analysis.

• Proceedings of the KIEE Conference
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• 2001.10a
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• pp.331-333
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• 2001

The flooded type battery is used for solar lighting system. Because the characteristic of flooded type battery is the short life time, the maintenance cost is high. So the using floe fed type battery in this system is inappropriate. The valve regulated lead acid batter(VRLA) is the maintenance free and cycle service purpose. This paper presents the development of control system and monitoring system to applied VRLA battery for maintenance free and long life time in system.

• Journal of the Korean institute of surface engineering
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• v.40 no.5
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• pp.225-233
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• 2007

Effects of alloying elements on the corrosion layer formation of Pb-grid/active materials interface has been researched for improvement of corrosion resistance of Pb-Ca alloy. For this research, various amounts of alloying elements such as Sn, Ag and Ba were added to the Pb-Ca alloys and investigated their corrosion behaviors. Batteries fabricated by using these alloys as cathode grids were subjected to life cycle test. Overcharge life cycle test was carried out at $75^{\circ}C$, 4.5 A, for 110 hrs. with KS standard (KSC 8504). And then, after keeping the battery with open circuit state for 48 hr, discharge was carried out at 300A for 30 sec. Corrosion morphology and interface between Pb-grid and active materials were investigated by using ICP, SEM, WDX, and LPM. Corrosion layer of Pb-Ca alloy got thicken with increasing Ca content. For Pb-Ca-Sn alloy, thickness of corrosion layer decreased as Sn and Ag content increased gradually. In case of Pb-Ca-Sn-Ba alloy, thickness of corrosion layer decreased up to 0.02 wt% Ba addition, whereas, it was not changed in case of above 0.02 wt% Ba addition.

• Proceedings of the KIEE Conference
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• 1998.07b
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• pp.560-562
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• 1998

A new approach to developing battery SOC indicator for electric vehicle is discussed in this paper. One of the most difficult problems associated with the development of electric vehicle is the battery indicator which reliably informs the state of charge(SOC) of the battery to the driver. And the condition to be satisfied with SOC indicator installed on the electric vehicle is that it should be used under frequently variable load. A new method to determining SOC using neural networks(NN) is proposed to satify the condition. The training data of NN are obtained by using mathematical model of lead-acid battery, and calculating discharge currents and terminal voltages while battery discharges with constant current. The 3-layered NN with back propagation algorithm is used Simulation results show that the proposed method is appropriate as SOC indicator of the battery.