• Journal of the Korean Electrochemical Society
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• v.13 no.2
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• pp.128-131
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• 2010

Graphite sheet electro-deposited with lead was evaluated as a possible candidate for current collectors of lead acid batteries. Cyclic voltammetry was performed on the materials to evaluate the electrochemical properties. The graphite sheet electro-deposited with lead is electrochemically stable in the cathodic potential sweep. However, in the anodic potential sweep, the graphite sheet electro-deposited with lead is electrochemically unstable due to the oxygen evolution and the intercalation of sulfuric acid. Lead acid batteries were prepared by using a graphite sheet and a cast grid as current collectors for anode and performance test using those batteries was carried out. A lead acid battery with graphite sheets showed higher capacity and energy density than a conventional lead acid battery with cast grid.

• Applied Chemistry for Engineering
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• v.24 no.4
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• pp.344-349
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• 2013

Energy storage system is an energy reservoir which can store the electrical energy produced by the power plant into the chemical energy at the time whenever it needs to use. Accordingly, the energy storage system can help to improve the energy utilization efficiency and the stabilization of the power supply system. In addition, it can cope with the issues of carbon dioxide reduction and depletion of fossil fuel. Lead-acid battery in the secondary battery fields is one of the most developed technologies. It is also economical, reliable storage device. Therefore, the instantiation case of energy storage system using lead-acid battery was investigated for the reference studies.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.65 no.6
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• pp.962-968
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• 2016

The large scaled lead-acid battery is widely used for efficient operation of the photovoltaic system in many islands. However, lithium-ion battery is now being introduced to mitigate the fluctuation of wind power and to replace lead-acid battery. Therefore, hybrid ESS(Energy Storage system) that combines lithium-ion battery with lead-acid battery is being required because lithium-ion battery is costly in present stage. Under this circumstance, this paper presents the optimal algorithm to create composition rate of hybrid ESS by considering fixed and variable costs in order to maximize advantage of each battery. With minimization of total cost including fixed and variable costs, the optimal composition rate can be calculated based on the various scenarios such as load variation, life cycle and cost trend. From simulation results, it is confirmed that the proposed algorithms are an effective tool to produce a optimal composition rate.

• KEPCO Journal on Electric Power and Energy
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• v.2 no.1
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• pp.49-54
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• 2016

The large scaled lead-acid battery is widely used for efficient operation of the photovoltaic system in many islands. However, lithium-ion battery is now being introduced to mitigate the fluctuation of wind power and to replace lead-acid battery. Therefore, hybrid ESS (Energy Storage system) that combines lithium-ion battery with lead-acid battery is being required because lithium-ion battery is costly in present stage. Under this circumstance, this paper presents the optimal algorithm to create composition rate of hybrid ESS by considering fixed and variable costs in order to maximize advantage of each battery. With minimization of total cost including fixed and variable costs, the optimal composition rate can be calculated based on the various scenarios such as load variation, life cycle and cost trend. From simulation results, it is confirmed that the proposed algorithms are an effective tool to produce a optimal composition rate.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 1998.11a
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• pp.177-180
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• 1998

To manage lead-acid battery efficiently and to use it longer in UPS, the state of charge(SOC) indicator of the battery is needed. So a new approach to developing battery SOC indicator for UPS is discussed in this paper. This method to determining SOC by combining the available data of discharge characteristics of a battery with neural networks(NN) is presented. The 3-layered NN with back propagation algorithm has been used. Exprement results show that the proposed method is appropriate as SOC indicator of the battery.

• Proceedings of the KIEE Conference
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• 2009.07a
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• pp.945_946
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• 2009

This paper describes the development of the rapid battery charger for lead-acid battery. Due to heat which is caused by increased internal resistance during charging, it is difficult to increase charging current for the lead-acid battery. In this paper, the rapid charging algorithm which apply short discharging pulse current during charging procedure is developed and it makes the ion layer, which is generated during charging time, disappeared into electrolyte. The prototype battery charger based on resonant converter is developed for 48V battery charger and test procedure is introduced.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2004.10a
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• pp.128-133
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• 2004

This study has been focused on the development of shear forming process of grid for lead-acid battery. The grid plays an important role in the flow of electricity because the grid is a skeleton of the pasted plate. Therefore, it must be of the highest quality to prevent plate failures and then, battery failure, and ensure the best battery performance possible. The finite element analysis of the shear forming process is carried out and the result is compared with the experimental data. The influence of the numerical parameters such as clearance, velocity of punch and critical damage value on the simulation results turns out to be very considerable.

• The Transactions of the Korean Institute of Power Electronics
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• v.19 no.2
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• pp.139-148
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• 2014

State-of-charge (SOC) is one of the significant indicators to estimate the driving range of the electric vehicle and to control the alternator of the conventional engine vehicles as well. Therefore its precise estimation is crucial not only for utilizing the energy effectively but also preventing critical situations happening to the power train and lengthening the lifetime of the battery. However, lead-acid battery is time-variant, highly nonlinear, and the hysteresis phenomenon causes large errors in estimation SOC of the battery especially under the frequent discharge/charge. This paper proposes a novel estimation technique for the SOC of the Lead-Acid battery by using a well-known Extended Kalman Filter (EKF) and an electrical equivalent circuit model of the Lead-Acid battery considering diffusion and hysteresis characteristics. The diffusion is considered by the reconstruction of the open circuit voltage decay depending on the rest time and the hysteresis effect is modeled by calculating the normalized integration of the charge throughput during the partial cycle. The validity of the proposed algorithm is verified through the experiments.

• Korean Journal of Materials Research
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• v.32 no.3
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• pp.146-152
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• 2022

One disadvantage of deep cycle flooded lead-acid batteries is increasing water loss caused by use of (+) Pb-Sb / (-) Pb-Sb alloy grid. Water loss is generated by the emission of hydrogen gas from the (-) electrode during battery charging. In this paper, we maintain cycle life aspect through the development of hybrid flooded lead-acid batteries to which a (+) Pb-Sb / (-) Pb-Ca grid is applied and deal with the improvement of water loss. The amount of water loss compared to that of the (-) Pb-Sb grid decreased when Ca was added to the (-) Pb grid. For the (-) Pb-Ca grid, it was confirmed that the time to reach 0.0 V, at which water decomposition occurs, was increased compared to that of the (-) Pb-Sb grid at the NPV (Negative Potential Voltage). In the cycle life test conducted with the BCI (Battery Council International) standard, compared to the (+) Pb-Ca grid, the (+) Pb-Sb grid increased the life cycle of the batteries and the (+) Pb-Ca grid showed an early end of life due to PbO corrosion layer generation, as determined through SEM / EDS and Tear Down analysis. In conclusion, by addition of Sb to (+) Pb grid and Ca to (-) Pb grid, we developed a hybrid flooded lead-acid battery that meets user requirements to improve water loss characteristics and preserve cycle life characteristics.

• Corrosion Science and Technology
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• v.2 no.1
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• pp.1-6
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• 2003

A comprehensive coverage of corrosion in batteries is rendered difficult by the wide choice of materials, environments and physical features as obtained in practical settings. Understanding of the complex processes that occur in these electrochemical systems gets clearer as new theoretical approaches backed by sophisticated analytical and characterization techniques continue to provide valuable insights which aid in controlling/mitigating wasteful corrosion reactions which affect battery shelf-life, cycle life, rate capability and capacity. In the light of the above, I limit myself to a discussion on corrosion aspects in representative system such as conventional Leclanche, lead-acid battery and magnesium batteries, and advanced lithium systems.