• Title/Summary/Keyword: Lead Oxide

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Properties of PZI Thin film on the Ru/RuO2 Electrode (Ru/RuO2전극에 성장한 PZT 박막의 특성에 관한 연구)

  • Kang, Hyun-Il;Choi, Jang-Hyun;Park, Young;Song, Joon-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.10
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    • pp.865-869
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    • 2002
  • The structural and electrical properties of PZT (lead zirconate titante) thin films grown on Pt (platinum) and Ru/Ru $O_2$(ruthenium/ruthenium oxide) electrodes were investigated. Thin films of PZT were deposited on a variety of electrodes using the rf-magnetron sputtering process. PZT films exhibited polycrystalline structure with strong PZT (100) plane and weak (211) plane for an optimizied Pt electrode and (100), (101), (111), (200), (210), (211) planes for Ru/Ru $O_2$. Switching polarization versus fatigue characteristic of Pt/Ti electrodes showed 20% degradation up to 1 $\times$ 10$_{9}$ cycles. No significant fatigue was observed in the films on Ru/Ru $O_2$ electrodes up to Ix109 test cycles. The results show that the new Ru/Ru $O_2$ bottom electrodes are expected to reduce the degradation of ferroelectric fatigue.

Study on the Ag Thin Film Layer Deposition of the YBCO Coated Conductor Using a Plasma Surface Treatment (플라즈마 표면처리를 이용한 YBCO Coated Conductor의 Ag 박막층 증착에 관한 연구)

  • Jeong, Hyun-Gi;Yang, Sung-Chae;Choi, Byoung-Jung;Du, Ho-Ik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.1
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    • pp.32-36
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    • 2017
  • The Ag thin film of YBCO (yttrium barium copper oxide) CC (coated conductor) protect the YBCO layer and, at the same time, affects the electrical characteristics of the YBCO CC. Therefore, YBCO CC with the commercialization of the Ag thin film layers makes it easy to establish a process, it can lead to a variety of characteristic changes in YBCO CC. In this paper, plasma surface treatment was carried out to facilitate the deposition of the Ag thin film and the deposition process of YBCO CC. Surface roughness from the test results was increased as the time of the plasma surface treatment increased from 5 to 20 minutes. On the other hand, the surface roughness was decreased for the time of the plasma surface treatment over 20 minutes. Furthermore, after depositing, the increasing of deposit amount and reduced lifting phenomenon showed a similar tendency with the rise time of surface roughness.

Aging effect of annealed oxide CMP slurry (열처리된 산화막 CMP 슬러리의 노화 현상)

  • Lee, Woo-Sun;Shin, Jae-Wook;Choi, Kwon-Woo;Ko, Pil-Ju;Seo, Yong-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.335-338
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    • 2003
  • Chemical mechanical polishing (CMP) process has been widely used to planarize dielectric layers, which can be applied to the integrated circuits for sub-micron technology. Despite the increased use of CMP process, it is difficult to accomplish the global planarization of in the defect-free inter-layer dielectrics (ILD). Especially, defects such as micro-scratch lead to severe circuit failure which affect yield. CMP slurries can contain particles exceeding $1\;{\mu}m$ in size, which could cause micro-scratch on the wafer surface. In this paper, we have studied aging effect the of CMP sin as a function of particle size. We prepared and compared the self-developed silica slurry by adding of abrasives before and after annealing. As our preliminary experiment results, we could be obtained the relatively stable slurry characteristics comparable to original silica slurry in the slurry aging effect.

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Development of Inorganic Metal Oxide based Hole-Transporting Layer for High Efficiency Perovskite Solar Cell (고효율 페로브스카이트 태양전지용 무기 금속 산화물 기반 정공수송층의 개발)

  • Lee, Haram;Mai, Cuc Thi Kim;Jang, Yoon Hee;Lee, Doh-Kwon
    • Current Photovoltaic Research
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    • v.8 no.2
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    • pp.60-65
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    • 2020
  • In perovskite solar cells with planar heterojunction configuration, selection of proper charge-transporting layers is very important to achieve stable and efficient device. Here, we developed solution processible Cu doped NiOx (Cu:NiOx) thin film as a hole-transporting layer (HTL) in p-i-n structured methylammonium lead trihalide (MAPbI3) perovskite solar cell. The transmittance and thickness of NiOx HTL is optimized by control the spin-coating rate and Cu is additionally doped to improve the surface morphology of undoped NiOx thin film and hole-extraction properties. Consequently, a perovskite solar cell containing Cu:NiOx HTL with optimal doping ratio of Cu exhibits a power conversion efficiency of 14.6%.

Study of Nanoparticle Effect on Durability of Carbon fiber/Epoxy Resin Composites in Moisture Environment (수분환경에서 탄소섬유강화 에폭시수지의 내구성에 대한 나노입자의 영향)

  • Ahn, Seok-Hwan;Choi, Young-Min;Moon, Chang-Kwon
    • Journal of Power System Engineering
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    • v.18 no.2
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    • pp.43-49
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    • 2014
  • This study has been investigated on the durability of carbon fiber/epoxy composites (CFRP) in moisture environment. The carbon fiber/epoxy composites were modified to use the nanoparticles such as carbon nanotubes and titanium oxide. These hybrid composites were exposed to moisture environment for a certain period of time. Weight gain according to immersion time, quasi-static tensile test and micro-graphic characterization were investigated on the samples exposed to moisture environment. Consequently, the weight gains increased with increasing immersion time and weight gain of the hybrid composites was lower than the one of CFRP through the whole immersion time. The tensile strengths decreased with increasing immersion time and tensile strengths of the hybrid composites were higher than the one of CFRP through the whole immersion time. The CFRP were observed more degraded than hybrid compositess in moisture environment. Therefore, it was concluded that the addition of nanoparticles in CFRP could lead to improve the durability in moisture environment.

Workers' Possible Exposure Hazards in Solar Energy Industries (결정질 실리콘 기반 태양광산업에서의 근로자노출 가능 유해인자)

  • Jang, Jae-Kil;Park, Hyunhee
    • Journal of the Korean Solar Energy Society
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    • v.33 no.5
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    • pp.24-33
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    • 2013
  • Renewable energy industries, including sola cell plants, has been ever increasing ones for reducing fossil fuel consumption and strengthening national energy policy. In this paper we tried to identify occupational health hazards in solar cell-related industries operated in Korea. Poly silicon, silicon ingot and wafer, solar cell and module are major processes for producing solar cells. Poly silicon operations may cause hazards to workers from metal silicon, silanes, silicon, hydro fluoric acid and nitric acid. Solar cells could not be constructed without using metals such as aluminum and silver, acids such as hydrofluoric acid and nitric acid, bases such as sodium hydroxide and potassium hydroxide, and solvent and phosphorus chloride oxide. Workers in module assembly process may exposed to isopropanol, flux, solders that contain lead, tin and/or copper. To prevent occupational exposure to these hazards, it is essential to identify the hazards in each process and educate workers in industries with proper engineering and administrative control measures.

Development of gradient composite shielding material for shielding neutrons and gamma rays

  • Hu, Guang;Shi, Guang;Hu, Huasi;Yang, Quanzhan;Yu, Bo;Sun, Weiqiang
    • Nuclear Engineering and Technology
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    • v.52 no.10
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    • pp.2387-2393
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    • 2020
  • In this study, a gradient material for shielding neutrons and gamma rays was developed, which consists of epoxy resin, boron carbide (B4C), lead (Pb) and a little graphene oxide. It aims light weight and compact, which will be applied on the transportable nuclear reactor. The material is made up of sixteen layers, and the thickness and components of each layer were designed by genetic algorithm (GA) combined with Monte Carlo N Particle Transport (MCNP). In the experiment, the viscosities of the epoxy at different temperatures were tested, and the settlement regularity of Pb particles and B4C particles in the epoxy was simulated by matlab software. The material was manufactured at 25 ℃, the Pb C and O elements of which were also tested, and the result was compared with the outcome of the simulation. Finally, the material's shielding performance was simulated by MCNP and compared with the uniformity material's. The result shows that the shielding performance of gradient material is more effective than that of the uniformity material, and the difference is most noticeable when the materials are 30 cm thick.

Analysis of Deterioration Characteristics of Polyvinyl Chloride Insulation Wires for Electrical Apparatus by Series Arcing (전기기기용 비닐절연전선에서의 직렬 아크에 의한 열화 특성 분석)

  • Kim, Hyang-Kon;Gil, Hyung-Jun;Kim, Dong-Ook;Kim, Dong-Woo;Choi, Chung-Seog
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.234-235
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    • 2006
  • In this study, we experimented deterioration characteristics of PVC insulation wires for electrical apparatus by series arcing and analyzed the heat generation at the contacts of wires, glowing/growing process of copper oxide, waveforms of contact voltage, current, power dissipation, and so on. We found out that how glowing contacts and surface arcing can decompose PVC insulation and that subsequent series arc can lead to ignition. We expect that these results are useful for improving fire protection technology by providing a better understanding of how electrical fires can initiate.

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Preparation of Polymeric Self-Assembly and Its Application to Biomaterials

  • Cho, Chong-Su;Park, In-Kyu;Nah, Jae-Woon;Toshihiro Akaike
    • Macromolecular Research
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    • v.11 no.1
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    • pp.2-8
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    • 2003
  • The self-assembly of polymers can lead to supramolecular systems and is related to the their functions of material and life sciences. In this article, self-assembly of Langmuir-Blodgett (LB) films, polymer micelles, and polymeric nanoparticles, and their biomedical applications are described. LB surfaces with a well-ordered and layered structure adhered more cells including platelet, hepatocyte, and fibroblast than the cast surfaces with microphase-separated domains. Extensive morphologic changes were observed in LB surface-adhered cells compared to the cast films. Amphiphilic block copolymers, consisting of poly(${\gamma}$-benzyl L-glutamate) (PBLG) as the hydrophobic part and poly(ethylene oxide) (PEO) [or poly(N-isopropylacrylamide) (PNIPAAm)] as the hydrophilic one, can self-assemble in water to form nanoparticles presumed to be composed of the hydrophilic shell and hydrophobic core. The release characteristics of hydrophobic drugs from these polymeric nanoparticles were dependent on the drug loading contents and chain length of the hydrophobic part of the copolymers. Achiral hydrophobic merocyanine dyes (MDs) were self-assembled in copolymeric nanoparticles, which provided a chiral microenvironment as red-shifted aggregates, and the circular dichroism (CD) of MD was induced in the self-assembled copolymeric nanoparticles.

Water Extracts of Cultured Mountain Ginseng Stimulate Immune Cells and Inhibit Cancer Cell Proliferation

  • Oh, Chan-Ho;Kang, Pil-Sung;Kim, Jae-Whune;Kwon, Jin;Oh, Suk-Heung
    • Food Science and Biotechnology
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    • v.15 no.3
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    • pp.369-373
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    • 2006
  • Water extracts obtained from cultured mountain ginseng (CMG) were evaluated for their ability to stimulate immune cells and inhibit cancer cell proliferation. The lymphocyte subpopulation in mouse splenocytes in vivo was significantly increased by the administration of the CMG extract (27.4 mg/mouse). Interleukin-2 and ${\gamma}$-interferon in the mice serum increased up to 30% in CMG extract-treated mice. At a concentration of 1.37 mg/mL, nitric oxide increased up to 400% in the macrophage cell line treated with CMG extract. The CMG extract significantly retarded the proliferation of human acute promyelocytic (HL60), human histiocytic (U937), and mouse lymphocytic (L1210) leukemia cell lines in vitro at concentrations over 2.74-13.7 mg/mL. In addition, CMG extract treatments (1.37 mg/mL and 2.74 mg/mL) lead to the increased expression of the p53 gene and protein in cultured U937 leukemia cell lines. These results indicate that water extracts of CMG are capable of both immune cell stimulation and cancer cell growth inhibition.