• Title/Summary/Keyword: Leaching resistance

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Properties of artificial lightweight aggregates made from waste sludge

  • Chiou, I.J.;Chen, C.H.
    • Computers and Concrete
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    • v.8 no.6
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    • pp.617-629
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    • 2011
  • In this investigation, reservoir sediment and municipal sewage sludge were sintered to form the artificial lightweight aggregates. The sintered aggregates were compared with the commercialized lightweight aggregates to in terms of potential alkali-silica reactivity and chemical stability based on analyses of their physical and chemical properties, leaching of heavy metal, alkali-silica reactivity, crystal phase species and microstructure. Experimental results demonstrated that the degree of sintering of an aggregate affected the chemical resistance more strongly than did its chemical composition. According to ASTM C289-94, all potential alkali-silica reactivity of artificial lightweight aggregates were in the harmless zone, while the potential reactivity of artificial lightweight aggregates made from reservoir sediment and municipal sewage sludge were much lower than those of traditional lightweight aggregates.

Study of the Application of Gel Electrolyte in the Reference Electrode of $Cu/CuSO_4$

  • Lin, Cunguo;Xu, Likun;Liu, Yang
    • Corrosion Science and Technology
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    • v.7 no.3
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    • pp.179-181
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    • 2008
  • With nano-$SiO_2$ and sulphate acid, a kind of colloid electrolyte is synthesized by sol-gel method. It is placed outside the reference electrode as a layer of gel electrolyte so as to decrease the leaching of $Cu^{2+}$ and increase the life of the reference electrode. The performance of the gel electrode in simulating soil solution is measured as follows: the potential of the electrodes ranging from 60 mV to 80 mV (vs. SCE) with potential variation no more than $\pm10mV$, enough resistance to polarization. The $Cu^{2+}$ effusion rate of the reference electrode without gel electrolyte is 3 times that with colloid electrolyte, which means that gel electrolyte can extend the life of the reference electrode significantly.

A Study on Hardening Behavior of Colloidal Silica-Cement Grout (실리카졸-시멘트 그라우트의 고결특성에 대한 연구)

  • Kim, Young-Hun;Kim, Hae-Yang;Hyun, Ho-Gyu;Chun, Byung-Sik
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.529-534
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    • 2009
  • This study had propose that a characteristic of recently developed Silicasol to make a close in this study, grouting material usually used portland cement and a characteristic is compared between Silicasol and sodium silicate in this study, examined strength and environmentally friendly for compare characteristics of sodium silicate and Silicasol through unconfined compressive strength, SEM analysis, Permeability test, Chemical Resistance test, leaching test etc. In the test, I gained that unconfined compressive strength of Silicasol three times promoted than sodium silicate Within 72 hours and I gined through analysis of SEM that Silicasol is more compactivetive than sodium silicate. In the result of test, it was found to be a environmentally friendly material as the toatal amount of eluviated elementary had small quantity.

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A Study on the Development and Characteristics of Eco-friendly None Alkaline Silica Sol Grouting Material (친환경 비알칼리성 실리카졸 지반주입재의 개발과 특성에 관한 연구)

  • Hyunsang Kang;Daeseouk Chung
    • Journal of the Society of Disaster Information
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    • v.19 no.4
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    • pp.747-756
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    • 2023
  • Purpose: In this study, a grout material mixed using non-alkaline silica-based materials, which is an eco-friendly injection material to stabilize ground, is investigated to improve conventional problems. Method: The homogel specimens of Eco-Friendly Non-Alkaline Silica Sol (ENASS) and L.W. and S.G.R., representative silicate grouting are manufactured. Physicochemical and engineering properties of the specimens are evaluated in laboratory with uniaxial compression strength, hydraulic conductivity, shrinkage, chemical resistance, elution, fish poison, waste leaching. Result: Laboratory test results show that the ENASS was superior in all aspects compared to the existing injection matirial. The suitability of the grout material with ENASS is investigated with filed tests. Conclusion: The results of laboratory and field tests demonstrates that the grout material with ENASS is eco-friendly material that increases the strength, decreases the permeability, and discharges pollutants without leaching.

The Effect of Seawater on Hydration of Clinker Minerals (I) Effects of SO42- and Cl- ions (시멘트 클린커 광물의 수화에 미치는 해수성분의 영향 (I)SO42- 및 Cl-이온에 의한 영향)

  • 신도철;송태웅;한기성;최상흘
    • Journal of the Korean Ceramic Society
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    • v.24 no.1
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    • pp.77-85
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    • 1987
  • Hardened cement paste is mainly affected by corrosion of sulphate and chlorine ions in sea water. In this investigation, many specimens were made with the cement clinker minerals such as C3S, C3A, C4AF and their mixture according to cement composition added various blending materials. After the specimens were immersed in 4% MgSO4 and MgCl2 solutions, the product of reaction, the microstructure of specimen and Ca+2 ion leached in the solution were studied. The formation of Ca(OH)2 in the specimen of C3S is reduced relatively by adding pozzolanic admixtures. The chlorine ion is easily diffuse into the C3S specimen and produced CaCl2 compound, and it makes the specimen porous by leaching out itself into the solution. The specimen of C3A, C4AF are broken down by expanding reaction of ettringite and gypsum compound produced in the MgSO4 solution. At a later period, the ettringite is transformed into gypsum and 5MgO.2Al2O3·15H2O. The C3A in the MgCl2 solution combines chlorine ion to form Friedel's salt and prevents the diffusion reaction of chlorine ion into the specimen. Granulated slag shows inferior effect on the resistance of the specimen in MgSO4 solution by forming ettringite and gypsum, but good result in MgCl2 solution. Pozzolanic materials, on the whole, offer noticable effect on the resistance of the specimen in both solutions.

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Decay of Populus cathay Treated with Paraffin Wax Emulsion and Copper Azole Compound

  • Liu, Jie;Liu, Min;Hou, Bingyi;Ma, Erni
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.1
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    • pp.21-32
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    • 2019
  • In order to investigate the decay process of wood treated with preservative, waterproofing agent and their compound systems, a full-cell process was applied to impregnate the sapwood of poplar (Populus cathay) at paraffin wax emulsion concentrations of 0.5% and 2.0%, Copper Azole (CA) concentrations of 0.3% and 0.5%, and their four compound systems, respectively. Leaching tests and laboratory decay resistance against the white-rot fungus Corious versicolor (L.) Murrill for treated wood were carried out according to the America Standard E11-06 and China Standard GB/T 13942.1-2009. At certain time intervals during the decay test, samples were characterized by Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction technique (XRD) to investigate the time-dependent changes of chemical components and crystalline structure, thus clarifying the decay mechanisms. The results suggested that white-rot fungi degrade hemicellulose and lignin in the wood cell wall first, followed by a simultaneous degradation of polysaccharides and lignin. Besides, CA could not only slower the decomposition of both hemicellulose and lignin, but also reduce the degradation amount of hemicellulose. However, paraffin wax emulsion at high concentration had a negative effect on the impregnation of CA for the compound system treated wood.

Zinc Borosilicate Thick Films as a Ag-Protective Layer for Dye-Sensitized Solar Cells

  • Yeon, Deuk-Ho;Lee, Eun-Young;Kim, Kyung-Gon;Park, Nam-Gyu;Cho, Yong-Soo
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.313-316
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    • 2009
  • A zinc borosilicate glass having a low softening temperature of $490^{\circ}C$ has been investigated as a protective layer for Ag patterns against chemical reactions with a $I^-/I_3^-$ electrolyte in dye-sensitized solar cells (DSSCs). A thick glass layer was prepared by the typical screen printing and firing processes to obtain a final thickness of ${\sim}5{\mu}m$. The chemical leaching performance of the glass layer in the electrolyte revealed that the reactive Ag pattern can be significantly protected by utilizing the low softening protective layer. The electrical resistance of the FTO-coated glass substrate was effectively maintained at a low value of ${\sim}27{\Omega}$ as long as the glass layer was well densified at a sufficiently high temperature of ${\sim}520^{\circ}C$. The transmittance of the layer was near 60%, depending on the firing temperature of the glass layer.

Microwave dielectric properties of $La_2O_3-CaO-B_2O_3$ glass-added alumina ($La_2O_3-CaO-B_2O_3$계 유리 첨가 알루미나 복합체의 유전특성)

  • Lim, Dong-Ha;Kim, Hyun-Beom;Shin, Hyun-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.323-323
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    • 2007
  • Influence of $La_2O_3$ addition to $CaO-B_2O_3$-based glass on the water leaching resistance of the glass was first investigated. The optimized $La_2O_3-CaO-B_2O_3$(LCB) glass was ball milled for varying time, followed by mixing with $Al_2O_3$ crystalline phase to form $Al_2O_3$-LCB glass composites at $875^{\circ}C$ for 1h. Microwave dielectric properties of the composites were investigated as a function of the ball milling time of the LCB glass. Dielectric constant and quality factor of the composites were 6.31 and 13856 GHz, respectively, when the LCB glass was ball milled for 2h prior to mixing with $Al_2O_3$.

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Microwave dielectric properties of $La_2O_3-ZnO-B_2O_3$ glass-added alumina ($La_2O_3-ZnO-B_2O_3$계 유리 첨가 알루미나 복합체의 유전특성)

  • Hong, Seung-Hyuk;Jung, Eun-Hee;Shin, Hyun-Ho;Oh, Chang-Yong;Lim, Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.324-324
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    • 2007
  • Influence of $La_2O_3$ addition to $ZnO-B_2O_3$-based glass on the water leaching resistance of the glass was first investigated. The optimized $La_2O_3-ZnO-B_2O_3$ (LZB) glass was ball milled for varying time, followed by mixing with $Al_2O_3$ crystalline phase to form $Al_2O_3$-LZB glass composites at $875^{\circ}C$ for lh. Microwave dielectric properties of the composites were investigated as a function of the ball milling time of the LZB glass. Dielectric constant and quality factor of the composites were 6.01 and 11676 GHz, respectively, when the LZB glass was ball milled for 2h prior to mixing with $Al_2O_3$.

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Microwave dielectric properties of $Nd_2O_3-ZnO-B_2O_3$ glass-added alumina ($Nd_2O_3-ZnO-B_2O_3$계 유리 첨가 알루미나 복합체의 유전 특성)

  • Kim, Kyeong-Beom;Shin, Hyun-Ho;Yoon, Sang-Ok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.326-326
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    • 2007
  • Influence of $Nd_2O_3$ addition to $ZnO-B_2O_3$-based glass on the water leaching resistance of the glass was first investigated. The optimized $Nd_2O_3-ZnO-B_2O_3$ (NZB) glass was ball milled for varying time, mixing with followed by $Al_2O_3$ crystalline phase to form $Al_2O_3$-NZB glass composites at $875^{\circ}C$ for 1h. Microwave dielectric properties of the composites were investigated as a function of the ball milling time of the NZB glass. Dielectric constant and quality factor were 5.70 and 9497 GHz, respectively, when the NZB glass was ball milled for 6h prior to mixing with $Al_2O_3$.

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