• Journal of the Korean institute of surface engineering
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• v.54 no.1
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• pp.30-36
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• 2021

In this study, double-layered anodizing films were formed on Al 5052 and Al 6061 alloys consecutively first in sulfuric acid and then in oxalic acid, and hardness, withstand voltage, surface roughness and acid resistance of the anodizing films were compared with single-layered anodizing films in sulfuric acid and oxalic acid electrolytes. Hardness of the double-layered anodizing film decreased with increasing ratio of inner layer to outer layer for both Al 5052 and Al 6061 alloys, suggesting that outer anodizing film formed in sulfuric acid electrolyte is damaged during the second anodizing in oxalic acid electrolyte. Withstand voltage of the double-layered anodizing films increased with increasing the thickness ratio of inner layer to outer layer. Surface roughness of the double-layered anodizing films were comparable with that of single-layered anodizing film formed in sulfuric acid but higher than that of single layer anodizing film formed in oxalic acid electrolyte. In acid resistance test, all of the double-layered and single-layered anodizing films showed good acid resistance more than 3 h without any visible gas evolution, which is attributable to sealing of pores. Based on the experimental results obtained in this work, it is possible to design a double-layered anodizing film with cost-effectiveness and improved physical and electrical properties by combining two consecutive anodizing processes of sulfuric acid anodizing and oxalic acid anodizing methods.

• Transactions on Electrical and Electronic Materials
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• v.13 no.2
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• pp.85-88
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• 2012

Studies on the effects of layered silicate content on the AC electrical treeing and breakdown behaviors of epoxy/layered silicate nanocomposites were carried out in needle-plate electrode geometry. Wide-angle X-ray diffraction (WAXD) analysis and transmission electron microscopy (TEM) observation showed that 1 wt% of the multilayered silicate was fully exfoliated into nano-sized monolayers in the epoxy matrix however, over 3 wt% of the silicate was in an intercalated state. When 1 wt% layered silicates were incorporated, an electrical tree was initiated in 439 min and propagated at a speed of 2.3 ${\mu}m$/min after applying 781.4 kV/mm, representing a decreased in starting initiation time by a factor of 11.0 and increase in propagation speed by a factor 8.2 in comparison with neat epoxy resin. These values were in great decline after the layered silicate content was increased to 3wt% which implies that the exfoliated silicate blocked the tree initiation and propagation processes effectively. However the effect was largely decreased in the intercalated state.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.04a
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• pp.195-198
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• 2005

The role of elastic/plastic mismatch on the contact crack initiation is investigated for designing desirable surface-coated asymmetric layered composites. Various layered composites such as $Si_3N_4$ ceramics on $Si_3N_4+BN$ composite, soda-lime glass on various substrates with different elastic modulus for the analysis. Spherical indentation is conducted for producing contact cracks from the surface or interface between the coating and the substrate layer. A finite element analysis of the stress fields in the loaded layer composites enables a direct correlation between the damage patterns and the stress distributions. Implications of these conclusions concerning the design of asymmetric layered composites indicate that the elastic modulus mismatch is one of the important parameter for designing layered composite to prevent the initiation of contact cracks.

• Structural Engineering and Mechanics
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• v.5 no.5
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• pp.645-662
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• 1997

A nonlinear semi-three-dimensional layered finite element procedure is developed for cracking and failure analysis of reinforced concrete beams and the spandrel beam-column-slab connections of flat plates. The layered element approach takes the elasto-plastic failure behaviour and geometric nonlinearity into consideration. A strain-hardening plasticity concrete model and a smeared steel model are incorporated into the layered element formulation. Further, shear failure, transverse reinforcement, spandrel beams and columns are successfully modelled. The proposed method incorporating the nonlinear constitutive models for concrete and steel is implemented in a finite element program. Test specimens including a series of reinforced concrete beams and beam-column-slab connections of flat plates are analysed. Results confirm the effectiveness and accuracy of the layered procedure in predicting both flexural and shear cracking up to failure.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.11a
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• pp.137-140
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• 2005

Exfoliated nanocomposites of polypropylene/layered silicate were prepared by a melt compounding process using maleic anhydride modified polypropylene (PP-g-MAH) and organoclay. It was found that polypropylene/layered silicate nanocomposites exhibited remarkable reinforcement compared with the pure polypropylene or conventional composite filled with agglomerated organoclay. The polypropylene /layered silicate nanocomposites showed stronger and earlier shear thinning behaviors and outstanding strain hardening behavior than pure polypropylene or other conventional composites in shear and uniaxial elongational flows, respectively. We simulated rheological modeling for the pure polymer matrix and polypropylene/layered silicate nanocomposite in shear and elongational flows using K-BKZ integral constitutive equation. The two types of K-BKZequations have been examined to describe experimental results of shear and uniaxial elongational viscosities of pure polypropylene and polypropylene/layered silicate nanocomposite.

• Korea-Australia Rheology Journal
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• v.18 no.4
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• pp.217-224
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• 2006

Rapid flow advancement without void formation is essential in the liquid composite molding (LCM) such as resin transfer molding (RTM) and vacuum assisted resin transfer molding (VARTM). A highly permeable layer in multi-layered preform has an important role in improvement of the flow advancement. In this study, a multi-layered preform which consists of three layers is employed. Radial flow experiment is carried out for the multi-layered preform. A new analytic model for advancement of flow front is proposed and effective permeability is defined. The effective permeability for the multi-layered preform is obtained analytically and compared with experimental results. Compaction test is performed to determine the exact fiber volume traction of each layer in the multi-layered preform. Transverse permeability employed in modeling is measured experimentally unlike the previous studies. Accurate prediction of flow advancement is of great use for saving the processing time and enhancing product properties of the final part.

• Journal of the Korean Society of Safety
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• v.21 no.1 s.73
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• pp.79-85
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• 2006

Olefinic compatibilized blend(R-PP/R-PE)/layered silicate composites have been prepared by melt intercalation technique directed from $Na^{+}$ montmorillonite(MMT) or organophilic montmorillonites while using magnesium hydroxide as flame retardant. Morphology and flammability properties were characterized by X-ray diffraction(XRD), transmission electron microscopy(TEM), scanning electron microscopy(SEM), thermogravimetry analysis(TGA), limiting oxygen index(LOI), UL94 test. It is found that the compatibilized blend/layered silicate(Cloisite 20A) nanocomposites have a mixed immiscible-intercalated structure and there is better intercalation when a compatibilizer is combined with the polymer and layered silicate to be melt blended. A very large increase in the LOI value was observed with hybrid filler addition and further enhancement in thermal stability and compatibility of blend was obtained for the compatibilized blend containing small amount of layered silicate.

• Korean Journal of Human Ecology
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• v.7 no.2
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• pp.113-119
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• 1998

The purpose of this study was to investigate the effect of geometrical structure on the heat transfer of insulating nonwovens. Commercially available single and double layered polyester nonwovens have used. Thermal conductivity, k and thermal conductance, h were measured by using a constant temperature sandwich type device at dry and wet state. The results obtained were as follows: 1. Double layered nonwovens showed slightly lower thermal conductance and higher warmability than single layered nonwovens. 2. As moisture regain increased, double layered nonwovens showed higher increasing rate of thermal conductivity than single layered nonwovens.

• Transactions on Electrical and Electronic Materials
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• v.13 no.3
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• pp.149-152
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• 2012

The effects of amino silane coupling agent on the AC electrical treeing and breakdown behaviors in an epoxy/layered silicate (1 wt%) were examined in needle-plate electrode geometry. A layered silicate was exfoliated in an epoxy base resin by using our AC electric field apparatus. To measure the tree initiation and propagation and the breakdown rate, an alternating current (AC) of 10 kV (60 Hz) was applied to the specimen in needle-plate electrode arrangement with a $30^{\circ}C$ insulating oil bath. In the epoxy/amino silane system, the tree initiation time was 11.5 times higher and the breakdown time was 17.9 times higher than those of the neat epoxy resin. The tree initiation time in the epoxy/layered silicate (1 wt%) system with the amino silane was 2.0 times higher, and the breakdown time was 1.5 times higher than those of the epoxy/layered silicate (1 wt%) system.

• Geomechanics and Engineering
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• v.11 no.6
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• pp.867-877
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• 2016

Collapse shape of tunnel roof in layered Hoek-Brown rock media is investigated within the framework of upper bound theorem. The traditional collapse mechanism for homogeneous stratum is no longer suitable for the present analysis of roof stability, and it would be necessary to propose a curve failure mode to describe the velocity discontinuity surface in layered media. What is discussed in the paper is that the failure mechanism of tunnel roofs, consisting of two different functions, is proposed for layered rock media. Then it is employed to investigate the impending roof failure. Based on the nonlinear Hoek-Brown failure criterion, the collapse volume of roof blocks are derived with the upper bound theorem and variational principle. Numerical calculations and parametric analysis are carried out to illustrate the effects of different parameters on the shape of failure mechanism, which is of overriding significance to the stability analysis of tunnel roof in layered rock media.