• Title/Summary/Keyword: Layer by Layer Deposition

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Effect of Working Pressure on Anode Characteristics of Tin Oxide Thin Films (공정압력에 따른 주석 산화물 박막의 음극 특성)

  • Son, Hyeon-Cheol;Mun, Hui-Su;Seong, Sang-Hyeon;Park, Jong-Wan
    • Korean Journal of Materials Research
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    • v.9 no.1
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    • pp.14-17
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    • 1999
  • Tin oxide films as an anode layer for microbatteries were deposited by using rf magnetron sputtering. Characterization of the films was carried out in terms of working pressure in the range of 5~30 mtorr. Rf power and substrate temperature during deposition were fixed at 2.5W/$\textrm{cm}^2$ and A.T., respectively. The crystal orientation of $SnO_2$films was changed from (110) to (101) or (211) with the increasing working pressure. Refractive index and film density of the films also decreased with the increasing working pressure. The $SnO_2$ thin film formed under optimum conditions was found to have a reversible capacity of 446.9$\mu$Ah/$\textrm{cm}^2$-$\mu\textrm{m}$ and good reversibility when the working pressure was fixed at 10mtorr. As the working pressure decreased, film density increased. It was thought that the capacity of $SnO_2$films increased due to the increase in the amount of active materials which can react with Li electrochemically. Furthermore, cycle characteristics of the anode material was also influenced by film stress.

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Water Column Structure and Dispersal Pattern of Suspended Particulate Matter (SPM) in a floating ice-dominated fjord, Marian Cove, Antarctica during Austral Summer (유빙이 점유한 남극 마리안 소만의 하계기간 수층 구조와 부유물질 분산)

  • Yoo, Kyu-Cheul;Yoon, Hoo-Il;Kang, Cheon-Yun;Kim, Boo-Keun;Oh, Jae-Kyung
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.5 no.4
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    • pp.295-304
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    • 2000
  • Vertical measurement of CTDT at about 30 min intervals and spatial surface temperature, salinity, and concentration of suspended particulate matters were conducted to elucidate the character of water column and the dispersal pattern in a floating ice-dominated fjord, Marian Cove, West Antarctica. Marian Cove showed two distinct water layers in terms of turbidity; 1) cold, fresh, and turbid surface plume in the upper 2 m,2) warm, saline, and relatively clean Maxwell Bay inflow between 15-45 m in water depth. Thermal melting of Maxwell Bay inflow and tidewater glacier/floating ices developed the surface mixed layer and the activity of floating ices cause Maxwell Bay inflow to be unstable. Due to the unstable water column, the development of Maxwell Bay inflow and subsequent surface plume are not influenced by tidal frequency. Coastal current generated by strong northwesterly wind may extend warm, saline, and turbid surface plume into the central part of the cove along the northern coast via the western coast of Weaver Peninsula. Terrigenous sediments of meltwaters from the glaciated ice cliffs near the corner of tidewater glacier and some coasts enter into the cove and their dispersion depends upon the hydrographic regimes (tide, wind, wave etc.). At the period of spring tide, the strong wind stress with the northwesterly wind direction reserve suspended sediment-fed surface plume and so allow the possibility of deposition of terrigenous sediments within the basin of cove.

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A development of new dielectric tracer test method for groundwater logging: laboratory soil column test (지하수 검층을 위한 새로운 유전율 추적자 시험법의 개발)

  • Kim Man-Il;Kim Hyoung-Soo;Jeong Gyo-Cheol
    • The Journal of Engineering Geology
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    • v.14 no.3 s.40
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    • pp.301-311
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    • 2004
  • This study is suggested a new dielectric tracer test method to understand geological structure of porous media and groundwater flow to use the dielectric constant which is one of electrical special quality of various geological materials. To measure their parameters, tracer material is made an ethanol mixing liquid(EML) having a same specific gravity of water. Also, soil materials are prepared a dielectric tracer test using the FDR system that could measure dielectric constant for saturated standard sand and river sand layers which have different initial porosity. To compare with their results, we discussed with the concentration variation of saline water having a saline concentration $3\%$ which is general tracer material by using the electro multi-meter system in the laboratory or field test. In two tracer experiment results, EML tracer test could confirm definitely EML concentration variation from each saturated soil layer as standard and river sands. However, tracer test of saline water $3\%$ concentration could not confirm permeating movement of water by degree of salinity change because these are settled at lower part column in a whole column area continuously. These causes are that specific gravity of saline water is heavier than water. That is, it could know that deposition of saline water is composed of lower part of soil column continuously independently of the direction of water into saturated soil material.

Electrical and Optical Properties of the GZO Transparent Conducting Layer Prepared by Magnetron Sputtering Technique (마그네트론 스퍼터링법으로 제작된 GZO 투명전도막의 전기적 및 광학적 특성)

  • No, Im-Jun;Kim, Sung-Hyun;Shin, Paik-Kyun;Lee, Kyung-Il;Kim, Sun-Min;Cho, Jin-Woo
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.4
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    • pp.110-115
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    • 2010
  • Transparent conducting gallium-doped zinc oxide (GZO) thin films which were deposited on Corning glass substrate using an Gun-type rf magnetron sputtering deposition technology. The GZO thin films were fabricated with an GZO ceramic target (Zn : 97[wt%], $Ga_2O_3$ : 3[wt%]). The GZO thin films were deposited by varying the growth conditions such as the substrate temperature, oxygen pressure. Among the GZO thin films fabricated in this study, the one formed at conditions of the substrate temperature of 200[$^{\circ}C$], Ar flow rate of 50[sccm], $O_2$ flow rate of 5[sccm], rf power of 80[W] and working pressure of 5[mtorr] showed the best properties of an electrical resistivity of $2.536{\times}10^{-4}[{\Omega}{\cdot}cm]$, a carrier concentration of $7.746{\times}10^{20}[cm^{-3}]$, and a carrier mobility of 31.77[$cm^2/V{\cdot}S$], which indicates that it could be used as a transparent electrode for thin film transistor and flat panel display applications.

Electrode Dependence of Asymmetric Behavior of (La,Sr)CoO₃/Pb(Zr,Ti)O₃/(La,Sr)CoO₃ Thin Film Capacitors ((La,Sr)CoO₃/Pb(Zr,Ti)O₃/(La,Sr)CoO₃박막 캐패시터의 비대칭성의 전극 의존성)

  • 최치홍;이재찬;박배호;노태원
    • Journal of the Korean Ceramic Society
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    • v.35 no.7
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    • pp.647-647
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    • 1998
  • (La,Sr)CoO3/Pb(Zr,Ti)O3/(La,Sr)CoO3 (LSCO) heterostructures have been grown on LaAlO3 substrates by pulsed laser deposition (PLD) to investigate asymmetric polarization of Pb(Zr,Ti)O3 (PZT) thin flims with different electrode configuration. P-V hysteresis loop of LSCO/PZT/LSCO was symmetric. However, LaCoO3 (LCO_/PZT/LSCO showed a largely asymmetric P-V hystersis loop and large relaxation of the remanent polarization at the negatively poled state, which means that the negatively poled state was unstable. On the other hand, LSCO/PZT/LCO exhibited large relaxation of the positively poled state. The asymmetric behavior of the polarized states implies the presence of an interal electric firld inside the PZT layer. It is suggested that internal electric field is caused by built-in voltages at LCO/PZT and LSCO/PZT interfaces. The built-in voltages at LCO/PZT and CSCO/PZT interfaces were 0.6 V and -0.12 V, respectively.

Fabrication and Characterization of High Performance Green OLEDs using $Alq_3$-C545T Systems ($Alq_3$-C545T시스템을 이용한 고성능 녹색 유기발광다이오드의 제작과 특성 평가)

  • Jang Ji-Geun;Kim Hee-Won;Shin Se-Jin;Kang Eui-Jung;Ahn Jong-Myong;Lim Yong-Gyu
    • Journal of the Microelectronics and Packaging Society
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    • v.13 no.1 s.38
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    • pp.51-55
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    • 2006
  • The green emitting high performance OLEDs using the $Alq_3$-C545T fluorescent system have been fabricated and characterized. In the device fabrication, 2-TNATA [4,4',4'-tris(2-naphthylphenyl-phenylamino)-triphenylamine] as a hole injection material and NPB [N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] as a hole transport material were deposited on the ITO(indium thin oxide)/glass substrate by vacuum evaporation. And then, green color emission layer was deposited using $Alq_3$ as a host material and C-545T[10-(2-benzothiazolyl)-1,1,7,7- tetramethyl-2,3,6,7-tetrahydro-1H,5H,11H-[1]/benzopyrano[6,7,8-ij]-quinolizin-11-one] as a dopant. Finally, small molecule OLEDs with structure of ITO/2-TNATA/NPB/$Alq_3$:C545T/$Alq_3$/LiF/Al were obtained by in-situ deposition of $Alq_3$, LiF and Al as the electron transport material, electron injection material and cathode, respectively. Green OLEDs fabricated in our experiments showed the color coordinate of CIE(0.29, 0.65) and the maximum power efficiency of 7.3 lm/W at 12 V with the peak emission wavelength of 521 nm.

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A Study on the Preparation and Characteristics of Electrodeposited Lead Dioxide Electrodes (전착 이산화납전극의 제조 및 특성에 관한 연구)

  • Kim, Jae Kwan;Lee, Chung Young;Nam, Chong Woo
    • Applied Chemistry for Engineering
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    • v.4 no.2
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    • pp.273-283
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    • 1993
  • Addition of various acids or organic compounds to the electrolyte solution during the electrodeposition of $PbO_2$ on titanium madras substrate strongly affected performance of the deposited $PbO_2$ layer. Results of X-ray diffractometry ascertained that ${\beta}-PbO_2$ was deposited in acidic electrolyte. Among additives used in this experiment, $PbO_2$ with a high oxygen overvoltage was electrodeposited when sodium lauryl sulfate was added, and $PbO_2$ with a lower chlorine overvoltage was electrodeposited when polyethylene glycol was added to the electrolyte solution. The oxygen and chlorine overvoltage of $PbO_2$ was strongly dependent on the stirring provided during the electrodeposition experiment. It was observed by the SEM results that the $PbO_2$ grains deposited when stirring was not provided during the electrodeposition have larger than $PbO_2$ grains deposited by stirring. In the $PbO_2$ deposition under acidic electrolyte, the oxygen overvoltage increased with larger $PbO_2$ grains and the chlorine overvoltage decreased with smaller $PbO_2$ grains. The optimal current efficiency of $PbO_2$ in the presence of perchloric acid was observed at $Pb(NO_3)_2$ 560g/l, $65{\sim}70^{\circ}C$, and pH>1.

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Retinopathy Induced by Zinc Oxide Nanoparticles in Rats Assessed by Micro-computed Tomography and Histopathology

  • Kim, Young Hee;Kwak, Kyung A;Kim, Tae Sung;Seok, Ji Hyeon;Roh, Hang Sik;Lee, Jong-Kwon;Jeong, Jayoung;Meang, Eun Ho;Hong, Jeong-sup;Lee, Yun Seok;Kang, Jin Seok
    • Toxicological Research
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    • v.31 no.2
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    • pp.157-163
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    • 2015
  • Nanotechnology has advanced at an extremely rapid pace over the past several years in numerous fields of research. However, the uptake of nanoparticles (NPs) into the body after administration through various routes may pose a risk to human health. In this study, we investigated the potential ocular toxicity of 20-nm, negatively- charged zinc oxide (ZnO) NPs in rats using micro-computed tomography (micro-CT) and histopathological assessment. Animals were divided into four groups as control group, ZnO NPs treatment group (500 mg/kg/day), control recovery group, and ZnO NPs treatment and recovery group. Ocular samples were prepared from animals treated for 90 days (10 males and 10 females, respectively) and from recovery animals (5 males and 5 females, respectively) sacrificed at 14 days after final treatment and were compared to age-matched control animals. Micro-CT analyses represented the deposition and distribution of foreign materials in the eyes of rats treated with ZnO NPs, whereas control animals showed no such findings. X-ray fluorescence spectrometry and energy dispersive spectrometry showed the intraocular foreign materials as zinc in treated rats, whereas control animals showed no zinc signal. Histopathological examination revealed the retinopathy in the eyes of rats treated with ZnO NPs. Neuronal nuclei expression was decreased in neurons of the ganglion cell layer of animals treated with ZnO NPs compared to the control group. Taken together, treatment with 20-nm, negatively-charged ZnO NPs increased retinopathy, associated with local distribution of them in ocular lesions.

Interpretation of Sedimentary Structure and Depositional Environment Based on a High-Resolution Seismic Profile across the Northeastern Boundary of the Pungam Basin (고해상도 탄성파자료를 이용한 풍암분지 북동부의 퇴적구조 및 퇴적환경 연구)

  • Kim, Gi Yeong;Heo, Sik
    • Journal of the Korean Geophysical Society
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    • v.2 no.2
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    • pp.91-99
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    • 1999
  • A high-resolution seismic profile acquired across the northeastern boundary of the Pungam Basin, one of the Cretaceous sedimentary basins in Korea, has been interpreted to delineate subsurface geological structures across the basin boundary. We identified boundary faults and unconformity surfaces of the basin and divided sediment body into three seismic depositional units (Units I, II, and III from youngest to oldest). Inferred from fault geometry and type, northeastern part of the Pungam Basin has been formed by a strike-slip fault whereas the normal faults near the boundary were formed by transtensional movement along a fault zone. A 350-400 m thick sediment layer is overlying the Precambrian gneiss. Bedding planes of Unit III are dipping westward and are closely related to an anticline in the acoustic basement. Unit II is also tilted westward, suggesting that the eastern part of the fault zone was uplifted after deposition of lower part of the sedimentary body. Afterward, the uplifted sediment layers were eroded and transported to the western part of the basin. Chaotic reflection pattern of sedimentary Units II and III may suggest that strike-slip movement along the fault zone deformed basin-filled sediments.

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Enhancement of Crystallinity in ZnO:Al Films Using a Two-Step Process Involving the Control of the Oxygen Pressure (산소 압력의 조절과 함께 두 번의 증착 과정을 이용한 ZnO:Al 박막에 결정성의 향상)

  • Moon, Tae-Ho;Yoon, Won-Ki;Lee, Seung-Yoon;Ji, Kwang-Sun;Eo, Young-Joo;Ahn, Seh-Won;Lee, Heon-Min
    • Journal of the Korean Vacuum Society
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    • v.19 no.2
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    • pp.128-133
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    • 2010
  • ZnO:Al films were deposited by DC-pulsed magnetron sputtering using a two-step process involving the control of the oxygen pressure. The seed layers were prepared with various Ar to oxygen flow ratios and the bulk layers were deposited under pure Ar. As the oxygen pressure during the deposition of the seed layer increased, the crystallinity and degree of (002) texturing increased. The resistivity gradually decreased with increasing crystallinity from $4.7\times10^4\Omega{\cdot}cm$ (no seed) to $3.7\times10^4\Omega{\cdot}cm$ (Ar/$O_2$ = 9/1). The etched surface showed a crater-like structure and an abrupt morphology change appeared as the crystallinity was increased. The sample deposited at an Ar/$O_2$ flow ratio of 9/1 showed a very high haze value of 88% at 500 nm, which was explained by the large feature size of the craters, as shown in the AFM image.