• 제목/요약/키워드: Layer Removal

검색결과 664건 처리시간 0.036초

직접메탄올 연료전지에서 전지 성능에 대한 확산층의 영향 (Effect of Diffusion Layer for Cell Performance in DMFC)

  • 권부길;박경원;최종호;성영은
    • 한국전기화학회:학술대회논문집
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    • 한국전기화학회 2001년도 연료전지심포지움 2001논문집
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    • pp.179-184
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    • 2001
  • The diffusion layer within MEA(membrane electrode assembly) has been evaluated important factor for improvement of cell performance in DMFC. The diffusion layer in MEA structure leads to the reduction of catalyst loss in active catalysts layer as well as prevention of water-flooding in cathode. Cell performance is directly affected by interior properties of diffusion layer materials. Acetylene Black and $RuO_2$ with large pore size and low porosity compared to Vulcan XC-72R gave better performance caused by vigorous methanol diffusion and water removal. And $RuO_2$ as diffusion layer materials showed different behavior in anode and cathode compartment, that is, diffusion layers in anode and cathode side make methanol diffusion and water removal facilitate, respectively.

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An Investigation on Separation Configurations in Compressor Cascades with Boundary Layer Suction(BLS)

  • Zhang, Hualiang;Tan, Chunqing;Zhang, Dongyang;Wang, Songtao;Wang, Zhongqi
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2008년 영문 학술대회
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    • pp.143-149
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    • 2008
  • A numerical study was performed for a vane of a compressor with a high-turning angle and meridional divergence. At first, the effect of the suction position was discussed. Then, the optimal suction position was applied to the cascades with the aspect ratio of 2.53 and 0.3, respectively, to get the knowledge of the effect of the endwall boundary layer removal on the secondary flow along the blade height. At last, using the critical principles of the three-dimensional separation, the topological structures of the flow patterns of the body surfaces and the separation configurations were discussed in detail. The results show that the largest reduction of the total loss can be achieved when the suction slot is near the suction side. The topological structure as well as the separation configuration varies due to boundary layer removal, which restrains the flow separation at the corner and delays or depresses the separation on the suction surface. Compared with the original cascade, the cascade with the endwall boundary layer removal has a higher blade loading along the most span. Furthermore the flow loss decreases and distributes uniformly along the span.

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Development of Ceria-Based Slurry with High Selectivity for STI CMP

  • Lim, G.;Kim, T.E.;Kim, J.;Lee, J.H.;Lee, H.W.
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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    • pp.439-440
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    • 2002
  • Nano-Crystalline $CeO_2$ particles were dispersed in deionized water with controlled slurry chemicals for CMP test. According to the CMP test, the removal rate of $SiO_2$ layer was mainly controlled by the size and crystallinity of $CeO_2$ particles which can be controlled by the heat-treatment condition during $CeO_2$ synthesis. In contrast, the removal rate of $Si_3N_4$ layer was significantly influenced by the passivation reagent which protects the $Si_3N_4$ surface layer from excessive dissolution during CMP.

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자유수면습지의 잔재물층에 의한 하천수 질소제거 비교 (Comparison of Nitrogen Removal in Free Water Surface Wetlands Purifying Stream Water with and without Litter Layer on its Bottom)

  • 양홍모
    • 한국환경복원기술학회지
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    • 제11권6호
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    • pp.120-129
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    • 2008
  • Removal rate of $NO_3-N$ and TN in a free water surface wetland system with litter layer on its bottom was compared with that without one. The system was established on floodplain in the down reach of the Gwangju Stream in 2001. Its dimensions were 31 meters in length and 12 meters in width. Water of the stream was funneled into it and its effluent was discharged back into the channel. Average litter layer of 9.6 cm was formed on its bottom in 2007. The layer and above-ground parts of reeds and cattails on the system were eliminated in Spring 2008. Volumes and water quality of inflow and outflow of the system were analyzed from May to November in 2007 and 2008, respectively. Inflow into the system both in 2007 and 2008 averaged approximately $40m^3/day$ and hydraulic residence time both in 2007 and 2008 was about 1.5 days. Average influent $NO_3-N$ concentration in 2007 and 2008 was 2.16 and 2.05 mg/L, respectively and influent TN concentration in 2007 and 2008 averaged 3.98 and 3.89 mg/L, respectively. With a 0.05 significance level, effluent temperatures, influent concentrations of $NO_3-N$ and TN, and stem numbers per square meter and height of the emergent plants showed no difference between the system with litter layer and without one. $NO_3-N$ removal in the system with litter layer and without it averaged 55.59 and 46.06%, respectively and TN retention averaged 57.24 and 48.97%, respectively. Both $NO_3-N$ and TN abatement rates in the system with litter layer were significantly high (p < 0.001) when compared with those without one. The wetland system having litter layer on its bottom was more efficient for $NO_3-N$ and TN retention than that without one.

2단 생물막여과 탈질시스템에서 지하수의 질산성질소 및 입자제거특성 (Removal of Nitrate and Particulate from Groundwater with Two stage Biofilter system)

  • 이무재;박상민;전항배;김공수;임정수
    • 한국물환경학회지
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    • 제21권6호
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    • pp.669-675
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    • 2005
  • Biological nitrate removal from groundwater was investigated in the biofilters packed with both gravel/sand and plastic media. Removal of particles and turbidity were also investigated in the 2-stage biofilter system consisted of biofilter and subsequent sand filter. In the single biofilter packed with gravel and sand, nitrate removal efficiency was dropped with the increase of filtration velocity and furthermore, nitrite concentration increased up to 3.2 mg-N/L at 60 m/day. Denitrification rate at the bottom layer below 25 cm was faster 8 times than upper layer in the up-flow biofilter. Nitrite build-up, due to the deficiency of organic electron donors, occurred at the upper layer of bed. Besides DO concentration and organic carbon, contact time in media was the main factor for nitrate removal in a biofilter. The most of the effluent particles from biofilter was in the range from 0.5 to $2.0{\mu}m$, which resulted in high turbidity of 1.8 NTU. However, sand filter followed by biofilter efficiently performed the removal of particles and turbidity, which could reduce the turbidity of final filtrate below 0.5 NTU. Influent nitrate was removed completely in the 2-stage biofilter and no nitrite was detected.

산화제($H_2O_2$)의 첨가 유무에 따른 Ti/TiN막의 CMP 연마 특성 (Improvement of Polishing Characteristics Using with and without Oxidant ($H_2O_2$) of Ti/FiN Layers)

  • 이경진;서용진;박창준;김기욱;박성우;김상용;이우선
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.1
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    • pp.88-91
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    • 2003
  • Tungsten is widely used as a plug for the multi-level interconnection structures. However, due to the poor adhesive properties of tungsten (W) on $SiO_2$ layer, the Ti/TiN barrier layer is usually deposited onto $SiO_2$ for increasing adhesion ability with W film. Generally, for the W-CMP (chemical mechanical polishing) process, the passivation layer on the tungsten surface during CMP plays an important role. In this paper, the effect of oxidants controlling the polishing selectivity of W/Ti/TiN layer were investigated. The alumina ($Al_2O_3$) abrasive containing slurry with $H_2O_2$ as the oxidizer, was studied. As our preliminary experimental results, very low removal rates were observed for the case of no-oxidant slurry. This low removal rate is only due to the mechanical abrasive force. However, for Ti and TiN with $H_2O_2$ oxidizer, different removal rate was observed. The removal mechanism of Ti during CMP is mainly due to mechanical abrasive, whereas for TiN, it is due to the formation of metastable soluble peroxide complex.

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W/Ti/TiN막의 연마 선택비 개선을 위한 산화제의 역할 (Role of oxidant on polishing selectivity in the chemical mechanical planarization of W/Ti/TiN layers)

  • 이경진;서용진;박창준;김기욱;김상용;이우선
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 센서 박막재료 반도체 세라믹
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    • pp.33-36
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    • 2003
  • Tungsten is widely used as a plug for the multi-level interconnection structures. However, due to the poor adhesive properties of tungsten (W) on $SiO_2$ layer, the Ti/TiN barrier layer is usually deposited onto $SiO_2$ for increasing adhesion ability with W film. Generally, for the W-CMP (chemical mechanical polishing) process, the passivation layer on the tungsten surface during CMP plays an important role. In this paper, the effect of oxidants controlling the polishing selectivity of W/Ti/TiN layer were investigated. The alumina $(Al_2O_3)$ abrasive containing slurry with 5 % $H_2O_2$ as the oxidizer, was studied. As our preliminary experimental results, very low removal rates were observed for the case of no-oxidant slurry. This low removal rate is only due to the mechanical abrasive force. However, for Ti and TiN with 5 % $H_2O_2$ oxidizer, different removal rate was observed. The removal mechanism of Ti during CMP is mainly due to mechanical abrasive, whereas for TiN, it is due to the formation of metastable soluble peroxide complex.

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Clinical Importance of the Smear layer

  • Cho, Yong-Bum
    • 대한치과보존학회:학술대회논문집
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    • 대한치과보존학회 2002년도 추계학술대회
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    • pp.720-720
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    • 2002
  • A number of investigations have shown that the presence of bacteria is prerequisite for developing pulpal and/or periradicular pathosis. Depending on the stage of pulpal pathosis, various species of bacteria can be cultured from infected root canals. Kakehashi et al. showed that exposure of pulpal tissue in germ-free rats was characterized by minimal inflammation and dentinal bridging while exposure of pulpal tissue in conventional rats with normal oral flora was characterized by pulpal necrosis, chronic inflammation, and periapical lesions. Currently used methods of cleaning and shaping, especially rotary instrumentation techniques, produce a smear layer that covers root canal walls and the openings to the dentinal tubules. The smear layer contains inorganic and organic substances that include fragments of odontoblastic processes, microorganisms, their by products and necrotic materials. Because of its potential contamination and adverse effect on the outcome of root canal therapy, it seems reasonable to suggest removal of the smear layer for disinfection of the entire root canal system. Presence of this smear layer prevents penetration of intracanal medications into the irregularities of the root canal system and the dentinal tubules and also prevents complete adaptation of obturation materials to the prepared root canal surfaces. Removal of the smear layer by an intracanal irrigant and placement of an antibacterial agent in direct contact with the content of dentinal tubules should allow disinfection of this complex system and better outcome for the root canal therapy. A new solution, which was a mixture of a tetracycline, an acid, and a detergent(MTAD), was developed in the Department of Endodontics, Dental School. Lorna Linda University, USA. It has been demonstrated that MTAD was an effective solution for the removal of the smear layer and does not significantly change the structure of the dentinal tubules when used as a final irrigant in conjunction with 1 % NaOCl as a root canal irrigant. Studies are in progress to compare the anti- microbial properties of this newly developed solution with those of sodium hypochlorite and EDTA that are currently used to irrigate the root canals and remove the smear layer from the surfaces of instrumented root canals.canals.

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춘계 한국 동해남부 연안해역에서 해수중 $^{210}Po$$^{234}Th$의 제거 (Removal of $^{210}Po$ and $^{234}Th$ from Seawater at the East-southern Coastal Region of Korea Peninsula in Spring)

  • 이행필;양한섭;김기현
    • 한국수산과학회지
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    • 제29권3호
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    • pp.332-344
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    • 1996
  • 본 연구는 대마난류의 주류역인 동해 남부해역의 포항 연안의 6개 정점에서 1994년 4월 26일부터 29일까지 수층별로 채수하고, 이 해역에서 $^{210}Po$$^{234}Th$의 제거속도 혹은 체류시간과 제거과정을 알아보았다. $^{210}Po$는 대체적으로 연안쪽 정점들에서는 표면혼합층에서 낮고 수온약층을 포함한 하부층에서 다소 높지만, 바깥쪽 정점들에서는 표면혼합층에서 오히려 높아지는 경향을 보였다. 그러나 $^{210}Pb$는 수심이 깊어짐에 따라 점차 감소하는 경향을 보였다. 또한, 표면 혼합층에서는 대체적으로 $^{210}Po$가 어미핵종보다 부족량을 보이나, 수온약층을 포함한 하부층에서는 어미핵종과 거의 방사평형된 농도를 보이거나 약간의 과잉량을 보였다. $^{210}Pb$는 표면혼합층에서는 어미핵종인 $^{226}Ra$보다 과잉량을 보이나, 수온약층을 포함한 하부층에서는 약간 부족량을 보이거나 혹은 거의 방사평형된 농도를 보인다. $^{234}Th$는 표면혼합층과 수온약층이 그 하부층보다 현저히 낮다. $^{210}Po$의 체류시간은 $1\~4$년의 범위로 비교적 연안쪽의 정점들 (E3, E4, E5)이 바깥쪽에 위치한 정점들(E6, E7)보다 짧았다. 그러나 정점 E8에서는 약 10년으로 매우 길었으며, 이는 다른 정점들에 비해 표면혼합층이 두꺼운 관계로 하부 표면혼합층에서 재순환된 $^{210}Po$가 수직혼합되었기 때문일 것이다. 한편, $^{234}Th$의 체류시간은 $52\~74$일의 범위로 정점별 차이가 그다지 크지 않았으며, $^{210}Po$의 체류시간에 비해서 훨씬 짧았다. 표면혼합층 내에서 해수중 $^{234}Th$는 용존태의 수층별 제거속도상수가 총부유물질과 정의 상관성을 나타내는 것으로 보아 주로 비생물기원의 무기입자에 흡착되어 제거되고 있는 반면에, $^{210}Po$는 용존태의 제거 속도상수가 클로로필 $^{210}Po$와 정의 상관성을 나타내는 것으로 보아 주로 생물체 (주로 동${\cdot}$식물플랑크톤)에 흡수되어 제거되고 입자물질 농도에는 크게 영향을 받지 않는 것 같다.

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A Study of mechanical properties of oxide layer removed Co-Cr-Mo abutments

  • Ryu, Jae-ho;Huh, Jung-Bo;Ro, Jung-Hoon;Yun, Mi-Jung;Jeong, Chang-Mo
    • 대한치과의사협회지
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    • 제53권11호
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    • pp.804-816
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    • 2015
  • PURPOSE: The aim of this study was to evaluate the influence of the oxide layer removal process in the Co-Cr-Mo (CCM) abutment after casting procedure on the prosthesis settlement and screw stability. MATERIALS AND METHODS: CCM abutments of four different interface conditions (CCM-M; machined, CCM-O; oxide layer formed, CCM-B; blasted, CCM-P; polished after blasted) and gold abutment (Gold-C; Cast with type III Gold alloy) were used. The initial settling values of abutments were evaluated according to the difference of implant-abutment length when the tightening torques were applied at 5 Ncm and 30 Ncm, and the settling values of abutments caused by loading were evaluated according to the difference of implant-abutment length before and after loading with 250 N, 100000 cycle. The loss ratios of removal torque for abutment screws were evaluated according to the difference in value of removal torques under 30 Ncm tightening torque applied before and after cyclic loading. RESULTS: The CCM-P and CCM-B group showed a higher initial settling value compared with the Gold-C group (P<.05), while the Gold-C group showed the highest settling values caused by loading (P<.05) and no significant differences were observed for between CCM groups (P>.05). The loss ratio of removal torque values for the CCM-B, CCM-P groups did not differ significantly from that of the Gold-C group (P>.05). CONCLUSION: Even though the oxide layer was removed by different methods, CCM abutment with internal conical connection structure showed lower abutment settling and similar screw loosening after cyclic loading compared with gold abutment.